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Structural Arrangements of Isomorphic Substitutions in Smectites: Molecular Simulation of the Swelling Properties, Interlayer Structure, and Dynamics of Hydrated Cs–Montmorillonite Revisited with New Clay Models

Brice F. Ngouana W.、Andrey G. Kalinichev2014-05-28The Journal of Physical Chemistry C

Three new structural models of montmorillonite with differently distributed Al/Si and Mg/Al substitutions in the tetrahedral and octahedral clay layers are systematically developed and studied by means of MD simulations to quantify the possible effects of such substitutional disorder on the swelling behavior, the inte…

Soil and Unsaturated FlowGroundwater flow and contamination studiesClay minerals and soil interactions

Thermal Expansion of HfO 2 and ZrO 2

R. Haggerty、Pankaj Sarin、Zlatomir D. Apostolov 等 5 位作者2014-05-28Journal of the American Ceramic Society

The thermal expansion of a low symmetry crystal can be much more interesting than the lattice parameter expansion would suggest. Here, the complete thermal expansion tensors for monoclinic and tetragonal phases of ZrO 2 and HfO 2 have been measured in air, by high‐resolution, high‐temperature X ‐ray diffraction. These…

Ferroelectric and Piezoelectric MaterialsHigh-pressure geophysics and materialsThermal Expansion and Ionic Conductivity

Luminescence thermometry below room temperature via up-conversion emission of Y2O3:Yb3+,Er3+ nanophosphors

Vesna Lojpur、G. Nikolić、Miroslav D. Dramićanin2014-05-28Journal of Applied Physics

This study explores potential of Er3+-Yb3+ doped phosphors for up-conversion luminescence thermometry in the temperature range from 10 K to 300 K. Yttrium oxide nanopowder doped with trivalent ytterbium and erbium ions (Y1.97Yb0.02Er0.01O3) was prepared by hydrothermal synthesis as an example. The intensity ratios of…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsSolid State Laser Technologies

Heterostructures Produced from Nanosheet-Based Inks

F. Withers、H. Yang、L. Britnell 等 16 位作者2014-05-28Nano Letters

The new paradigm of heterostructures based on two-dimensional (2D) atomic crystals has already led to the observation of exciting physical phenomena and creation of novel devices. The possibility of combining layers of different 2D materials in one stack allows unprecedented control over the electronic and optical pro…

Graphene research and applications2D Materials and ApplicationsSurface Chemistry and Catalysis

Comparison of Gold Nanoparticle Mediated Photoporation: Vapor Nanobubbles Outperform Direct Heating for Delivering Macromolecules in Live Cells

Ranhua Xiong、Koen Raemdonck、Karen Peynshaert 等 9 位作者2014-05-28ACS Nano

There is a great interest in delivering macromolecular agents into living cells for therapeutic purposes, such as siRNA for gene silencing. Although substantial effort has gone into designing nonviral nanocarriers for delivering macromolecules into cells, translocation of the therapeutic molecules from the endosomes a…

Gold and Silver Nanoparticles Synthesis and ApplicationsElectrohydrodynamics and Fluid DynamicsLaser-Ablation Synthesis of Nanoparticles

Synthesis of nickel nanoparticles by chemical and green route and their comparison in respect to biological effect and toxicity

S. Sudhasree、Afreen Banu、P. Brindha 等 4 位作者2014-05-28Toxicological & Environmental Chemistry Reviews

Recent reports demonstrated an increase in the synthesis of nanoparticles (NP) and its applications. The chemical preparation of NP may be harmful. Thus, in this study, the biological activity and toxicology of nickel nanoparticles (NiNP) synthesized through chemical and green routes were compared. Chemical synthesis…

Nanoparticles: synthesis and applications

Engineered Nanomaterials in Food: Implications for Food Safety and Consumer Health

Alina Martirosyan、Yves-Jacques Schneider2014-05-28International Journal of Environmental Research and Public Health

From the current state-of-the-art, it is clear that nanotechnology applications are expected to bring a range of benefits to the food sector aiming at providing better quality and conservation. In the meantime, a growing number of studies indicate that the exposure to certain engineered nanomaterials (ENMs) has a pote…

Nanoparticles: synthesis and applicationsHeavy Metal Exposure and Toxicity

Electrochemical Quartz Crystal Microbalance (EQCM) Study of Ion Dynamics in Nanoporous Carbons

Wan‐Yu Tsai、Pierre‐Louis Taberna、Patrice Simon2014-05-28OpenAlex

Electrochemical quartz crystal microbalance (EQCM) and cyclic voltammetry (CV) measurements were used to characterize ion adsorption in carbide-derived carbon (CDC) with two different average pore sizes (1 and 0.65 nm), from neat and solvated 1-Ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMI-TFSI) el…

Supercapacitor Materials and FabricationFuel Cells and Related MaterialsConducting polymers and applications

Photoinduced Superwetting Single-Walled Carbon Nanotube/TiO2 Ultrathin Network Films for Ultrafast Separation of Oil-in-Water Emulsions

Shoujian Gao、Zhun Shi、Wen Bin Zhang 等 5 位作者2014-05-28OpenAlex

A SWCNT/TiO2 nanocomposite ultrathin film that has superhydrophilic and underwater superoleophobic properties after UV-light irradiation is successfully prepared by coating TiO2 via the sol-gel process onto an SWCNT ultrathin network film. The robust and flexible SWCNT/TiO2 nanocomposite films with a thickness and por…

Membrane Separation TechnologiesSurface Modification and SuperhydrophobicityElectrohydrodynamics and Fluid Dynamics

REXS 2013 – Workshop on Resonant Elastic X-ray Scattering in Condensed Matter

Guillaume Beutier、C. Mazzoli、F. Yakhou 等 6 位作者2014-05-27Journal of Physics Conference Series

The aim of this workshop was to bring together experts in experimental and theoretical aspects of resonant elastic x-ray scattering, along with researchers who are new to the field, to discuss important recent results and the fundamentals of the technique. The meeting was a great success, with the first day dedicated…

Advanced X-ray Imaging TechniquesX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena

The wingspan of mathematical crystallography

M. Nespolo、Gregory L. McColm2014-05-27Acta Crystallographica Section A Foundations and Advances

The resurgence in mathematical crystallography motivated the formation of the IUCr Commission on Mathematical Crystallography, as well as this virtual special issue of Acta Crystallographica Section A . This foreword describes some of the current activities of the Commission and introduces the articles in the special…

Crystallization and Solubility StudiesQuasicrystal Structures and PropertiesX-ray Diffraction in Crystallography

Tannic acid-modified fatty amide anticorrosive coatings from Pongamia glabra oil

Manawwer Alam、Naser M. Alandis2014-05-27Anti-Corrosion Methods and Materials

Purpose – The purpose of this investigation was to develop sustainable resource-based anticorrosive coating material using Pongamia glabra seed oil and tannic acid (TA), as well as to improve the coating properties. Design/methodology/approach – TA-modified fatty amide diol was synthesized by condensation polymerizati…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingEpoxy Resin Curing Processes

Molecular dynamics simulation of Cr-precipitate demixing in FeCr alloys

Panagiotis Grammatikopoulos、K. Nordlund2014-05-27Radiation effects and defects in solids

The mechanical properties of FeCr alloys rely heavily on atomic distribution and can be affected by phenomena such as Cr precipitation. While precipitation of FeCr alloys of various Cr concentrations has been studied before, dissolution of already existing Cr precipitates in FeCr alloys has not; this was the focus of…

Microstructure and Mechanical Properties of SteelsFusion materials and technologiesNuclear Materials and Properties

Magnetic phase diagram and ordered ground state of GdMn2O5multiferroic studied by x-ray magnetic scattering

C. Vecchini、A. Bombardi、L. C. Chapon 等 6 位作者2014-05-27Journal of Physics Conference Series

The magnetic structure of multiferroic GdMn2O5 is studied by x-ray magnetic scattering, both off resonance and in resonant conditions at the Gd L III edge. Temperature dependence of magnetic Bragg reflections shows an initial incommensurate (ICM) ordering appearing at T~40K with magnetic propagation vector k ICM ~(0.4…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Low-temperature Synthesis of (K0.5Na0.5)NbO3 Nanopowders by an Urea Sol–Gel Combustion Method

Nguyễn Đức Văn、Đào Ngọc Nhiệm2014-05-27Chemistry Letters

Abstract Lead-free piezoelectric (K0.5Na0.5)NbO3 nanopowders were synthesized by urea sol–gel combustion method using freshly prepared Nb2O5·nH2O and alkali hydroxides as starting materials and urea as a fuel. The effects of metal cation/urea molar ratio and calcination temperature on the crystalline phase formation o…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Electric-field modulation of liquid crystal structures in contact with structured surfactant monolayers

Pau Guillamat、Francesc Sagués、Jordi Ignés‐Mullol2014-05-27Physical Review E

We present experiments in which we use an electric field to switch between different configurations in the cellular patterns induced in a confined nematic liquid crystal by the contact with a surfactant monolayer that features lateral order and surface defects. By using different combinations of far-field alignment an…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPlant Reproductive Biology

Thermomechanical behavior, light and X-ray scattering of polylactic acid

A. Reyes-Mayer、Angel Romo‐Uribe2014-05-27Emerging Materials Research

This research focuses on the thermal properties, microstructure and mechanical behavior of extruded films of biodegradable polylactic acid (PLA) and compares these properties with those from polyethylene, high density and linear low density. Thermal properties showed poorer thermal stability of PLA (some 100°C lower t…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Synthesis of chiral porphyrins and their use in photochemical oxidation of carbonyl compounds

Dominika J. Walaszek、Ksenia Maximova、Katarzyna Rybicka‐Jasińska 等 5 位作者2014-05-27Journal of Porphyrins and Phthalocyanines

A series of chiral A 4 , A 2 B 2 , and AB 3 porphyrins bearing proline moieties at the meso-phenyl group has been synthesized. Photostability studies revealed that the number of L-proline units and their position on meso-phenyl rings strongly influence the decomposition rate of the catalyst. 5,10,15-Tris(mesityl)-20-(…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesLuminescence and Fluorescent Materials

Synthesis and thermal stability of polystyrene and poly(vinyl chloride) coated with polythiophene and modified with Fe 2 O 3 nanoparticles

Zoha Vatani、Hossein Eisazadeh2014-05-27Journal of Vinyl and Additive Technology

In this study, polystyrene and poly(vinyl chloride) particles were coated successfully with polythiophene in aqueous media. These nanocomposites were prepared in situ by polymerization of thiophene in the presence of FeCl 3 as an oxidant and poly(vinyl pyrrolidone) as a surfactant. The effect of Fe 2 O 3 nanoparticles…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsSynthesis and properties of polymers

Current induced abnormal electroresistance effect observed in epitaxial La0.9Hf0.1MnO3 thin films

Jie Xing、Ju Gao、Le Wang2014-05-27Journal of Applied Physics

La0.9Hf0.1MnO3 thin films with thickness 100 nm were prepared by using a pulsed laser deposition technique. Transport behaviors were investigated under various applied currents without an applied magnetic field. When the applied current is not too large, the peak value of the resistance gradually decreases with increa…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides