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Determination of Peukert’s Constant Using Impedance Spectroscopy: Application to Supercapacitors

Edmund M. Mills、Sangtae Kim2016-11-30The Journal of Physical Chemistry Letters

Peukert's equation is widely used to model the rate dependence of battery capacity, and has recently attracted attention for application to supercapacitors. Here we present a newly developed method to readily determine Peukert's constant using impedance spectroscopy. Impedance spectroscopy is ideal for this purpose as…

Supercapacitor Materials and FabricationAdvanced Battery Technologies ResearchAdvanced battery technologies research

Coupling template nanocasting and self-activation for fabrication of nanoporous carbon

Lingjun Kong、Mingxiang Liu、Zeng-Hui Diao 等 6 位作者2016-11-30Scientific Reports

Abstract Hierarchical nanoporous carbon (NPC) with great surface area and developed pore size distribution has been intently concerned. Herein, we report a facile method coupling template nanocasting and self-activation to fabricate nanoporous carbon with continuous micro, meso and macro pores, in which CaCO 3 acted a…

Supercapacitor Materials and FabricationCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Polyolefine Composites Reinforced by Rice Husk and Saw Dust

Thi Thu Loan Doan、H. Brodowsky、Edith Mäder2016-11-30InTech eBooks

Due to the global demand for fibrous light-weight materials, research on composites reinforced with plant materials has increased. Natural fiber reinforced composites offer several advantages: light weight, competitive specific mechanical properties, easy processing, large volume availability, low cost, and low enviro…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Influence of main chain on the phase behaviors of side‐chain liquid‐crystalline polymers with triphenylene mesogens of long alkyl tail substituents

Ping Li、Sheng Chen、Hang Luo 等 5 位作者2016-11-30Journal of Polymer Science Part A Polymer Chemistry

ABSTRACT A series of side‐chain liquid‐crystalline polymers (SCLCPs) containing triphenylene mesogen, in which the long alkyl tail Tp connected directly with main chain, were synthesized successfully. The chemical structures of the monomers were confirmed by 1 H NMR and mass spectrometry. The phase behaviors of polyme…

Liquid Crystal Research AdvancementsBlock Copolymer Self-AssemblyAdvanced Materials and Mechanics

High-Content Lignocellulosic Fibers Reinforcing Starch-Based Biodegradable Composites: Properties and Applications

Sherif Mehanny、Lamis R. Darwish、Hamdy Ibrahim 等 5 位作者2016-11-30InTech eBooks

Natural source-based composites became promising substitutes and synthetic petrochemical-based counterparts. So far, thermoplastic starch and lignocellulosic fibers are the most common materials for making such eco-friendly ?green? materials. Low cost, abundance, and renewability are the factors that lead to deploying…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

A superhydrophobic manhole for drops

Dwayne Chung Kim Chung、So Hung Huynh、Shufen Wang 等 7 位作者2016-11-30Journal of Materials Chemistry A

An evaporative pre-concentration method towards environmental monitoring for sustainability working in an energy conserving manner.

Surface Modification and SuperhydrophobicityNanomaterials and Printing TechnologiesElectrohydrodynamics and Fluid Dynamics

Solution and solid state structures and magnetism of a series of linear trinuclear compounds with a hexacoordinate Ln III and two terminal Ni II centers

Peter Comba、Markus Enders、Michael Großhauser 等 6 位作者2016-11-30Dalton Transactions

Reported are the syntheses, structures and magnetic properties, also by NMR spectroscopy in solution, of a series of 13 linear trinuclear 3d–4f compounds with a lanthanide( <sc>iii</sc> ) surrounded by two Ni <sup>II</sup> ions, NiII2Ln <sup>III</sup> , where the central Ln <sup>III</sup> is hexacoordinate.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Production and Characterization of Hybrid Polymer Composites Based on Natural Fibers

Wendy Rodríguez-Castellanos、Denis Rodrigue2016-11-30InTech eBooks

In this chapter, a review is made on the processing and properties of hybrid composites based on a polymer matrix and a blend of different natural (lignocellulosic) fibers. In particular, the processing methods are described and comparisons are made between the general properties with a focus on physical, mechanical a…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Isophase Transitions of Cellulose – A Short Review

Michael Ioelovich2016-11-30Athens Journal of Sciences

Cellulose has a complicated supramolecular structure consisting of nanofibrils, which are built of ordered crystallites and low ordered noncrystalline domains.In this critical review, isophase temperature transitions in noncrystalline domains of cellulose were described and discussed.It has been shown that due to stru…

Advanced Cellulose Research StudiesLignin and Wood ChemistryMaterial Properties and Processing

The unique effect of chain entanglements and particle morphology on the sintering of ultrahigh molecular weight polyethylene

Ramin Hosseinnezhad、Saeid Talebi、Mostafa Rezaei2016-11-30Journal of Elastomers & Plastics

Nascent ultrahigh molecular weight polyethylene (UHMWPE) is a thermoplastic material, consisting of nodular-fibrillar structure making it too much porous. At the present work, the effect of both particle morphology and chain entanglements on the sintering of UHMWPE was investigated. Neck growth for particles of three…

Polymer crystallization and propertiesInjection Molding Process and PropertiesPolymer Foaming and Composites

Barrier-Free Nucleation at Grain-Boundary Triple Junctions During Solid-State Phase Transformations

Huajing Song、J.J. Hoyt2016-11-30Physical Review Letters

Molecular dynamics simulations are used to provide strong evidence for barrier-free nucleation events in a heterogeneous solid-solid system. The barrier-free events are characterized by an absence of an incubation time and a growth rate of the emerging phase that is independent of the system size. Furthermore, an anal…

Microstructure and mechanical propertiesSolidification and crystal growth phenomenananoparticles nucleation surface interactions

Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2

Sangen Zhao、Yi Yang、Yaoguo Shen 等 11 位作者2016-11-30Angewandte Chemie

Abstract Nitrates have long been ignored for practical uses as nonlinear optical (NLO) materials because they are usually very easy to dissolve in water; despite this, the π‐conjugated [NO 3 ] − is among the most desirable NLO‐active structural units. The cooperation of three structural chromophores, namely, Bi 3 O 6…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Measurement and Modeling of Solid–Liquid Equilibrium of para-tert-Butylbenzoic Acid in Acetic Acid/Methanol + Water and Acetic Acid + para-tert-Butyltoluene Binary Systems at Various Temperatures

Alka Kumari、Kadakanchi Sandeepa、Ramesh Tangirala 等 5 位作者2016-11-30Journal of Chemical & Engineering Data

In this work, experimental solubility data of para-tert- butylbenzoic acid in binary solvents of acetic acid + water (293.15 to 333.15) K, methanol + water (293.15 to 328.15) K, and acetic acid + para-tert -butyltoluene (293.15 to 323.15) K were studied over acetic acid/methanol mass fraction, w 2 (on solute free basi…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Investigation on Fluorescence Quenching Mechanism of Perylene Diimide Dyes by Graphene Oxide

Yuzhen Zhao、Kexuan Li、Zemin He 等 7 位作者2016-11-30Molecules

Perylene diimide derivatives were used as probes to investigate the effect of the molecular structures on the fluorescence quenching mechanism in a perylene diimide/graphene oxide system. The electrons transferred from the excited state of dyes to the conductive band of graphene oxide with different concentrations wer…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsLuminescence and Fluorescent Materials

Renewable Biocomposite Properties and their Applications

Thimmapuram Ranjeth Kumar Reddy、Hyun‐Joong Kim、Ji-Won Park2016-11-30InTech eBooks

Recently, with increasing environmental awareness and expanding global waste problems, eco-friendly biofillers have been recognized as a promising alternative to inorganic fillers in the reinforcement of thermoplastic and biodegradable plastics. Therefore, many industries are seeking more eco-friendly materials that w…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

Enhancing the Infrared Response of Carbon Nanotubes From Oligo-Quaterthiophene Interactions

Anouar Belhboub、P. Hermet、Laurent Alvarez 等 11 位作者2016-11-30The Journal of Physical Chemistry C

Infrared response on a carbon nanotube is weak because this homonuclear allotrope of carbon does not bear permanent dipoles. Here, we report the discovery of an exaltation of the infrared absorption response in single-walled carbon nanotubes from dye molecule interactions. A study performed on dimethylquaterthiophene…

Carbon Nanotubes in CompositesFullerene Chemistry and ApplicationsMechanical and Optical Resonators

Rapid Immobilization of Oligonucleotides at High Density on Semiconductor Quantum Dots and Gold Nanoparticles

Abootaleb Sedighi、Ulrich J. Krull2016-11-30Langmuir

Oligonucleotide-coated nanoparticles (NPs) have been used in numerous applications such as bioassays, as intracellular probes, and for drug delivery. One challenge that is confronted in the preparation of oligonucleotide-NP conjugates is derived from surface charge because nanoparticles are often stabilized and made w…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Conversion Process of Amorphous Si-Al-C-O Fiber into Nearly Stoichiometric SiC Polycrystalline Fiber

Ryutaro Usukawa、Hiroshi Oda、Toshihiro Ishikawa2016-11-30Journal of the Korean Ceramic Society

Tyranno SA (SiC-polycrystalline fiber, Ube Industries Ltd.) shows excellent heat-resistance up to 2000 o C with relatively high mechanical strength. This fiber is produced by the conversion process from a raw material (amorphous Si-Al-C-O fiber) into SiCpolycrystalline fiber at very high temperatures over 1500 o C in…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Conversion of biogenic aragonite into hydroxyapatite scaffolds in boiling solutions

Daniel Reinares‐Fisac、S. Veintemillas‐Verdaguer、Lurdes Fernández-Dı́az2016-11-30CrystEngComm

The interaction of Sepia officinalis cuttlefish bone, made of aragonitic CaCO3, with (NH4)2HPO4 boiling solutions produces porous carbonate-bearing hydroxyapatite (Ca10(PO4)6(OH)2) scaffolds with extremely large specific surface area. Percentages of aragonite into hydroxyapatite conversion close to 90% are reached aft…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionBuilding materials and conservation