Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInduced optical activity in the terbium(III) complex of pyridine-2,6-dicarboxylic acid through association with resolved tris(ethylenediamine)chromium(III)John S. Madaras and Harry G. BrittainCite this: Inorg. Chem. 1980, 19, 12, 3841–3842Publication Date (Print):December 1,…
SUMMARY The accumulation of clay and organic material, forming argillans and organans, is poorly understood and is at least not a subject of general agreement. Electron scanning and microprobe show striking features. The argillans, having Si, Al and Fe, are clearly layered and seldom cracked. The organans do not conta…
Fluorescence spectra of MgP in triphenylene and phosphorescence spectra of CuP and PdP in triphenylene have been obtained from room temperature down to 10 °K. Analysis of the temperature dependence of the MgP spectra shows that the coupling between the Mg porphin guest and the triphenylene host is weak. A temperature-…
Abstract Die übermolekulare Struktur von Polyethylen niedriger Dichte ist elektronenmikroskopisch an chemisch gehärteten und kontrastierten Ultramikrotom‐Dünnschnitten untersucht worden. Der Innenaufbau der Sphärolithe aus Lamellen und die Eigenstruktur der Lamellen werden beschrieben. Die gefundenen Strukturen werden…
Abstract The gelation level attained in an unplasticized PVC pressure pipe determines the balance in the basic physical properties of strength, stiffness and ductility. In turn, the gelation level attained is dependent upon the processing conditions. Measurement of the gelation level can be used to control both the pr…
Abstract not Available.
Emission and excitation spectra of MgS: Sb 3+ phosphors are measured at various temperatures. In addition to the A , B and C excitation bands peculiar to Tl + -type ions, three bands corresponding to charge transfer transitions are observed. On each excitation band, distinct Jahn-Teller splitting is observed and the p…
The elastic moduli of both gray and nodular cast iron were measured by a pulse-echo elastic-wave technique at ambient and elevated temperatures up to 760°C. When compared at similar graphite contents, the elastic moduli of gray cast iron were much lower than those of nodular cast iron. These results are satisfactorily…
X-ray diffraction data for various materials reveal that naturally occurring microparacrystals cannot exceed a certain limiting size. The empirically obtained linear relationship between the square root of the limiting number of lattice planes within a paracrystal and the reciprocal value of the relative distance fluc…
Discontinuities corresponding to the simultaneous creation of two and possibly three electronic vacancies were observed in the absorption spectra of germanium. They occur at photon energies approximately equal to the energy required for the synchronous removal of two inner electrons. The magnitude of the observed disc…
The anomalous volume contraction ωa(T) of Fe-Ni and Fe-Pt Invar alloys were analyzed in terms of the Grüneisen equation using the experimental data of thermal expansion coefficient. It was found that ωa(T) increases with increasing Fe composition or temperature and remains nonzero even above the Curie point ϑ f for bo…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReactions of protoporphyrin with tetracyanoethyleneRobert K. DiNello and David DolphinCite this: J. Org. Chem. 1980, 45, 25, 5196–5204Publication Date (Print):December 1, 1980Publication History Published online1 May 2002Published inissue 1 December 1980https://doi.org/10.10…
Extended glass‐forming regions were found by twin‐roller quenching in the systems of with and/or . The crystallization of the glasses was studied by DTA and x‐ray analysis; a new metastable crystalline phase was observed for . The glasses exhibited lithium ion conductivities in the 10 −5 –10 −6 (Ω‐cm) −1 range at room…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTemperature-dependent 5T2(Oh) .dblharw. 1A1(Oh) spin equilibrium in a six-coordinate cobalt(III) complex. Investigation by phosphorus-31 NMR in solutionPhilipp Guetlich, Bruce R. McGarvey, and Wolfgang KlaeuiCite this: Inorg. Chem. 1980, 19, 12, 3704–3706Publication Date (Pr…
Abstract The scattering of X-rays from a concentrated Al (NO 3 ) 3 aqueous solution has been measured and analyzed at 25 °C. Good agreement with experimental data is achieved through a model in which Al 3+ (H 2 O) 6 interacts with twelve water molecules through short and linear H-bonds. The water molecules which are t…
The crystal structures of the following metamorphic olivines, M;*[SiO4], in the forsteritetephroite (Fo-Te) series were refned in space group Pbnm:
Summary Electron diffraction and electron-microprobe investigations have revealed the presence of order in the monazite-huttonite series. Chemical analyses from the literature and electron-microprobe analyses in this study show that the monazite-huttonite series, RE PO 4 -ThSiO 4 , is only continuous if the contributi…
It is shown that in the Flory model (1942) of semi-flexible polymer chains, an assumption of random occupation of sites is not valid for estimating the excluded volume effects when the fraction of gauche bonds is small. Thus the model is never completely ordered except presumably at T=0, and the free energy is such th…
Crosslinking of collagen is a prerequisite for the collagen fibers to withstand the physical stresses to which they are exposed. Significant progress has been made in understanding the functional groups on the molecule which are involved in the forma
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTantalum imido complexesS. M. Rocklage and R. R. SchrockCite this: J. Am. Chem. Soc. 1980, 102, 26, 7808–7809Publication Date (Print):December 1, 1980Publication History Published online1 May 2002Published inissue 1 December 1980https://pubs.acs.org/doi/10.1021/ja00546a043ht…