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Observation of Non-Förster-Type Energy-Transfer Behavior in Quantum Dot−Phthalocyanine Conjugates

Smita Dayal、Yongbing Lou、Anna Cristina S. Samia 等 6 位作者2006-10-11Journal of the American Chemical Society

The effect of linker chain length on the energy transfer from CdSe quantum dots (QDs) to silicon phthalocyanine (Pc) photodynamic therapy agents was investigated by steady-state and femtosecond time-resolved spectroscopy with 500 nm light for the specific excitation of the QD energy donor. The conjugation between the…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresPorphyrin and Phthalocyanine Chemistry

Intergrain connectivity and resistive broadening in vortex state: a comparison between MgB2, NbSe2 and Bi2Sr2Ca2Cu3O10 superconductors

S. D. Kaushik、S. Patnaik2006-10-11arXiv

Magnetoresistance and radio frequency penetration depth techniques are used to study grain connectivity and broadening of superconducting transition. We study and compare these issues in clean polycrytalline samples of three different superconducting systems e.g. MgB2, NbSe2 and Bi2Sr2Ca2Cu3O10. From the rf response,…

SuperconductivityMaterials Science

Study of transport properties of a molecular junction as a function of distance between the leads

Victor M. Garcia-Suarez、Tomasz Kostyrko、Steven Bailey 等 5 位作者2006-10-11arXiv

We consider a model of a molecular junction made of BDT (benzene dithiol) molecule trapped between two Au(100) leads. Using the ab initio approach implemented in the SIESTA package we look for the optimal configuration of the molecule as a function of a distance between the leads. We find that for the distance long en…

Materials Science

Proton-induced magnetic order in carbon: SQUID measurements

J. Barzola-Quiquia、S. Petriconi、P. Esquinazi 等 7 位作者2006-10-11arXiv

In this work we have studied systematically the changes in the magnetic behavior of highly oriented pyrolytic graphite (HOPG) samples after proton irradiation in the MeV energy range. Superconducting quantum interferometer device (SQUID) results obtained from samples with thousands of localized spots of micrometer siz…

Materials ScienceStrongly Correlated Electrons

Mechanics of atoms and fullerenes in single-walled carbon nanotubes. II. Oscillatory behaviour

Barry J. Cox、Ngamta Thamwattana、James M. Hill2006-10-11Proceedings of the Royal Society A Mathematical Physical and Engineering Sciences

The discovery of carbon nanotubes and C 60 fullerenes has created an enormous impact on possible new nanomechanical devices. Owing to their unique mechanical and electronic properties, such as low weight, high strength, flexibility and thermal stability, carbon nanotubes and C 60 fullerenes are of considerable interes…

Carbon Nanotubes in CompositesNanotechnology research and applicationsMechanical and Optical Resonators

Degenerate ground states and nonunique potentials: breakdown and restoration of density functionals

K. Capelle、C. A. Ullrich、G. Vignale2006-10-11arXiv

The Hohenberg-Kohn (HK) theorem is one of the most fundamental theorems of quantum mechanics, and constitutes the basis for the very successful density-functional approach to inhomogeneous interacting many-particle systems. Here we show that in formulations of density-functional theory (DFT) that employ more than one…

physics.atom-phChemical PhysicsStrongly Correlated ElectronsMaterials Science

Improved critical current densities in MgB2 tapes with ZrB2 doping

Xianping Zhang、Zhaoshun Gao、Dongliang Wang 等 7 位作者2006-10-11arXiv

MgB2/Fe tapes with 2.5-15 at.% ZrB2 additions were prepared through the in situ powder-in-tube method. Compared to the pure tape, a significant improvement in the in-field critical current density Jc was observed, most notably for 10 at.% doping, while the critical temperature decreased slightly. At 4.2 K, the transpo…

SuperconductivityMaterials Science

Plasmon-Assisted Chemical Vapor Deposition

David Boyd、Leslie Greengard、Mark L. Brongersma 等 5 位作者2006-10-11Nano Letters

We introduce a new chemical vapor deposition (CVD) process that can be used to selectively deposit materials of many different types. The technique makes use of the plasmon resonance in nanoscale metal structures to produce the local heating necessary to initiate deposition when illuminated by a focused low-power lase…

Thermal Radiation and Cooling TechnologiesGold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactions

Electrochemical Switching of the Cubic Nonlinear Optical Properties of an Aryldiethynyl‐Linked Heterobimetallic Complex between Three Distinct States

Marek Samoć、N. Gauthier、Marie P. Cifuentes 等 6 位作者2006-10-11Angewandte Chemie International Edition

Successive oxidation processes in a heterobimetallic iron–ruthenium complex (see picture) “switch” the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex.

Porphyrin and Phthalocyanine ChemistryElectron Spin Resonance StudiesPhotochemistry and Electron Transfer Studies

Mechanics of atoms and fullerenes in single-walled carbon nanotubes. I. Acceptance and suction energies

Barry J. Cox、Ngamta Thamwattana、James M. Hill2006-10-11Proceedings of the Royal Society A Mathematical Physical and Engineering Sciences

Owing to their unusual properties, carbon nanostructures such as nanotubes and fullerenes have caused many new nanomechanical devices to be proposed. One such application is that of nanoscale oscillators which operate in the gigahertz range, the so-called gigahertz oscillators. Such devices have potential applications…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsForce Microscopy Techniques and Applications

Low field phase diagram of spin-Hall effect in the mesoscopic regime

Zhenhua Qiao、Wei Ren、Jian Wang 等 4 位作者2006-10-11arXiv

When a mesoscopic two dimensional four-terminal Hall cross-bar with Rashba and/or Dresselhaus spin-orbit interaction (SOI) is subjected to a perpendicular uniform magnetic field $B$, both integer quantum Hall effect (IQHE) and mesoscopic spin-Hall effect (MSHE) may exist when disorder strength $W$ in the sample is wea…

Materials ScienceMesoscale and Nanoscale Physics

Structural, electronic and magnetic properties of Mn-doped GaAs(110) surface

A. Stroppa2006-10-11arXiv

First principles total-energy pseudopotential calculations have been performed to investigate STM images of the (110) cross-sectional surface of Mn-doped GaAs. We have considered configurations with Mn in interstitial positions in the uppermost surface layers with Mn surrounded by As (Int$_{As}$) or Ga (Int$_{Ga}$) at…

Materials Science

Finite size effects in the Verwey transition of magnetite thin films

Alexandre Bataille、Eric Vincent、Susana Gota 等 4 位作者2006-10-11arXiv

We report on the finite size effects in the Verwey transition of stress-free magnetite Fe3O4 thin films. A limit thickness of 20 nm is evidenced, above which the transition temperature TV is constant and close to 120 K (bulk value) and below which no genuine transition is observed. Field Cooled and Zero Field Cooled m…

Materials ScienceStrongly Correlated Electrons

Accurate modeling of left-handed media using finite-difference time-domain method and finite-size effects of a left-handed medium slab on the image quality revisited

Yan Zhao、Pavel Belov、Yang Hao2006-10-11arXiv

The letter contains an important message regarding the numerical modeling of left-handed media (LHM) using the finite-difference time-domain (FDTD) method which remains at the moment one of the main techniques used in studies of these exotic materials. It is shown that conventional implementation of the dispersive FDT…

Materials Science

Fungus-Mediated Biotransformation of Amorphous Silica in Rice Husk to Nanocrystalline Silica

Vipul Bansal、Absar Ahmad、Murali Sastry2006-10-11Journal of the American Chemical Society

Rice husk is a cheap agro-based waste material, which harbors a substantial amount of silica in the form of amorphous hydrated silica grains. However, there have been no attempts at harnessing the enormous amount of amorphous silica present in rice husk and its room-temperature biotransformation into crystalline silic…

Geomagnetism and Paleomagnetism StudiesDiatoms and Algae ResearchSilicon Effects in Agriculture

Optical Properties of ZnO Nanocrystals Doped with Cd, Mg, Mn, and Fe Ions

Y. S. Wang、Philippe Thomas、Paul O’Brien2006-10-11OpenAlex

ZnO nanocrystals doped with Cd, Mg, Mn, and Fe ions were obtained by thermolysis of a family of metal cupferrates. The nanocrystals were characterized by X-ray diffraction, energy-dispersive X-ray analysis, transmission electron microscopy, UV-visible, luminescence, and excitation spectroscopy. The band gap of the nan…

Quantum Dots Synthesis And PropertiesPerovskite Materials and ApplicationsZnO doping and properties

Heart Valve Tissue Engineering: Concepts, Approaches, Progress, and Challenges

Karen Mendelson、Frederick J. Schoen2006-10-11OpenAlex

Potential applications of tissue engineering in regenerative medicine range from structural tissues to organs with complex function. This review focuses on the engineering of heart valve tissue, a goal which involves a unique combination of biological, engineering, and technological hurdles. We emphasize basic concept…

Bone Tissue Engineering MaterialsTissue Engineering and Regenerative MedicineElectrospun Nanofibers in Biomedical Applications

Chemical screening methods to identify ligands that promote protein stability, protein crystallization, and structure determination

Masoud Vedadi、F. Niesen、Abdellah Allali‐Hassani 等 16 位作者2006-10-11OpenAlex

The 3D structures of human therapeutic targets are enabling for drug discovery. However, their purification and crystallization remain rate determining. In individual cases, ligands have been used to increase the success rate of protein purification and crystallization, but the broad applicability of this approach is…

Enzyme Structure and FunctionProtein Structure and DynamicsProtein purification and stability

Radiation Damage Effects in Insulators for Fusion Reactors: Microstructure Evolution in MgO-Al<sub>2</sub>O<sub>3</sub> System Oxide Crystals

Kazuhiro Yasuda、Syo Matsumura2006-10-10Advances in science and technology

Characteristic features of radiation damage in insulators for fusion reactors are that those materials are exposed to synergistic radiation damage of elastic displacements and electric excitation with the presence of an electric field. This paper describes the nucleation-and-growth of radiation-induced defects and the…

Nuclear materials and radiation effectsIon-surface interactions and analysisFusion materials and technologies

Nanostructured Carbon Films Produced by Pulsed Laser Deposition for Bio-Medical Applications

A. Mangione、L. Torrisi、A. Picciotto 等 5 位作者2006-10-10Advances in science and technology

Damond-like (DLC) films can be produced by Pulsed Laser Deposition (PLD) technique. Different pulsed lasers can be employed to generate hot carbon plasma, to deposit and/or to implant energetic carbon atoms and molecules on substrates. A Nd:Yag laser radiation with ns pulse duration, about 1010 W/cm2intensity and 30 H…

Metal and Thin Film MechanicsCarbon Nanotubes in CompositesDiamond and Carbon-based Materials Research