Materials Literature
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Because of the wide use of water injection for enhanced oil recovery in the oil fields in order to displace oil into the production well, many reservoirs experience scale deposition problems. Scale formation can cause the production path to be blocked and also cause significant reduction in productivity. One of the mo…
Boroxines, (R‐BO) 3 , which can be easily synthesized via a dehydration reaction of boronic acids, R–B(OH) 2 , selectively self‐assemble in toluene into nanofibers, nanorods, nanotapes, and nanotubes, depending on the aromatic substituent (R). Spectroscopic measurements show that the nanotube consists of a J ‐aggregat…
Nitinol’s superelastic and shape memory effects can be used in passive or active actuation systems. Often used in the aerospace industry, the use of Nitinol for actuation is also growing in the biomedical fields and elsewhere. However, the industry currently lacks the ability to produce complex Nitinol actuators, whic…
We introduce a method for isolating graphene grown on epitaxial Ru(0001)/α-Al2O3. The strong graphene/Ru(0001) coupling is weakened by electrochemically driven intercalation of hydrogen underpotentially deposited in aqueous KOH solution, which allows the penetration of water molecules at the graphene/Ru(0001) interfac…
Sharp dynamic thermal gradient (∇T ≈ 45 °C mm(-1)) field-driven assembly of cylinder-forming block copolymer (c-BCP) films filled with PS-coated gold nanoparticles (AuNPs; dNP ≈ 3.6 nm, φNP ≈ 0-0.1) is studied. The influence of increasing AuNP loading fraction on dispersion and assembly of AuNPs within c-BCP (PS-PMMA)…
Exchanging one Ge(2+) with two Li(+) per formula unit in (GeTe)n(Sb2Te3) (n = 1, 2, 3, ...) eliminates cation vacancies, because it leads to an equal number of cations and anions. This substitution results in the solid solution (GeTe)x(LiSbTe2)2 (with x = n - 1, but n not necessarily an integer). For x < 6, these stab…
We investigated the growth and partial reduction of Sm 2 O 3 (111) thin films on Pt(111) using low energy electron diffraction (LEED) and scanning tunneling microscopy (STM). We find that the Sm 2 O 3 (111) films are high quality and grow in a defective fluorite structure wherein the Sm cations adopt a hexagonal (1.37…
Crystallization temperatures, activation energies, and thermal diffusivities of In3Sb1Te2 (IST) and Ge2Sb2Te5 (GST) are investigated with a differential scanning calorimetry, a xenon laser flash, and a transmission electron microscopy. The activation energies for crystallizing the IST and the GST are 5.2 eV and 3.31 e…
There is a growing need for biolabels that can be used in both optical and electron microscopies, are non-cytotoxic, and do not photobleach. Such biolabels could enable targeted nanoscale imaging of sub-cellular structures, and help to establish correlations between conjugation-delivered biomolecules and function. Her…
Letter to the EditorThe oxidative stress mechanism is probably the most well developed toxicological pathway for explaining nanoparticle toxicity (Meng et al. 2009) and a number of in vitro models ...
Piezoelectret transducers may be characterized relative to other kinds of piezoelectric transducers with respect to their combined transmit-receive performance by a figure of merit (FOM). Reasonable FOMs for the specific case of broadband (non-resonant) airborne ultrasonics are discussed in this paper. These FOMs are…
In biopolyester synthesis, polyhydroxyalkanoate (PHA) synthase (PhaC) catalyzes the polymerization of PHA in bacterial cells, followed by a chain transfer (CT) reaction in which the PHA polymer chain is transferred from PhaC to a CT agent. Accordingly, the frequency of CT reaction determines PHA molecular weight. Prev…
The syntheses, crystal structures, and characterizations of a series of monovalent metal gold(III) iodates, namely, α-NaAu(IO3)4, β-NaAu(IO3)4, RbAu(IO3)4, α-CsAu(IO3)4, β-CsAu(IO3)4, and AgAu(IO3)4 are reported. Their structures feature Au(IO3)4(-) anions that are separated by alkali metal ions or silver(I) ions. The…
This work covers different aspects of additive manufacturing of Nitinol parts. Firstly, requirements for the powder material and guidelines for the powder preparation are described in detail because the use of proper powder is essential for additive processing of high quality parts. Next, this work presents examples f…
In this communication, we report details of structural, magnetic, and dielectric properties of multiferroic Bi7Fe3Ti3O21 at cryogenic temperatures. The low temperature impedance spectroscopic studies showed a relaxor-like dielectric anomaly which follows Vogel-Fulcher relation with freezing temperature (TVF) of 33 K.…
We demonstrate a new device that combines a light-field effect and an electrical-gate effect to control the drain current in a dual-gate transistor. We used two organic layers, photochromic spiropyran (SP)-doped poly(triarylamine) (PTAA) and pristine PTAA, as top and bottom channels, respectively, connected to common…
Nitinol has the best shape memory and superelasticity properties of all known polycrystalline shape memory alloys (SMAs) due to diffusionless Martensitic transformation. Due to these unique properties, Nitinol is increasingly used in different fields such as biomedical, structural and aerospace engineering. However, u…
We have studied the contact network properties of two- and three-dimensional polydisperse, frictionless sphere packings at the random closed packing density through simulations. We observe universal correlations between particle size and contact number that are independent of the polydispersity of the packing. This al…
In this article we present the feasibility of using the shape memory alloy (SMA) wires, namely Nitinol, as an actuator for a steerable surgical cannula. A 3D finite element (FE) model of the actuated steerable cannula was then developed in ANSYS to show deflection of the surgical cannula under the actuation force. The…
Structural, elastic, electronic and optical properties as well as chemical bonding of the binary alkali metal selenides M 2 Se ( M = Li , Na , K , Rb ) were calculated using the full potential linearized augmented plane method. From the elastic constants it is inferred that these compounds are brittle in nature. The r…