Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
The precursor of aluminum-doped zinc oxide nanocrystals modified by nitrogen atoms (N-AZO) can be quantity-produced by ultrasonic–hydrothermal equipment. Then the N-AZO photocatalysts with good visible-light response were synthesized via solid-phase method with urea as a nitrogen source. The ultraviolet visible (UV–vi…
We report the synthesis of epitaxial bilayers of ultrathin La 0.92 MnO 3 /LaCoO 3 (LMO/LCO) on SrTiO 3 (STO) by polymer solution deposition. We have achieved an excellent control over the thickness (from ∼4 to ∼20 nm) and roughness of the films, which allows the fabrication of the sharp interfaces required for their f…
Abstract For chiral gels and related applications, one of the critical issues is how to modulate the stereoselective interaction between the gel and the chiral guest precisely, as well as how to translate this information into the macroscopic properties of materials. Herein, we report that this process can also be mod…
In this study, the extent to which the scaffold architecture of polyglycerol sulfates affects inflammatory processes and hemocompatibility is investigated. Competitive L-selectin binding assays, cellular uptake studies, and blood compatibility readouts are done to evaluate distinct biological properties. Fully glycero…
Using density functional theory with a hybrid functional, we calculate the ionization energies and electron affinities of a series of delafossite compounds ($AM$O${}_{2}$: $A=\text{Cu}$, Ag; $M=\text{B}$, Al, Ga, In, Sc). The alignments of the valence band maximum and the conduction band minimum, which directly relate…
We present a microscopic study of optical properties of Bernal-stacked bilayer graphene. Our focus lies on the absorption spectrum explicitly including the impact of fully momentum-dependent optical and Coulomb matrix elements. Our approach is based on the density matrix formalism combined with tight-binding wave func…
Abstract Organic nanoparticles are attracting many significant applications in bio‐imaging and nanomedicine. However, in comparison with intensive studies of metal and inorganic nanoparticles, the research of organic nanoparticles is still at a very early stage due to their complex physical and chemical properties. Mo…
In this work, two mesoporous silicas functionalized with C18 groups (SM-C18 and SBA-15-C18) have been synthesized for their evaluation as stationary phases in SPE for the extraction and preconcentration of seven steroid hormones (estrone, estradiol, estriol, ethinyl estradiol, diethylstilbestrol, testosterone, and pro…
Macrocyclic compounds consisting of three 2,6-pyridylene and three 3,5-pyridylene units linked by acetylene bonds were synthesized by a Sonogashira reaction. The X-ray structures showed π-stacked pairs of two macrocycles, in which a 2,6-pyridylene unit of the one molecule overlaps a 3,5-pyridylene of the other molecul…
Rare-earth materials epitaxially codeposited with III-V semiconductors form small, spherical rare-earth-monopnictide nanoparticles embedded within the III-V host. The small size of these particles (approximately 1.5 nm diameter) suggests that interesting electronic properties might emerge as a result of both confineme…
Long glass fiber (LGF)‐reinforced thermoplastic polyurethane (TPU) elastomers and polyoxymethylene (POM) (LGF/TPU/POM) composites were prepared by using self‐designed impregnation device. Dynamic mechanical properties of the LGF/TPU/POM composites have been investigated by using dynamic mechanical thermal analysis. Th…
Safe storage of hydrogen is a key issue for development of the hydrogen economy. Solid-state hydrogen storage through reversible formation of hydrides is one of the most promising methods. Herein reports for the very first time a combined experimental and theoretical study of the hydrogen absorption–desorption of MSi…
Molecular and ionic species of nitrogen oxides have been injected, formed, and then trapped within a borosilicate glass during a thermal poling process. This original observation denotes a new aspect of poling mechanisms for ionic glasses. For each poled borosilicate glasses studied, compositional, structural, and sec…
Helium plasma irradiation leads to the formation of nanostructures on the surface when certain conditions are satisfied. The surface morphology changes due to helium plasma irradiation were investigated on single crystal tungsten samples with different crystal orientations. Differences in surface morphology changes we…
The aim of this study was to investigate the effect of elastane linear density and draft ratio on the physical and mechanical properties of core-spun yarns. Twenty yarn samples were prepared on industrial scale in a spinning mill with two different yarn linear densities, each with different two elastane deniers and fi…
We observe that the zircon-type RCrO4 (R = Ho, Gd, Lu) compounds exhibit complicated magnetic properties and large magnetic entropy change due to the strong competition between ferromagnetic and antiferromagnetic interactions. For a field change of 7 T, the maximum values of entropy change and refrigerant capacity rea…
We have studied the optical response and dynamical behavior of photocarriers in BiFeO${}_{3}$ thin films by means of transient absorption (TA) and photocurrent (PC) measurements. PC and absorption spectroscopy indicate that BiFeO${}_{3}$ thin films have an indirect band gap energy of \ensuremath{\sim}2.4 eV. The TA an…
The catalytic, electrochemical, and optical properties of gold clusters and small nanoparticles depend on the cluster size, on the nature of the ligand shell and on the solvent environment. The structural and electronic properties of the neutral and trication bare cluster Au 11 are investigated using density functiona…
A simple approach to the highly fluorescent near-infrared aza-BODIPY dyes with higher fluorescence quantum yields (up to 0.81 in toluene) in comparison with their known analogues is presented. Our approach is based on the restricted rotations of the 1,7-phenyl groups to the mean plane of the aza-BODIPYs, which is achi…
Magnetic and structural aspects of the annealing-induced transformation of rapidly-solidified Mn55Al45 ribbons from the as-quenched metastable antiferromagnetic (AF) ε-phase to the target ferromagnetic (FM) L10 τ-phase are investigated. The as-solidified material exhibits a majority hexagonal ε-MnAl phase revealing a…