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Multicomponent 5-fluorouracil loaded PAMAM stabilized-silver nanocomposites synergistically induce apoptosis in human cancer cells

Ishita Matai、Abhay Sachdev、P. Gopinath2015-01-01Biomaterials Science

Herein, we report the development of a poly(amidoamine) (PAMAM) dendrimer based multicomponent therapeutic agent for in vitro cancer therapy applications. In this approach, Generation 5 (G5) PAMAM dendrimers stabilizing silver nanoparticle surface (DsAgNPs) were used to encapsulate anticancer drug 5-fluorouracil (5-FU…

Advanced biosensing and bioanalysis techniquesRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Controlled stepwise-synthesis of core–shell Au@MIL-100 (Fe) nanoparticles for sensitive surface-enhanced Raman scattering detection

Jia Liao、Dongmei Wang、Liu Anqi 等 5 位作者2015-01-01The Analyst

A novel porous Au@MIL-100 (Fe) core-shell structure in which a Au nanoparticle (AuNP) core is coated with a controllable uniform metal-organic framework shell has been fabricated by using a facile step-by-step procedure. The as-synthesized Au@MIL-100 (Fe) takes advantage of the high adsorption capability of the MIL-10…

Gold and Silver Nanoparticles Synthesis and ApplicationsMercury impact and mitigation studiesAdvanced Nanomaterials in Catalysis

Water splitting with polyoxometalate-treated photoanodes: enhancing performance through sensitizer design

John Fielden、Jordan M. Sumliner、Nannan Han 等 8 位作者2015-01-01Chemical Science

Improved sensitizer design dramatically enhances visible light-driven water oxidation from dye-sensitized TiO <sub>2</sub> photoanodes treated with polyoxometalate water oxidation catalyst [{Ru <sub>4</sub> O <sub>4</sub> (OH) <sub>2</sub> (H <sub>2</sub> O) <sub>4</sub> }(γ-SiW <sub>10</sub> O <sub>36</sub> ) <sub>2<…

Advanced Photocatalysis TechniquesPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Photo-induced bending in a light-activated polymer laminated composite

Xiaoming Mu、Nancy Sowan、Julia Tumbic 等 6 位作者2015-01-01Soft Matter

Light activated polymers (LAPs) have attracted increasing attention since these materials change their shape and/or behavior in response to light exposure, which serves as an instant, remote and precisely controllable stimulus that enables non-contact control of the material shape and behavior through simple variation…

Polymer composites and self-healingPhotochromic and Fluorescence ChemistrySilicone and Siloxane Chemistry

Confined crystallization of fenofibrate in nanoporous silica

Leia M. Dwyer、Vladimir K. Michaelis、Marcus O’Mahony 等 5 位作者2015-01-01CrystEngComm

Producing stable nanocrystals confined to porous excipient media is a desirable way to increase the dissolution rate and improve the bioavailability of poorly water soluble pharmaceuticals. The poorly soluble pharmaceutical fenofibrate was crystallized in controlled pore glass (CPG) of 10 different pore sizes between…

Drug Solubulity and Delivery SystemsMesoporous Materials and CatalysisCrystallization and Solubility Studies

Higher mobility in bulk semiconductors by separating the dopants from the charge-conducting band – a case study of thermoelectric PbSe

Heng Wang、Xianlong Cao、Yoshiki Takagiwa 等 4 位作者2015-01-01Materials Horizons

Dopants are not the same in heavily doped semiconductors. For higher mobility dopants should be on the anion site for n-type and the cation site for p-type semiconductors, as these dopants are less disruptive to the band for the majority charge carriers.

Quantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

Mechanochromic luminescence and aggregation induced emission for a metal-free β-diketone

Tristan Butler、William A. Morris、Jelena Samonina‐Kosicka 等 4 位作者2015-01-01Chemical Communications

Reversible mechanochromic luminescence (ML) is known for difluoroboron β-diketonates (BF2bdks). Here, we report ML for the methoxy-substituted dinaphthoylmethane (dnmOMe) ligand even without coordination to boron. In addition, dnmOMe shows solvatochromism and aggregation-induced emission (AIE). Diketone thin films sho…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications

Sonication-assisted alcoholysis of boron nitride nanotubes for their sidewalls chemical peeling

Dukeun Kim、Sayuka Nakajima、Toshiki Sawada 等 9 位作者2015-01-01Chemical Communications

Boron nitride (BN)-based nanomaterials attract considerable attention due to their unique properties. In this study, we found that sonication treatment of multiwalled boron nitride nanotubes (BNNTs) in primary alcohols had led to chemical peeling of their sidewalls through alcoholysis, thereby producing boron nitride…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Healable shape memory (thio)urethane thermosets

Le‐Thu T. Nguyen、Thuy Thu Truong、Hà Trần Nguyên 等 7 位作者2015-01-01Polymer Chemistry

(Thio)urethane networks combining SM properties and self-healability under mild temperature conditions <italic>via</italic> the DA chemistry were developed. The effect of various network architectures in SM-aided scratch healing was evaluated.

