Materials Literature
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The oiling out and crystallization of a pharmaceutical compound from a water−ethanol mixture has been studied using a range of in-line process analytical techniques in order to more fully understand the phenomenon and build in control of its crystallization. Mechanistically, oiling out was found to follow a number of…
The inhomogeneous distribution of excess or deficient silver atoms lies behind the large and linear transverse magnetoresistance displayed by ${\mathrm{Ag}}_{2\ifmmode\pm\else\textpm\fi{}\ensuremath{\delta}}\mathrm{Se}$ and ${\mathrm{Ag}}_{2\ifmmode\pm\else\textpm\fi{}\ensuremath{\delta}}\mathrm{Te}$, introducing spat…
The effect of temperature on the kinetics of physical aging of thin films formed from two amorphous glassy polymers, polysulfone based on bisphenol A and poly(2,6-dimethyl-1,4-phenylene oxide), was investigated by monitoring the changes in gas permeability and refractive index. Films with different thicknesses were su…
N, Ar, and Er ions were implanted into ZnO at 15 K within a large fluence range. The Rutherford backscattering technique in the channeling mode was used to study in situ the damage built-up in the Zn sublattice at 15 K. Several stages in the damage formation were observed. From the linear increase of the damage for lo…
Covalent and noncovalent chemistries that are selective to single-walled carbon nanotubes of a particular electronic type have become increasingly important for electronic structure separation and on-chip modification of nanoelectronic devices. By monitoring transient Raman spectroscopy and photoluminescence (PL) duri…
We have developed a set of numerical tools for the quantitative analysis of defect dynamics in quasiperiodic structures. We have applied these tools to study dislocation motion in the dynamical equation of Lifshitz and Petrich [Phys. Rev. Lett. 79 (1997) 1261] whose steady state solutions include a quasiperiodic struc…
We examine the spin torque (ST) response of magnetic tunnel junctions (MTJs) with ultra-thin MgO tunnel barrier layers to investigate the relationship between the spin-transfer torque and the tunnel magnetoresistance (TMR) under finite bias. We find that the spin torque per unit current exerted on the free layer decre…
We consider theoretically a superlattice formed by thin conducting layers separated spatially between insulating layers. The dispersion of two coupled phonon-plasmon modes of the system is analyzed by using Maxwell's equations, with the influence of retardation included. Both transmission for the finite plate as well…
Fermi-surface deformations in strongly correlated metals, in comparison to results from band-structure calculations, are investigated. We show that correlation-induced interband charge transfers in multi-orbital systems may give rise to substantial modifications of the actual Fermi surface. Depending in particular on…
A completely aqueous, stepwise deposition process with Bombyx mori silk fibroin for the assembly of nanoscale thin film coatings is reported the first time. The focus of this work was to develop an understanding of the control of this deposition process and to characterize the films formed from a physicochemical persp…
A one dimensional theory of lateral spin-polarized transport is derived from the two dimensional flow in the vertical cross section of a stack of ferromagnetic and paramagnetic layers. This takes into account the influence of the lead on the lateral current underneath, in contrast to the conventional 1D modeling by th…
Raman scattering data were collected on graphite monochromator. Spectra were interpreted in terms of the space group $P6_3mc$, a subgroup of space group $P6_3/mmc$. The latter has commonly been used for the interpretation of Raman scattering data. Space group $P6_3mc$ corresponds to the buckling of graphene sheets and…
Nd_0.67Sr_0.33MnO_3 nanoparticles with the grain size of about 30 nm are prepared by sol-gel method.These nanopowders are annealed at four different temperatures viz. 800 oC, 900 oC, 1000 oC and 1100 oC to study the effect of particle size on magnetic, transport and electron magnetic resonance (EMR) spectral parameter…
A method for estimation of reversible and irreversible susceptibilities of initial magnetization curves has been developed. It deals only with the energy necessary for magnetizing and demagnetizing the sample, not with the nature of the magnetization processes neither with a specific type of anisotropy, so it could be…
Spintronics in ferromagnetic metals is built on a complementary set of phenomena in which magnetic configurations influence transport coefficients and transport currents alter magnetic configurations. In this Letter we propose that corresponding effects occur in circuits containing antiferromagnetic metals. The critic…
Carbohydrate conjugate rod-coil amphiphiles were synthesized and their self-assembling behavior in aqueous solution was investigated. These amphiphiles were observed to self-assemble into supramolecular structures that differ significantly depending on the molecular architecture. The rod-coil amphiphiles based on a sh…
On the basis of Kirkendall Effect, high symmetric 18-facet polyhedral nanocrystals of Cu7S4 with a hollow nanocage could be converted from cubic nanocrystals of Cu2O in an aqueous media. The presence of organic additives makes the surface energy of {110} smaller than those of {100} and {111}. The growth of nanocrystal…
We study the changes in the electronic structure induced by lattice defects in graphene planes. In many cases, lattice distortions give rise to localized states at the Fermi level. Electron-electron interactions lead to the existence of local moments. The RKKY interaction between these moments is always ferromagnetic,…
We have studied the frequency and temperature dependences of permittivity and impedance of the compounds ACu3Ti4O12 (A=Ca,Bi2∕3,Y2∕3,La2∕3) in the ranges of 10−1–106Hz and −150–200°C. All compounds investigated display similar dielectric properties. Specifically, they all have a Debye-like relaxation and their dielect…
The quintessence of the hot-injection method, a synthesis route for monodisperse, highly luminescent semiconductor nanocrystals, is reviewed. The separate stages of nucleation and growth of the nanocrystals are discussed in the framework of classical nucleation theory and an equilibrium model proposed by Debye. We als…