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The chemical physics of unconventional superconductivity

Sumitendra Mazumdar、R. Torsten Clay2014-02-20International Journal of Quantum Chemistry

Attempts to explain correlated‐electron superconductivity (SC) have largely focused on the proximity of the superconducting state to antiferromagnetism. Yet, there exist many correlated‐electron systems that exhibit insulator‐superconducting transitions where the insulating state exhibits spatial broken symmetry diffe…

Physics of Superconductivity and MagnetismOrganic and Molecular Conductors ResearchIron-based superconductors research

In-situ scanning electron microscope observation of electromigration-induced void growth in 30 nm ½ pitch Cu interconnect structures

Kris Vanstreels、P. Czarnecki、Tomoyuki Kirimura 等 8 位作者2014-02-20Journal of Applied Physics

In-situ electromigration tests have been performed inside a scanning electron microscope on 30 nm wide single damascene interconnects without vias, where a good resolution was obtained and drift velocities during void growth could be measured at 300 °C. These tests showed direct evidence that the cathode end of the li…

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

Gradient magnetic binary alloy nanowire

Min Zeng、Haozhe Yang、Jue Liu 等 4 位作者2014-02-20Journal of Applied Physics

CoNi gradient binary-alloy nanowires are prepared in porous anodic aluminum oxide (AAO) template via electrodeposition. The coercivity and remanence of the nanowires are of high anisotropy due to the axial deposition of the magnetic compositions. The magnetocrystalline anisotropy and crystalline structure of the nanow…

Magnetic properties of thin filmsAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Inhibiting Effect of Nicotinic Acid Hydrazide on Corrosion of Aluminum and Mild Steel in Acidic Medium

J. Ishwara Bhat、Vijaya D. P. Alva2014-02-20Journal of the Korean Chemical Society

The corrosion behavior of aluminum and mild steel in hydrochloric acid medium was studied using a nicotinic acid hydrazide as inhibitor by potentiodynamic polarization, electrochemical impedance spectroscopy technique and gravimetric methods. The effects of inhibitor concentration and temperature were investigated. Th…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Amphiphilic Inclusion Spaces for Various Guests and Regulation of Fluorescence Intensity of 1,8‐Bis(4‐aminophenyl)anthracene Crystals

Misa Sugino、Keisuke Hatanaka、Yusuke Araki 等 6 位作者2014-02-20Chemistry - A European Journal

A host framework for inclusion of various guest molecules was investigated by preparation of inclusion crystals of 1,8-bis(4-aminophenyl)anthracene (1,8-BAPA) with organic solvents. X-ray crystallographic analysis revealed construction of the same inclusion space incorporating 1,8-BAPA and eight guest molecules includ…

Molecular Sensors and Ion DetectionCrystallography and molecular interactionsLuminescence and Fluorescent Materials

Compatibilization of polyamide 6/poly(2,6-dimethyl-1,4-phenylene oxide) blends by poly(styrene-co-maleic anhydride)

Zhenghong Guo、Yu Shen、Zhengping Fang2014-02-20Journal of Polymer Engineering

Abstract The properties of polyamide 6 (PA6)/poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) blends (60/40, wt%) compatibilized by poly(styrene-co-maleic anhydride) (SMA) were studied. The addition of SMA can form an in situ copolymer, SMA- graft -PA6. The SMA- graft -PA6 copolymer actually plays a key role as a compatib…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Strategy of tailoring the interface between multiwalled carbon nanotube and fluoroelastomer

Xiaoyu Meng、Xu Liu、Chuanbo Cong 等 4 位作者2014-02-20Polymer Composites

To fabricate multiwalled carbon nanotubes (MWCNTs)/tetrafluoroethylene‐propylene elastomer (TFEP) nanocomposite, the surface architecture of MWCNTs was tailored based on TFEP molecular structure. Silane coupling agent (SC) and fluorocarbon surfactant (FC) were separately used to improve the interaction and compatibili…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesTribology and Wear Analysis

Electronic and magnetic properties of boron nitride nanoribbons with square–octagon (4 | 8) line defects

Yang Han、Rui Li、Jian Zhou 等 5 位作者2014-02-20Nanotechnology

The electronic and magnetic properties of boron nitride nanoribbons (BNNRs) with square-octagon (4 | 8) line defects (LD-(4 | 8)), parallel to their edges, have been investigated by first-principles calculations. It is found that the zigzag type LD-(4 | 8) BNNR with boron terminated edges is an antiferromagnetic (AFM'…

Graphene research and applications2D Materials and ApplicationsBoron and Carbon Nanomaterials Research

Synthesis of protein‐assisted aqueous Ag 2 S quantum dots in the bovine serum albumin solution

Xia Chen、Ling Ding、Peng Liu 等 4 位作者2014-02-20Surface and Interface Analysis

A one‐step method was developed for preparing Ag 2 S quantum dots (QDs) using a common protein [bovine serum albumin (BSA)] to entrap QDs precursors (BSA–Ag + ). Fluorescence (FL) and ultraviolet spectra showed that the molar ratio of Ag + /BSA, temperature, and pH are the crucial factors for the quality of QDs. The Q…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Preparation of supramolecular corrosion inhibitor based on hydroxypropyl-β-cyclodextrin/octadecylamine and its anti-corrosion properties in the simulated condensate water

Baomin Fan、Gang Wei、Zhan Zhang 等 4 位作者2014-02-20Anti-Corrosion Methods and Materials

Purpose – This work was focused upon the main factors that influence the formation of a hydroxypropyl-β-cyclodextrin (HP-β-CD) supramolecular complex with octadecylamine (ODA) and their optimal processing conditions. The anti-corrosion properties of the products in the simulated boiler water condensate of power plants…

Corrosion Behavior and InhibitionSurfactants and Colloidal SystemsCrystallization and Solubility Studies

Anisotropic lateral growth of homoepitaxial diamond (111) films by plasma-enhanced chemical vapor deposition

Norio Tokuda、Masahiko Ogura、Satoshi Yamsaki 等 4 位作者2014-02-20Japanese Journal of Applied Physics

Anisotropic growth is observed for homoepitaxial diamond (111) films by microwave plasma-enhanced chemical vapor deposition in the lateral growth mode. Using ex situ atomic force microscopy, we clearly show the motion of single bi-atomic layer steps owing to homoepitaxial diamond growth for the first time. An atomisti…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Fluoroethylene Carbonate Addition Effect on Electrochemical Properties of Mixed Carbonate-based Organic Electrolyte Solution for a Capacitor

Min‐Gyeong Kim、Ick-Jun Kim、Sunhye Yang 等 4 位作者2014-02-20Bulletin of the Korean Chemical Society

In this paper, organic solvent electrolytes were prepared by a mixture of propylene carbonate (PC), dimethyl carbonate (DMC), tetraethylammonium tetrafluoroborate (<TEX>$TEABF_4$</TEX>)s to evaluate the ionic properties of propylene carbonate (PC)/dimethyl carbonate (DMC) mixtures as solvents for a capacitor applicati…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Poly (vinyl alcohol) Microspheres Sandwiched Poly (3-hydroxybutyric acid) Electrospun Fibrous Scaffold for Tissue Engineering and Drug Delivery

Naveen Nagiah、Giriprasath Ramanathan、Liji Sobhana 等 5 位作者2014-02-20International Journal of Polymeric Materials

Three drug delivery systems viz. doxycycline hyclate entrapped poly (vinyl alcohol) (PVA) microspheres (DM), composite fibers of doxycycline hyclatepoly (3-hydroxybutyric acid) (PHB) electrospun fibers (DF), and doxycycline hyclateloaded poly (vinyl alcohol) (PVA) microspheres sandwiched between composite fibers consi…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Selective Suspension of Single-Walled Carbon Nanotubes Using β-Sheet Polypeptides

Nicole M. B. Cogan、Charles J. Bowerman、Lisa J. Nogaj 等 5 位作者2014-02-20The Journal of Physical Chemistry C

Individual single-walled carbon nanotubes (SWNTs) were suspended in water using amphipathic β-sheet peptides of the general sequence Ac-(XKXE) 2 -NH 2 . By substituting natural and nonnatural amino acids of varying aromatic and hydrophobic character in the X position, the interactions between the peptide and the nanot…

Carbon Nanotubes in CompositesSupramolecular Self-Assembly in MaterialsOrigins and Evolution of Life

Microstructure and corrosion resistance of as cast Mg–Nd–Gd–Sr–Zn–Zr alloys for biomedical applications

Xiaobo Zhang、Xian He、Y. J. Xue 等 5 位作者2014-02-20Materials Technology

Mg–(4–x)Nd–xGd–0·3Sr–0·2Zn–0·4Zr (wt-%, x = 0, 1, 2 and 3) alloys were prepared by gravity casting. Microstructure was analysed by X-ray diffraction, optical microscopy and scanning electron microscopy respectively. The α-Mg and Mg41Nd5 phases existed in the as cast alloys with 4% and 3% Nd addition, while the new Mg3…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesHydrogen Storage and Materials

The structural basis of an NADP+-independent dithiol oxidase in FK228 biosynthesis

Jie Li、Cheng Wang、Zhimin Zhang 等 5 位作者2014-02-20Scientific Reports

The disulfide bond is unusual in natural products and critical for thermal stability, cell permeability and bioactivity. DepH from Chromobacterium violaceum No. 968 is an FAD-dependent enzyme responsible for catalyzing the disulfide bond formation of FK228, an anticancer prodrug approved for the treatment of cutaneous…

Enzyme Structure and FunctionRedox biology and oxidative stressCancer Research and Treatments

Effect of pore-level geometry on far-field radiative properties of three-dimensionally ordered macroporous ceria particle

Jaona Randrianalisoa、Wojciech Lipiński2014-02-20Applied Optics

The effects of pore size on direction-averaged radiative properties of three-dimensionally ordered macroporous (3DOM) cerium dioxide (ceria) particles are investigated in the spectral range of 0.3-10 μm. The particles are of spherical shape and contain interconnected pores in a face-centered cubic lattice arrangement.…

Atmospheric chemistry and aerosolsCatalytic Processes in Materials ScienceRadiative Heat Transfer Studies

Origins of the two simultaneous mechanisms causing glass transition temperature reductions in high molecular weight freestanding polymer films

D. Prevosto、S. Capaccioli、K. L. Ngai2014-02-20The Journal of Chemical Physics

From ellipsometry measurements, Pye and Roth [Phys. Rev. Lett. 107, 235701 (2011)] presented evidence of the presence of two glass transitions originating from two distinctly different and simultaneous mechanisms to reduce the glass transition temperature within freestanding polystyrene films with thickness less than…

Polymer crystallization and propertiesPhase Equilibria and ThermodynamicsMaterial Dynamics and Properties

Method To Incorporate Anisotropic Semiconductor Nanocrystals of All Shapes in an Ultrathin and Uniform Silica Shell

Eline M. Hutter、Francesca Pietra、Relinde J. A. van Dijk - Moes 等 7 位作者2014-02-20Chemistry of Materials

In this work, we present a method for the incorporation of anisotropic colloidal nanocrystals of many different shapes in silica in a highly controlled way. This method yields a uniform silica shell, with thickness tunable from 3 to 17 nm. The silica shell perfectly adapts to the shape of the nanocrystals, preserving…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films