Materials Literature
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The far infrared spectra of the rare earth sesquioxides, cerium dioxide, and nonstoichiometric praseodymium and terbium oxides have been observed over the range 10-250 cm -1 at liquid helium temperatures. Absorption due to the excitation of phonons and low-lying electronic states of the rare earth ions occur in this r…
The temperature dependence of the flow alignment angle has been measured in two nematic liquid crystals, ${p}^{\ensuremath{'}}$-methoxybenzylidene-$p\ensuremath{-}n$-butylaniline and $p\ensuremath{-}n$-hexyloxybenzylidene-${p}^{\ensuremath{'}}$-aminobenzonitrile. For both compounds this angle reaches a peak value at t…
We studied the second derivative of the magnetization with respect to the magnetic field, $\frac{{d}^{2}M}{d{H}^{2}}$, for polycrystalline materials having uniaxial anisotropy. Evidence is given of a singular point located at $H={H}_{A}$, the anisotropy field. The observed sharp peak is associated with the infinity at…
The crystal structure of pyridinium hexaiodopentaargentate, (C(5)H(5)NH) Ag(5)l(6), is unique among those of the halide and chalcogenide solid electrolytes in that face-sharing iodide octahedra as well as face-sharing tetrahedra and face-sharing between octahedra and tetrahedra provide the paths for silver ion transpo…
Polystyrenes with molecular weights up to 44 x 10(6) grams per mole have been characterized by light-scattering and equilibrium ultracentrifugation methods. The Mark-Houwink equation, which relates the molecular weight and the intrinsic viscosity of flexible polymers, can be used only if the measurements are made in a…
Thermogravimetric measurements were made for the oxidation of hot pressed silicon carbide at an oxygen pressure of 150 torr and at temperatures from 1300C to 1600C. Oxidized samples were then analyzed using X-ray, metallograph, and electron probe techniques. The oxidation rate was found to increase with temperature. T…
A phase-sensitive detection system is described in detail for measuring electron-energy distributions using conventional Langmuir probes. A switching circuit is also discussed which enables the system to measure the DC characteristics. A typical result is presented and modifications are suggested to enable probe chara…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBehavior of Ruthenium in GlassJ. MukerjiCite this: Ind. Eng. Chem. Prod. Res. Dev. 1972, 11, 2, 178–183Publication Date (Print):June 1, 1972Publication History Published online1 May 2002Published inissue 1 June 1972https://pubs.acs.org/doi/10.1021/i360042a010https://doi.org/…
An X ray goniometer is described in which the principal characteristic is that the sample, placed in a horizontal plane, remains motionless, while the X ray tube and X ray counter move symmetrically. This apparatus is specially designed for use with a high temperature X ray diffraction furnace associated with other te…
Copper single crystals of extremely low dislocation density have been obtained through a thermal cyclic annealing. Ball indentation in the dislocation-free area of (111) surface produced large dislocation rosettes, each arm extending in the 〈110〉 cystallographic orientations consisted of a row of prismatic dislocation…
Derivative structures based upon sphalerite or galena often exhibit hexagonal superstructures characteristic of a peculiar thirteenfold multiplicity. A synthetic semiconductor, Cu 7 As 6 Se 13 , is one of the examples. Crystals of Cu 7 As 6 Se 13 are rhombohedral with a = 8.71 Å, α = 105°41′. The space group is R 3. T…
The defect structures in irradiated type 304 stainless steel were characterized by transmission electron microscopy for irradiation temperatures between 370 and 840°C and for fluences ranging from 1018 to 1023 neutrons/cm2 (> 0.1 MeV). Below about 550°C the interstitial atoms produced by the irradiation precipitate as…
Laboratory studies are discussed in which steels were exposed to synthetic flue-gas atmospheres at temperatures ranging from 316 to 538 C (600 to 1000 F) in the presence of various salt mixtures. It was shown that the addition of chloride salts to mixed sulfates greatly accelerated the corrosion, particularly at 538 C…
The reflectance of evaporated rhenium (Re) and tungsten (W) was measured in the wavelength region from 300 to 2000 Å. Re and W of 99.99% purity were evaporated with a 6-kW fine-focused electron gun and deposited on glass and fused-quartz plates of various temperatures ranging from 40 to 500°C. With Re, films of highes…
Studies have been made of the tempering at 400° and 600°C of h.c.p. and orthorhombic martensitic phases in alloys with up to 32 w/o tantalum, and of the retained β phase in higher tantalum alloys. Precipitation of the equilibrium β phase as disc-shaped particles with the Burgers orientation relation and with a habit p…
Abstract In non-aqueous systems, kaolinite can show, in addition to the physical interactions, considerable chemical activity. This study considers the chemical reactions that can occur at the kaolinite surface and explains these reactions in terms of acid-base interactions. In certain applications the chemical activi…
ESR spectra of the ScS and YS molecules in their ground 2Σ+ states were measured while trapped in solid argon or neon matrices at 4°K. g tensors and hyperfine structure constants for interaction with the metal nuclei were accurately derived, within the ambiguity of multiple matrix sites. Earlier ESR data on ScO were a…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReaction of catechol with colloidal silica and silicic acid in aqueous ammoniaDennis W. BarnumCite this: Inorg. Chem. 1972, 11, 6, 1424–1429Publication Date (Print):June 1, 1972Publication History Published online1 May 2002Published inissue 1 June 1972https://pubs.acs.org/do…
A common objective in designing a postmortem type of plate-impact experiment is to be able to attribute the observable residual effects (such as residual strain, hardness, or dislocation density) primarily to the conditions which existed while the material was in a state of uniaxial strain. In the past it has generall…
In both pIants and animals the mechanism of ribosomal RNA synthesis is thought to be the same, yet genetic and biochemical evidence points to a dispersed origin along chromosomal DNA in plants