Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhase transitions in crosslinked gels of natural polymersTakayuki Amiya and Toyoichi TanakaCite this: Macromolecules 1987, 20, 5, 1162–1164Publication Date (Print):May 1, 1987Publication History Published online1 May 2002Published inissue 1 May 1987https://pubs.acs.org/doi/1…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIntramolecular excimer formation in bichromophoric molecules linked by a short flexible chainFrans C. De Schryver, Pol Collart, Jan Vandendriessche, Rudy Goedeweeck, Anne Mie Swinnen, and Marc Van der AuweraerCite this: Acc. Chem. Res. 1987, 20, 5, 159–166Publication Date (P…
In this investigation we have studied how the presence of a liquid phase affects the grain morphology and grain growth kinetics in Al 2 O 3 at 1800°C using the growth of both matrix grains and large spherical single‐crystal seeds growing into the matrix. The growth rates of the matrix grains were found to decrease in…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHeterobimetallic compounds linked by heterodifunctional ligandsR. Morris Bullock and Charles P. CaseyCite this: Acc. Chem. Res. 1987, 20, 5, 167–173Publication Date (Print):May 1, 1987Publication History Published online1 May 2002Published inissue 1 May 1987https://pubs.acs.…
Abstract Previous papers have shown that antiplasticization of polysulfone and poly(phenylene oxide) by low molecular weight diluents is accompanied by substantial reductions in permeability to gases like helium, carbon dioxide, and methane because of reduced mobility in the glass. These effects are not explained even…
ADVERTISEMENT RETURN TO ISSUEPREVarticleNEXTImmortal polymerization of .epsilon.-caprolactone initiated by aluminum porphyrin in the presence of alcoholMasato Endo, Takuzo Aida, and Shohei InoueCite this: Macromolecules 1987, 20, 12, 2982–2988Publication Date (Print):May 1, 1987Publication History Published online1 Ma…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStarburst dendrimers. 4. Covalently fixed unimolecular assemblages reiminiscent of spheroidal micellesDonald A. Tomalia, V. Berry, M. Hall, and D. M. HedstrandCite this: Macromolecules 1987, 20, 5, 1164–1167Publication Date (Print):May 1, 1987Publication History Published on…
The mechanical properties of cultured bovine aortic endothelial cells exposed to a fluid-imposed shear stress were studied using the micropipette technique. The cells, which were attached to a Thermanox plastic substrate, were exposed to a specific steady shear stress of either 10, 30, or 85 dynes/cm2 and for a durati…
This paper describes a new class of light control films consisting of submicron liquid crystal droplets dispersed in ultraviolct-cured polymer matrices. These films, which can respond optically to both applied electric fields and temperature changes, are potentially useful for displays and light shutters. The optical…
Abstract A thermotropic liquid crystalline polymer (LCP), when added to polystyrene (PS), can function as both a processing aid and a reinforcing filler. Thermal, rheological, and mechanical properties of the pure components and blends containing up to 10 percent LCP are reported. The LCP used is immiscible with PS, a…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTWhere are the protons in H3V10O283-?V. W. Day, W. G. Klemperer, and D. J. MaltbieCite this: J. Am. Chem. Soc. 1987, 109, 10, 2991–3002Publication Date (Print):May 1, 1987Publication History Published online1 May 2002Published inissue 1 May 1987https://pubs.acs.org/doi/10.102…
Magnetization processes in a sintered Nd-Fe-B permanent magnet (NEOMAX-35) were examined on a small scale using a Hall-effect microprobe with an active area 75 μm on a side. Probes were made by evaporating bismuth through a stencil mask onto glass slides. Experiments were performed by placing a probe onto the polished…
This paper presents the results of an experimental study of the mechanical properties of composites consisting of prehydrolyzed cellulose and thermoplastic matrices. The main feature of prehydrolyzed cellulose fibres is a high degree of brittleness, permitting the fibres to be finely comminuted in the shear field of n…
‘Epitaxy’ means order in the relative orientation of identical crystals nucleated and grown on a large single-crystal face. Every crystal of the deposited material is oriented in such a way that there is coincidence of some vectors of its reciprocal lattice with vectors of the reciprocal lattice of the substrate surfa…
Experiments have been performed to investigate the use of coral skeletons as bone graft substitutes. Skeletal fragments of different coral genera were implanted into cortical and spongy bone defects and used to bridge transcortical resections in the femur. The implant site was monitored for up to 18 months. Radiograph…
The possibility of extracting absolute inelastic electron scattering cross sections K(T) (differential in energy loss T and path length) for solids from experimental electron spectra is studied. Assuming homogeneous scattering properties for the solid, a formula is found, which allows a direct determination of [\ensur…
Acidic matrix macromolecules involved in regulation of biological crystal growth often contain aspartic acid-rich domains and covalently bound sulfated polysaccharides. We propose that sulfates and beta-sheet structured carboxylates cooperate in oriented calcite crystal nucleation. The sulfates concentrate calcium, cr…
Titanium(III) in corundum shows a short-lived (3.1 μs) broad 2E - 2T2 luminescence around λ = 740 nm, and a 10 times longer-lived 2A1 ("4s") – 2T2 centered around λ = 410 nm. Both these broad-band emissions with large Stokes shift offer prospects for tunable lasers. The absorption spectrum has been studied in detail,…
The results of studies on the kinetics and mechanisms of reactions involving the transfer of an electron and a hydrogen atom to quinone molecules in triplet states are surveyed and the spectroscopic-kinetic characteristics of the triplet exciplexes of quinones and the role of the electron donor–acceptor interactions a…
Raman scattering from acoustic phonons in Si-${\mathrm{Ge}}_{\mathrm{x}}$${\mathrm{Si}}_{1\mathrm{\ensuremath{-}}\mathrm{x}}$ Fibonacci superlattices is reported. The main features of the experimental results are determined by the Fourier components of the dependence on position along the growth direction of the photo…