Polymer composites and self-healingPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Tough protein–carbon nanotube hybrid fibers comparable to natural spider silks

Guangqiang Fang、Zhaokun Zheng、Jinrong Yao 等 10 位作者2015-01-01Journal of Materials Chemistry B

. In addition, we used several advanced characterization techniques, such as synchrotron radiation FTIR microspectroscopy and synchrotron radiation X-ray diffraction, to reveal the toughening mechanism in such a protein-inorganic hybrid system. We believe our attempt to produce such tough protein-based hybrid fibers b…

Electrospun Nanofibers in Biomedical ApplicationsProtein Hydrolysis and Bioactive PeptidesSilk-based biomaterials and applications

High surface area La 2 Sn 2 O 7 pyrochlore as a novel, active and stable support for Pd for CO oxidation

Jinshu Tian、Honggen Peng、Xianglan Xu 等 7 位作者2015-01-01Catalysis Science & Technology

A mesoporous La <sub>2</sub> Sn <sub>2</sub> O <sub>7</sub> -HT pyrochlore with an unusually high surface area was successfully synthesized with a simple hydrothermal method at 200 °C. Due to its high surface area and the presence of more active oxygen species, Pd supported on this mesoporous La <sub>2</sub> Sn <sub>2…

Advanced Condensed Matter PhysicsNuclear materials and radiation effectsElectronic and Structural Properties of Oxides

Vapour pressure and mixing thermodynamic properties of the KNbO 3 –NaNbO 3 system

A. Popovič、L. Bencze、Jurij Koruza 等 4 位作者2015-01-01RSC Advances

The analytical description of excess functions was made possible using more advanced treatment of experimental data with respect to literature.

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

Configuration coordinate energy level diagrams of intervalence and metal-to-metal charge transfer states of dopant pairs in solids

Zoila Barandiarán、Andries Meijerink、Luis Seijo2015-01-01Physical Chemistry Chemical Physics

Configuration coordinate diagrams, which are normally used in a qualitative manner for the energy levels of active centers in phosphors, are quantitatively obtained here for intervalence charge transfer (IVCT) states of mixed valence pairs and metal-to-metal charge transfer (MMCT) states of heteronuclear pairs, in sol…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsLuminescence and Fluorescent Materials

Interplay of Oxidative Stress and Autophagy in PAMAM Dendrimers-Induced Neuronal Cell Death

Yubin Li、Haiyan Zhu、Shaofei Wang 等 10 位作者2015-01-01Theranostics

Poly-amidoamine (PAMAM) dendrimers are proposed to be one of the most promising drug-delivery nanomaterials. However, the toxicity of PAMAM dendrimers on the central nervous system seriously hinders their medical applications. The relationship between oxidative stress and autophagy induced by PAMAM dendrimers, and its…

Autophagy in Disease and TherapyMicroplastics and Plastic PollutionDendrimers and Hyperbranched Polymers

Iron triad (Fe, Co, Ni) nanomaterials: structural design, functionalization and their applications

Wei Zhou、Lin Guo2015-01-01Chemical Society Reviews

The structure and the composition are two key factors that influence the physical, chemical, and other properties of materials. Correspondingly, structural design and functionalization with inorganic or organic materials provide efficient routes to enhancing some properties. Herein, iron triad nanomaterials, with a wi…

Graphene research and applicationsElectrodeposition and Electroless CoatingsAdvanced Materials Characterization Techniques

Theoretical maximum efficiency of solar energy conversion in plasmonic metal–semiconductor heterojunctions

Scott K. Cushing、Alan D. Bristow、Nianqiang Wu2015-01-01Physical Chemistry Chemical Physics

Plasmonics can enhance solar energy conversion in semiconductors by light trapping, hot electron transfer, and plasmon-induced resonance energy transfer (PIRET). The multifaceted response of the plasmon and multiple interaction pathways with the semiconductor makes optimization challenging, hindering design of efficie…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications