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n-Butyraldehyde self-condensation catalyzed by Ce-modified γ-Al 2 O 3

Chao Xiong、Ning Liang、Hualiang An 等 5 位作者2015-01-01RSC Advances

Ce–Al <sub>2</sub> O <sub>3</sub> showed an excellent catalytic activity and reusability for the self-condensation of <italic>n</italic> -butyraldehyde to 2-ethylhexanol. The acid–base property of Ce–Al <sub>2</sub> O <sub>3</sub> other than Ce valence state played a dominant role in its catalytic performance.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis for Biomass Conversion

Crystal-surface-induced simultaneous synthesis and hierarchical morphogenesis of conductive polymers

Kento Kuwabara、Yuya Oaki、Ryo Muramatsu 等 4 位作者2015-01-01Chemical Communications

The surface of oxidant crystals facilitates the simultaneous synthesis and morphogenesis of conductive polymer materials. Oxidant crystals as a condensed phase of the oxidative agent induce the formation of the conductive polymer nanoparticles and their accumulated films.

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsPolymer Surface Interaction Studies

Can microwave assisted in situ reduction of supported Pt nanoparticles challenge the chemical method in controlling the dispersion profile-catalytic performance relationship?

Salah A. Hassan、Heba M. Gobara、Mohamed M. Gomaa 等 5 位作者2015-01-01RSC Advances

In this comparative study of dispersion profile-catalytic performance relationships, Pt (of 0.3, 0.6 and 0.9 wt%) was supported on mesoporous silica surface <italic>via</italic> microwave assisted solution method or rotary chemical evaporation method in the <italic>in situ</italic> reduction step.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisNanomaterials for catalytic reactions

Luminescence properties of novel emission-tunable NaSr( 4−x−y )Ba x (BO 3 ) 3 :yEu 2+ phosphors for white light emitting diodes

Jun Huang、Jian Dai、Degang Deng 等 9 位作者2015-01-01RSC Advances

The emission peaks of the obtained NaSr <sub>(3.98−x)</sub> Ba <italic>x</italic> (BO <sub>3</sub> ) <sub>3</sub> :0.02Eu <sup>2+</sup> phosphors can be continuously tuned from 609 nm to 544 nm by adjusting the Ba <sup>2+</sup> concentration.

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsGas Sensing Nanomaterials and Sensors

Biodegradable polymer–platinum drug conjugates to overcome platinum drug resistance

Qiang Yang、Ruogu Qi、Jing Cai 等 9 位作者2015-01-01RSC Advances

Biodegradable polymers with pendent pair-wised carboxylic acids but lacking sulfur were used to chelate oxaliplatin prodrug which self-assembled into micelles in water for drug delivery.

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Contact angle of a nanodrop on a nanorough solid surface

Gersh O. Berim、Eli Ruckenstein2015-01-01Nanoscale

The contact angle of a cylindrical nanodrop on a nanorough solid surface is calculated, for both hydrophobic and hydrophilic surfaces, using the density functional theory. The emphasis of the paper is on the dependence of the contact angle on roughness. The roughness is modeled by rectangular pillars of infinite lengt…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction Studiesnanoparticles nucleation surface interactions

Multitip semiconductor field emitters with new-type bilayer protecting coatings

G. G. Sominskii、T. A. Tumareva、E. P. Taradaev 等 5 位作者2015-01-01Technical Physics

We investigate the operation of multitip silicon field emitters with new-type bilayer metal—fullerene protective coatings in technical vacuum. The experiments indicate that such cathodes ensures emission current densities averaged over the cathode surface of about 0.5 A/cm 2 and can be used in high-voltage devices inc…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchNanowire Synthesis and Applications

Differential interactions of conjugated polymer nanoparticles with glycosaminoglycans in synthetic urine

Megan Twomey、Tereza Vokatá、Manian Rajesh Kumar 等 4 位作者2015-01-01Chemical Communications

Four different conjugated polymer nanoparticles (CPNs) were used to differentiate structurally similar glycosaminoglycans (GAGs) in a urine simulant. Unique emission response patterns of CPNs were analyzed by linear discriminant analysis (LDA), confirming that structurally diverse CPNs are sensitive and effective at d…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Extended supramolecular organization of π-systems using yet unexplored simultaneous intra- and inter-molecular H-bonding motifs of 1,3-dihydroxy derivatives

Tathagata Mondal、Dipankar Basak、Abdelaziz Al Ouahabi 等 6 位作者2015-01-01Chemical Communications

Unique H-bonding motifs of 1,3-dihydroxyl derivatives involving simultaneous intra- and inter-molecular H-bonding results in extended organization of pendant chromophores with a spatial distance suitable for π-π interaction. A preformed assembly with appended acceptor units exhibits host-guest interaction with specifi…

Crystallography and molecular interactionsLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Small gold nanoparticles for interfacial Staudinger–Bertozzi ligation

Pierangelo Gobbo、Wilson Luo、Sung Ju Cho 等 7 位作者2015-01-01Organic & Biomolecular Chemistry

Small gold nanoparticles (AuNPs) that possess interfacial methyl-2-(diphenylphosphino)benzoate moieties have been successfully synthesized (Staudinger-AuNPs) and characterized by multi-nuclear MR spectroscopy, transmission electron microscopy (TEM), UV-Vis spectroscopy, thermogravimetric analysis, and X-ray photoelect…

Gold and Silver Nanoparticles Synthesis and ApplicationsClick Chemistry and ApplicationsNanocluster Synthesis and Applications

Main chain dendronized hyperbranched polymers: convenient synthesis and good second-order nonlinear optical performance

Wenbo Wu、Zhipeng Wang、Rui Xiao 等 5 位作者2015-01-01Polymer Chemistry

By using low generation dendrimers as macromonomers, two main chain dendronized hyperbranched polymers, with good comprehensive nonlinear optical performance, were prepared conveniently with satisfying yields through a one-pot “A <sub>3</sub> + B <sub>2</sub> ” approach.

Nonlinear Optical Materials ResearchLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Microwave-assisted synthesis of water-soluble, fluorescent gold nanoclusters capped with small organic molecules and a revealing fluorescence and X-ray absorption study

Cora Helmbrecht、Dirk Lützenkirchen−Hecht、Walter Frank2015-01-01Nanoscale

Colourless solutions of blue light-emitting, water-soluble gold nanoclusters (AuNC) were synthesized from gold colloids under microwave irradiation using small organic molecules as ligands. Stabilized by 1,3,5-triaza-7-phosphaadamantane (TPA) or L-glutamine (GLU), fluorescence quantum yields up to 5% were obtained. Au…

Gold and Silver Nanoparticles Synthesis and ApplicationsCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Facile synthesis of Co 3 O 4 with different morphology and their application in supercapacitors

Tian Ouyang、Kui Cheng、Shuying Kong 等 8 位作者2015-01-01RSC Advances

Co <sub>3</sub> O <sub>4</sub> with different morphologies on nickel foam is successfully achieved <italic>via</italic> a simple hydrothermal method by changing the volume ratio between ethanol and water.

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationCatalysis and Hydrodesulfurization Studies

Hollow Al 2 O 3 spheres prepared by a simple and tunable hydrothermal method

Guangxin Xue、Xin Huang、Ning Zhao 等 5 位作者2015-01-01RSC Advances

The tunable Al <sub>2</sub> O <sub>3</sub> hollow spheres were prepared by a simple hydrothermal approach combining heat treatment.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications