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On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow

Hannes Alex、Norbert Steinfeldt、Klaus Jähnisch 等 5 位作者2013-04-29Nanotechnology Reviews

Abstract Nanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of be…

Catalytic Processes in Materials ScienceOxidative Organic Chemistry ReactionsNanomaterials for catalytic reactions

Expression, purification, crystallization and preliminary X-ray diffraction analysis of a core fragment of FlgG, a bacterial flagellar rod protein

Yumiko Saijo‐Hamano、H. Matsunami、Keiichi Namba 等 4 位作者2013-04-29Acta Crystallographica Section F Structural Biology and Crystallization Communications

FlgG is a bacterial flagellar rod protein and constructs the distal rod connecting to the hook. FlgG of Salmonella enterica serovar Typhimurium is a 260-amino-acid protein composed of a folded core region and N- and C-terminal regions that are unfolded in solution. A core fragment of FlgG (FlgG47-227) was expressed, p…

Photosynthetic Processes and MechanismsEnzyme Structure and FunctionPorphyrin Metabolism and Disorders

Monolayer Solids of Kr on Graphitized Carbon Black Surfaces and in Graphitic Hexagonal Pores

Kunimitsu Morishige2013-04-29The Journal of Physical Chemistry C

To examine the effects of the inherent heterogeneity in graphitic hexagonal pores on Kr adsorption in the monolayer (ML) regime, we measured the powder X-ray diffraction (XRD) patterns of Kr adsorbed on the walls of the graphitic hexagonal pores, as well as the flat surfaces of graphitized carbon black, as a function…

Graphene research and applicationsZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

A Novel S i 3 N 4 – S i C Ceramic Used for Volumetric Receivers

Jianfeng Wu、Meng Liu、Guowei Zhou 等 5 位作者2013-04-29International Journal of Applied Ceramic Technology

S i 3 N 4 – S i C composite ceramics used for volumetric receivers were fabricated by pressureless sintering of micrometer S i C , S i 3 N 4 , andalusite, and other minor additions powders. Mechanical, thermal expansion, thermal conductivity, and thermal shock resistance properties were tested at different sintering t…

Advanced ceramic materials synthesisThermal properties of materialsMicrowave Dielectric Ceramics Synthesis

The influence of additive content on microstructure and mechanical properties on the Csf/SiC composites after annealed treatment

Zhang yunlong、Ming Hu、Xiangge Qin 等 4 位作者2013-04-29Applied Surface Science

In this paper, micrometers long and 20–100 nm diameter SiC nanowires had been synthesized in the short cut fiber toughened SiC composites (Csf/SiC) by annealing treatment. The present work demonstrated that it was possible to fabricate the in situ SiC nanowires toughened Csf/SiC composites by annealed treatment. The “…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesBoron and Carbon Nanomaterials Research

New Method of Synthesizing Aluminum Oxynitride Spinel Powders

Guozhi Ruan、Hai‐Sen Xu、Zhihui Zhang 等 6 位作者2013-04-29Journal of the American Ceramic Society

Aluminum oxynitride spinel ( AlON ) powders were synthesized by aluminothermic reaction in a reducing N 2 ‐ CO atmosphere. Low cost and easily available aluminum and γ‐ Al 2 O 3 alumina micrometer‐sized powders were employed as starting materials. Mixed powders consisting of 75 wt% Al and 25 wt% Al 2 O 3 were milled t…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

Construction of a functional silk‐based biomaterial complex with immortalized chondrocytes in vivo

Yusu Ni、Yi Jiang、Jianchuan Wen 等 8 位作者2013-04-29Journal of Biomedical Materials Research Part A

To explore the feasibility of constructing a functional biomaterial complex with regenerated silk fibroin membrane and immortalized chondrocytes in vivo. Rat auricular chondrocytes (RACs) were transfected with the lentivirus vector pGC-FU-hTERT-3FLAG or pGC-FU-GFP-3FLAG, encoding the human telomerase reverse transcrip…

RNA Interference and Gene DeliveryAntimicrobial Peptides and ActivitiesSilk-based biomaterials and applications

Surface force arising from adsorbed graphene oxide in alumina suspensions with different shape and size

Hazlina Husin、Yee‐Kwong Leong、Jishan Liu 等 5 位作者2013-04-29AIChE Journal

The effects of graphene oxide (GO) on the yield stress‐pH of α‐Al 2 O 3 (alumina) suspensions were investigated. For micron‐sized platelet alumina suspensions, micron‐sized GO additive increased the maximum yield stress by as much as six‐folds. This was attributed to GO‐mediated bridging interactions between the plate…

Graphene research and applicationsNanopore and Nanochannel Transport StudiesElectrostatics and Colloid Interactions

Macroscale Plasmonic Substrates for Highly Sensitive Surface‐Enhanced Raman Scattering

María D. Alba、Nicolás Pazos‐Pérez、Belén Vaz 等 14 位作者2013-04-29Angewandte Chemie

Moderne Weltwunder: Nanostrukturierte Filme aus plasmonischen Pyramiden-Arrays (siehe Bild) wurden durch einfaches Aufstempeln von vorgefertigten homogenen Nanokolloiden erzeugt. Die Materialien wirken als effiziente optische Verstärker und können für die Konstruktion quantitativer, billiger, tragbarer, ultraempfindli…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Dynamic transitions in molecular dynamics simulations of supercooled silicon

Xiaojun Mei、Jacob Eapen2013-04-29Physical Review B

Two dynamic transitions or crossovers, one at a low temperature (T${}^{*}$ \ensuremath{\approx} 1006 K) and the other at a high temperature (T${}^{0}$ \ensuremath{\approx} 1384 K), are shown to emerge in supercooled liquid silicon using molecular dynamics simulations. The high-temperature transition (T${}^{0}$) marks…

Geological and Geochemical AnalysisMaterial Dynamics and PropertiesTheoretical and Computational Physics

One-, Two-, and Three-Dimensional Hopping Dynamics

Keiko M. Aoki、Susumu Fujiwara、Kiyoshi Sogo 等 5 位作者2013-04-29Crystals

Hopping dynamics in glass has been known for quite a long time. In contrast, hopping dynamics in smectic-A (SmA) and hexatic smectic-B (HexB) liquid crystals (LC) has been observed only recently. The hopping in SmA phase occurs among the smectic layers (one-dimensionally), while hopping in HexB phase occurs inside the…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesPlant and animal studies

Cure behavior and antimicrobial performance of sulfur‐cured natural rubber vulcanizates containing 2‐hydroxypropyl‐3‐piperazinylquinolinecarboxylic acid methacrylate or silver‐substituted zeolite

Kanisorn Jai‐eau、Ekachai Wimolmala、Narongrit Sombatsompop2013-04-29Journal of Vinyl and Additive Technology

This work used 2‐hydroxypropyl‐3‐piperazinylquinolinecarboxylic acid methacrylate (HPQM) or silver‐substituted zeolite (SSZ) as antibacterial agents for natural rubber (NR) compounds vulcanized by conventional vulcanization (CV), semi‐efficient vulcanization, and efficient vulcanization (EV) systems. The cure behavior…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesAntimicrobial agents and applications

Role of strain in interacting silicon nanoclusters

Roberto Guerra、Stefano Ossicini2013-04-29Physical Review B

The possibility of controlling the optical transition probability between neighboring silicon nanoclusters (Si-NCs) constitutes nowadays an attractive prospect in nanophotonics and photovoltaics. In this work, by means of theoretical ab initio calculations, we investigate the effect of strain on the optoelectronic pro…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

Electronic Delocalization in Coordination Polymers Based on Bimetallic Carboxylates

María A. Castro、Adrián E. Roitberg、Fabio D. Cukiernik2013-04-29Journal of Chemical Theory and Computation

Computational methods (DFT at the B3LYP, PBE0 and m06 levels, MO fragments decomposition, and the broken symmetry approach) have been used to evaluate the influence of the bridging ligand (BL) on the extent of electron delocalization in coordination polymers based on diruthenium tetracarboxylates. The efficiency of th…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Investigation on the optical properties of ZnS nano-rod and chiral sculptured thin films using experimental and theoretical approaches

Araz Siabi-Garjan、Hadi Savaloni、Fatemeh Abdi 等 5 位作者2013-04-29Physica Scripta

ZnS thin films with nano-rod and chiral sculptured structures of different thicknesses were deposited on glass substrates. Nano-structure of the films was obtained, using field emission scanning electron microscopy (FESEM). Their optical properties were measured by spectrophotometry in the spectral range of 350–1000 n…

Photonic Crystals and ApplicationsOptical Coatings and GratingsNear-Field Optical Microscopy

Modulated exciton-plasmon interactions in Au-SiO_2-CdTe composite nanoparticles

Li‐Juan Tang、Jinyou Xu、Pengfei Guo 等 8 位作者2013-04-29Optics Express

Well-defined Au-SiO(2)-CdTe composite nanoparticles were synthesized via a multistep chemical approach in water solution to gain insight into the interaction between metal and semiconductor nanostructures. Photoluminescence measurement reveals that the fluorescence of CdTe quantum dots (QDs) in this composite with opt…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Magnetoelectric coupling at the EuO/BaTiO3 interface

Shi Cao、P. Liu、Jinke Tang 等 9 位作者2013-04-29Applied Physics Letters

Magnetization modulation by ferroelectric polarization switching is reported for the ferromagnetic-ferroelectric EuO/BaTiO3 heterostructure. The value of the magnetization critical exponent β is consistent with the expected Heisenberg-like ferromagnetism of EuO and reported Curie temperature. The critical exponent is…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Fabrication of a Poly(3-octylthiophene-2,5-diyl) Electrochemiluminescence Device Assisted by Perylene

Tatsuya Daimon、Eisuke Nihei2013-04-29Materials

In this study, we report the light-emitting assistance effect of perylene on a polymer electrochemiluminescence (ECL) device using poly(3-octylthiophene-2,5-diyl) (P3OT). An ECL device is a liquid type self-luminous device with a simple structure, and can be fabricated by a relatively easy procedure. Significant impro…

Advanced biosensing and bioanalysis techniquesConducting polymers and applicationsAnalytical Chemistry and Sensors

In-plane optical spectroscopy study on FeSe epitaxial thin film grown on SrTiO3substrate

R. H. Yuan、Wei Kong、Lei Yan 等 5 位作者2013-04-29Physical Review B

We perform in-plane optical spectroscopy measurement on (00l) FeSe thin film grown on SrTiO${}_{3}$ substrate by the pulsed laser deposition method. The study indicates that the low-frequency conductivity consists of two Drude components: a broad one which takes up most of the spectral weight and a very narrow one rou…

Corporate Finance and GovernanceCorporate Taxation and AvoidanceIron-based superconductors research

Confinement-Induced Crystal Growth in One-Dimensional Isotactic Polystyrene Nanorod Arrays

Hui Wu、Yan Cao、Ryohei Ishige 等 7 位作者2013-04-29ACS Macro Letters

This work demonstrates the anomalous crystal growth of isotactic polystyrene (iPS) in nanorod arrays with different rod sizes. At the bottom of the nanorods, the crystals in bulk film grow into nanorods along either the [110] or [100] direction parallel to the rod axis. On the top side of the nanorods, the polymer exh…

Polymer crystallization and propertiesBlock Copolymer Self-AssemblyAnodic Oxide Films and Nanostructures