Materials Literature
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Shape memory cyclomatrix network polymers comprising oxazolidone and triazine groups linked by a shape memory segment of polycaprolactone are synthesised by co-reacting a cyanate ester with an epoxy monomer in the presence of a polycaprolactone diol (PCLD). These systems possess transition temperatures (Ttrans) betwee…
We present experimental and theoretical studies of the magneto-optical properties of $p$-type In${}_{1\ensuremath{-}x}$Mn${}_{x}$As and In${}_{1\ensuremath{-}x}$Mn${}_{x}$Sb ferromagnetic semiconductor films in ultrahigh magnetic fields oriented along [001]. Samples were fabricated by molecular beam epitaxy (MBE) and…
Bacterial cellulose is a highly hydrated pellicle made up of a random assembly of ribbon shaped fibers less than 5 nm wide. The unique properties provided by the nanometric structure have led to a number of diagnostic biological probes, display devices due to their unique size-dependent medical applications. Bacterial…
Abstract We present herein a short tripeptide sequence (Lys–Phe–Gly or KFG) that is situated in the juxtamembrane region of the tyrosine kinase nerve growth factor (Trk NGF) receptors. KFG self‐assembles in water and shows a reversible and concentration‐dependent switching of nanostructures from nanospheres (vesicles)…
Abstract An organotin‐substituted Dawson‐type phosphotungstate was covalently linked to a trithiocarbonate group by postfunctionalization methods. This organopolyoxometalate led to a series of polyoxometalate (POM)–poly( N , N ‐diethylacrylamide) hybrids in a controlled way through reversible addition–fragmentation ch…
Through extreme flow-induced fusion and rupturing of microscale droplets within a mixture of two or more oil-in-water emulsions, each having a different type of mutually immiscible oil, we create complex oil-in-water nanoemulsions composed of multicomponent compartmentalized nanodroplets. The extreme flow temporarily…
Nanotransfer printing is used to fabricate large-area visible 3D negative index metamaterials. Material growth aspects of nanotransfer printing are explored for multilayered metamaterials, and alternative dielectrics and deposition conditions are introduced that enabled nearly ideal geometries with excellent optical p…
, respectively. These values are very low when compared to the previous reports, making this system very promising. The cytotoxicity assay showed that these silver nanoparticles are safe for mammalian cells at the studied concentrations.
The alignment of carbon nanotubes (CNT) is the fundamental requirement to ensure their excellent functions but seems to be desolated in recent years. A facile method, hot-press combined with peel-off (HPPO), is introduced here, through which CNT can be successfully vertically aligned on the polymeric membrane substrat…
A near ultraviolet excitable phosphor based on Sm3+-doped YAl3(BO3)4 has been synthesized by modified solid-state reaction at 1000°C. The phase purity and photoluminescence (PL) behavior of the phosphor are studied in detail using the powder X-ray diffraction technique and PL measurements. X-ray diffraction reveals th…
The effect of excess Ba concentration on the dielectric nonlinearity was investigated in Mn and V-doped BaTiO3 multi layer ceramic capacitors (MLCC) under the same grain size condition, which was described by the Preisach model utilizing the first order reversal curve (FORC) distribution. The high-field dielectric con…
This work investigates the mechanical behavior of a clamped-clamped microbeam modeled within the framework of the strain-gradient elasticity theory. The governing equation of motion gives proper account of both the effect of the nonlinear midplane stretching and of an applied axial load. An electric-voltage difference…
For the first time, the adsorption of xyloglucan (XG) on chitin nanocrystals (ChiNC) surface was proved using quartz crystal microbalance with dissipation (QCM-D) and by successfully building up spin-coated assisted layer-by-layer (LbL) structures on solid substrates. Several parameters in the adsorption process, such…
N-(Pyridin-2-yl-carbamothioyl)benzamide (PCMB) was newly synthesized and tested as a corrosion inhibitor for C-steel in 0.5 M H2SO4 using chemical and electrochemical techniques. Polarization measurements showed that the synthesized compound acted as a mixed inhibitor. The inhibition efficiencies obtained from the dif…
Tenacissoside C, a natural bioactive compound of C21 steroidal saponins, was isolated and purified from air-dried stems of Marsdenia tenacissima. In the present study, the MTT assay showed that tenacissoside C exhibited obvious cytotoxicity in K562 cells with IC50 values of 31.4, 22.2, and 15.1 µM for 24, 48, and 72 h…
The multiple melting behavior of poly(butylene succinate) (PBSu) nanocomposites containing silica nanotubes (SiNTs) and strontium hydroxyapatite nanorods (SrHNRs) was studied with Step Scan DSC. In the reversing signal curves, recrystallization proved to be significant for samples crystallized at low temperature, whic…
A visualization study on flow condensation in hydrophobic rectangular silicon microchannels with hydraulic diameter of approximately 150 μm is conducted. Thin Au film with thickness of 200 nm is sputtered on channel surfaces to create a hydrophobic surface with an equilibrium contact angle of approximately 96°. In add…
A family of three new mononuclear complexes of the general form [Fe(L(pz))2(NCE)2] has been prepared (L(pz) = 4-p-tolyl-3-(2-pyrazinyl)-5-(2-pyridyl)-1,2,4-triazole; E = S, Se, BH3). All three exhibit spin crossover, in two cases with hysteresis, with T1/2 being predictably tuned by varying the coordinated anion.
The segmental motions of flexible chains in the lamellar structure of a strongly segregated poly(styrene)-poly(dimethylsiloxane) (PS-PDMS) diblock were investigated over a time scale of a few tens of microseconds. (2)H NMR experiments were performed on the PDMS block, selectively perdeuterated. Transverse relaxation m…
Polycarboxybetaine and poly(ethylene glycol) materials resist nonspecific protein adsorption but differ in influencing biological functions such as enzymatic activity. To investigate this difference, we studied the influence of carboxybetaine and oligo(ethylene glycol) moieties on hydrophobic interactions using molecu…