Materials Literature
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A spin-bearing bis-bidentate ligand, designed from a pyrimidyl-substituted R-CN2S2 neutral radical, is used to co-ordinate two Mn(II) metal centres yielding a thermally stable complex with antiferromagnetic coupling between the ligand-centred spin and the metal-centred spins, and thus an overall ferrimagnetic coupling…
A two-phase liquid-liquid extraction process is presented which is capable of extracting water-soluble single-walled carbon nanotubes into an organic phase. The extraction utilizes electrostatic interactions between a common phase transfer agent and the sidewall functional groups on the nanotubes. Large length-depende…
Herein we report a method for the direct synthesis of suspended single-walled carbon nanotubes (su-SWNTs) using carbon nanofibres (CNFs) as templates via a three-step fabrication process. Plasma-enhanced chemical vapour deposition was first employed to grow vertically aligned CNFs, which were then post-treated with an…
Electrochemical anodization was applied to an aluminium (Al) sheet patterned with a metallic tantalum (Ta) mask, which gave rise to the formation of patterned anodic aluminium oxide (AAO). The morphological evolution of the AAO porous structure with anodizing time was characterized by scanning electron microscopy. Lat…
Laboratory experiments have been carried out to investigate the effect of temperature on the performance of diethylenetriamine penta (methylene phosphonic acid), DETPMP, against barium sulfate scale formation. This paper presents the findings from this recent experimental study. By maintaining both supersaturation and…
A method for three-dimensional reconstruction and imaging of surface topography in a scanning electron microscope (SEM) is briefly presented. The method is based on the 'shape from shadows' approach and is particularly suitable for relatively smooth surfaces, where stereoscopic methods may be less efficient. The autho…
The origin of ferromagnetism in lightly doped polycrystalline diluted magnetic semiconductor, Zn1-xNixO (x = 0.025, 0.05), synthesized by a low-temperature combustion method, has been found to be from Ni metal impurities, as evidenced from powder XRD, electron diffraction, optical absorption, and magnetic properties.
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTNative Structure and Degradation Pattern of Silk Sericin Studied by 13C NMR SpectroscopyHidetoshi Teramoto, Aya Kakazu, and Tetsuo AsakuraView Author Information New Silk Materials Laboratory, National Institute of Agrobiological Sc…
Based on Timoshenko laminated beam models, this paper investigates the influence of initial stress on the vibration and transverse wave propagation in individual multi-wall carbon nanotubes (MWNTs) under ultrahigh frequency (above 1 THz), in which the initial stress in the MWNTs can occur due to thermal or lattice mis…
X-ray diffraction and transmission electron microscopy were used to investigate the hydrothermal formation of chrysotile Mg3[Si2O5](OH)4 nanotubes from amorphous SiO2 and nanocrystalline Mg(OH)2. The results show that nanotubes form readily in a highly basic hydrothermal environment via the curling of flake-like nanoc…
Two new double perovskite oxides, Ca(2)NiOsO(6) and Sr(2)NiOsO(6), have been prepared as polycrystalline powders by solid state synthesis. The two oxides were structurally characterized by variable-temperature powder neutron diffraction. Ca(2)NiOsO(6) was found to adopt a monoclinic structure (P2(1)/n), while Sr(2)NiO…
Cellular differentiation, organization, proliferation and apoptosis are determined by a combination of an intrinsic genetic program, matrix/substrate interactions, and extracellular cues received from the local microenvironment. These molecular cues come in the form of soluble (e.g. cytokines) and insoluble (e.g. ECM…
We present the dynamic propensity distribution as an explicit measure of the degree to which the dynamics in a liquid over the time scale of structural relaxation is determined by the initial configuration. We then examine, for a binary mixture of soft discs in two dimensions, the correlation between the spatial distr…
A procedure is described for accurate Si isotope ratio measurements by multicollector inductively coupled plasma mass spectrometry (MC-ICPMS). Dissolved silicon was preconcentrated and separated from other elements present in natural surface waters using anion-exchange chromatography. The optimized procedure provides…
We present results obtained by dielectric spectroscopy in wide frequency (10(-2)-10(9) Hz) and temperature ranges on human hemoglobin in the three different solvents water, glycerol, and methanol, at a solvent level of 0.8 g of solvent/g of protein. In this broad frequency region, there are motions on several time-sca…
We use a recently derived reformulation of the diffusion constant (Stillinger and Debenedetti 2005 J. Phys. Chem. B 109 6604) to investigate heterogeneous dynamics and non-Gaussian diffusion in a binary Lennard-Jones mixture. Our work focuses on the joint probability distribution of particles with velocity v 0 at time…
In the present study, we describe the synthesis of highly luminescent uncoated water-soluble CdSe quantum dots (QDs) possessing the following characteristics: approximately 2 nm in diameter, with very good size distribution (in 95% homodispersed) accompanied by a broad-band photoluminescent spectrum. The synthetic pro…
Elemental selenium nanobelts have been synthesized for the first time by a novel and mild solution method. The synthetic reaction was carried out with cellulose as both reducing and morphology-directing agents in solution under simple hydrothermal conditions at low temperature, which is quite different from the therma…
Metal-free mononuclear, dinuclear and trinuclear phthalocyanines were prepared by a mixed cyclotetramerisation of a 1,2,4,5-tetracyanobenzene derivative and 4,5-bis(2,6-dimethylphenoxy)phthalonitrile. For the first time, a pi-electron-conjugated trinuclear phthalocyanine was synthesised with phthalocyanine units conne…
We describe a six-step method for making colloidal clusters of 2, 3, or 4 silica particles with a radius of 1.2 microm. This method, originally described by Manoharan et al. (Manoharan, V. N.; Elsesser, M. T.; Pine, D. J. Science 2003, 301, 483), is based on the encapsulation of silica spheres in emulsion droplets. Th…