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Influence of Storage Conditions on the Stability of Lactide

Valentina N. Glotova、Margarita Zamanova、Anna V. Yarkova 等 6 位作者2014-01-01Procedia Chemistry

The objective following of the present study was to investigate the effect of different storage time and conditions on the stability of lactide. In this study the samples of lactide with different purities were stored under three various storage conditions and the compound integration was monitored for a period of 2 w…

biodegradable polymer synthesis and propertiesAmino Acid Enzymes and MetabolismDigestive system and related health

On the dual character of charged metal–molecule hybrids and the opposite behaviour of the forward and reverse CT processes

Jéssica Román-Pérez、Silvia P. Centeno、María Rosa López‐Ramírez 等 7 位作者2014-01-01Physical Chemistry Chemical Physics

DFT calculations predict two different electronic structures of metal-molecule hybrids which are selected depending on the surface charge. While the metal-to-molecule CT states are very sensitive to the charge, the energies of the reverse molecule-to-metal CT processes are surprisingly not modified at all by the charg…

Radioactive element chemistry and processingElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides

Influence of Temperature Change on Column Buckling of Double Walled Carbon Nanotubes Using Different Theories

Khaled Amara、Okkacha Youb、Mokhtar Bouazza 等 5 位作者2014-01-01Energy Procedia

The present paper examines the thermal effect on axially compressed buckling of a multiwalled carbon nanotube based on the gradient elasticity theories. The small-size effect, which plays an essential role in the buckling behavior with large aspect ratios under axial compression coupling with temperature change, is ca…

Carbon Nanotubes in CompositesBoron and Carbon Nanomaterials ResearchNonlocal and gradient elasticity in micro/nano structures

Magnéli oxides as promising <em>n</em>-type thermoelectrics

Gregor Kieslich、Wolfgang Tremel2014-01-01AIMS Materials Science

The discovery of a large thermopower in cobalt oxides in 1997 lead to a surge of interest in oxides for thermoelectric application. Whereas conversion efficiencies of <em>p</em>-type oxides can compete with non-oxide materials, <em>n</em>-type oxides show significantly lower thermoelectric performances. In this contex…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsTransition Metal Oxide Nanomaterials

Synthesis and Properties of a Biodegradable Dendritic Magnetic Resonance Imaging Contrast Agent

Tingting Li、Yue Qian、Mingzhou Ye 等 6 位作者2014-01-01Chinese Journal of Chemistry

Abstract Novel biodegradable dendritic contrast agents (DCAs) based on polyester dendrimers were synthesized and characterized. The DCAs were stable at acidic pH, but hydrolyzed rapidly at physiological pH, which rendered the DCA's long‐term Gd 3+ retention as low as that of small molecule CAs. Their longitudinal rela…

Metal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal ComplexesDendrimers and Hyperbranched Polymers

Interfacial complexation behavior of anionic and cationic cellulose derivatives

Mahmoud H.M.A. Shibraen、Chunyan Wang、Hajo Yagoub 等 6 位作者2014-01-01RSC Advances

Study effect of pH values, ionic strength and temperature on assembly behavior of quaternized cellulose and carboxymethyl cellulose.

Nanocomposite Films for Food PackagingAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Supramolecular hydrogel based on L-cysteine and silver nanoparticles

О. А. Баранова、S. D. Khizhnyak、П. М. Пахомов2014-01-01Journal of Structural Chemistry

A supramolecular hydrogel is synthesized on the basis of L-cysteine and silver nitrate with incorporated silver nanoparticles (SNPs), which are stabilized by L-cysteine. The steps in the synthesis and the structure and properties of the new system are investigated.

Advanced biosensing and bioanalysis techniquesSupramolecular Self-Assembly in MaterialsNanocluster Synthesis and Applications

Silica–PEG gel immobilization of mammalian cells

Eduardo Reátegui、Lisa Kasinkas、Katrina Kniesz 等 5 位作者2014-01-01Journal of Materials Chemistry B

In this study, human foreskin fibroblasts and mouse embryonic fibroblasts were encapsulated in mechanically reversible, THEOS and THEOS-PEG gels that completely immobilized them restricting their motility, growth and proliferation. The changes in the membrane integrity and metabolic activity (MA) of the immobilized ce…

3D Printing in Biomedical ResearchProtist diversity and phylogenyDiatoms and Algae Research

Surface Transport Mechanism and Bi-Pathway ORR Kinetics for Solid Oxide Fuel Cell Cathode

Hui Zhang、Mingyang Gong、Kirk Gerdes 等 4 位作者2014-01-01Journal of The Electrochemical Society

A one-dimensional continuum model related to close-packing theory has been developed to produce insights into the oxygen reduction reaction (ORR) process in a dense LSM-type cathode system. By incorporating SOFC cathode particle size, the modeling simulations reveal detailed surface processes and parallel reaction pat…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

One-step and eco-friendly modification of cellulose membranes by polymer grafting

Julie Credou、Rita Faddoul、Thomas Berthelot2014-01-01RSC Advances

Cellulose sheets were grafted with several acrylic polymers, first globally through a dipping procedure and then locally by inkjet printing.

Advanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical ApplicationsBiosensors and Analytical Detection

Spectroscopic and photophysical study of the demetallation of a zinc porphyrin and the aggregation of its free base in a tetraalkylphosphonium ionic liquid

Neeraj Kumar Giri、Abhinandan Banerjee、Robert W. J. Scott 等 5 位作者2014-01-01Physical Chemistry Chemical Physics

Dissolving zinc tetraphenylporphyrin in the tetraalkylphosphonium chloride ionic liquid P4448Cl results in progressive demetallation of the solute and quantitative production of the free base porphyrin. Aggregation of the free base occurs in which the monomer and J aggregates are in fully reversible thermal equilibriu…

Electrochemical sensors and biosensorsMolecular Sensors and Ion DetectionPorphyrin and Phthalocyanine Chemistry

Investigation of interphase effects on mechanical behaviors of carbon nanocone-based composites

Mir Masoud Seyyed Fakhrabadi、Navid Khani2014-01-01Mechanics & Industry

This paper presents the mechanical properties of carbon nanocone-based polymer composites in the presence of interphase layer. Some representative volume elements are considered to study the elastic behaviors of the transversely isotropic nanocomposite and the effects of the interphase layer on four of five independen…

Carbon Nanotubes in CompositesMechanical Behavior of CompositesPolymer Nanocomposites and Properties

Self-assembly of novel benzimidazole N-glycosylamines into nanofibers and nanospheres

Manivannan Kalavathi Dhinakaran、Kamalakannan Soundarajan、Thangamuthu Mohan Das2014-01-01New Journal of Chemistry

Cu <sup>2+</sup> ions induce the change in the morphology of self-assembled benzimidazole <italic>N</italic> -glycosylamines from nano-fibers to nano-spheres.

RNA Interference and Gene DeliverySupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Electrical and Magnetic Properties of Multiferroic $(1\hbox{-}{\rm x})\ {\hbox{BiFeO}}_{3}\hbox{-}{\rm x}\ {\hbox{CoFe}}_{2}{\hbox{O}}_{4}$ Nanocomposite Thin Films Derived by Sol-gel Process

Mintu Tyagi、Mukesh Kumari、Ratnamala Chatterjee 等 5 位作者2014-01-01IEEE Transactions on Magnetics

In the present work, multiferroic (1-x) BiFeO3-x (CoFe2O4) ( x=0, 0.3, 0.5) nanocomposite thin films were prepared by sol-gel spin coating process. Structural, electrical and magnetic properties of nanocomposite thin films have been studied. X-ray diffraction study confirmed the co-existence of both perovskite BiFeO3(…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

An Empirical Model for the Ballistic Limit of Bi-layer Ceramic/metal Armour

Ahmad Serjouei、Runqiang Chi、Sridhar Idapalapati 等 4 位作者2014-01-01Procedia Engineering

An empirical model to estimate the ballistic velocity limit (BLV) for ceramic/metal bi-layer armour materials is proposed by considering momentum and energy balance during impact process. Impact simulations of different combinations of various thicknesses and materials for front ceramic and backing metallic layers and…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology

High capacitance in BiFeO3 nanorod structure

Subhasis Rana、Nabanita Dutta、S.K. Bandyopadhyay 等 5 位作者2014-01-01AIP conference proceedings

A remarkably high value of specific capacitance of 450 F/g is observed through electrochemical measurements in the electrode made of multiferroic Bismuth Ferrite (BFO) in the form of nanorods protruding out. These were developed on porous Anodised Alumina (AAO) templates using wet chemical technique. Diameters of nano…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsSmart Materials for Construction

Thermal boundary conductance between Al films and GaN nanowires investigated with molecular dynamics

Xiaowang Zhou、Reese E. Jones、Patrick E. Hopkins 等 4 位作者2014-01-01Physical Chemistry Chemical Physics

GaN nanowires are being pursued for optoelectronic and high-power applications. In either use, increases in operating temperature reduce both performance and reliability making it imperative to minimize thermal resistances. Since interfaces significantly influence the thermal response of nanosystems, the thermal bound…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies