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Biosynthesis of Vitamin B6

Robert E. Hill、Frederick J. Rowell、Ram N. Gupta 等 4 位作者1972-03-01Journal of Biological Chemistry

The biosynthesis of vitamin B6 was studied in an Escherichia coli mutant, blocked between pyridoxol and pyridoxal. Specific incorporation of glycerol, pyruvate, serine, and glucose was shown by chemical degradation of labeled samples of pyridoxol isolated from the medium of cultures which had been incubated with vario…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

Structure of Amorphous Silicon Monoxide

J. Yasaitis、Roy Kaplow1972-03-01Journal of Applied Physics

The pair distribution function in amorphous deposited silicon monoxide has been measured at room temperature. The result is not in good agreement with expectations for a mixture of well-defined amorphous silicon and amorphous SiO2. Other possibilities, for which the average number of nearest-neighbor Si–O bonds per at…

High-pressure geophysics and materialsGlass properties and applicationsX-ray Diffraction in Crystallography

Collisional Detachment Studies of NO−

Melinda A. McFarland、D. B. Dunkin、F. C. Fehsenfeld 等 5 位作者1972-03-01The Journal of Chemical Physics

Rate constants for collisional detachment of NO−, NO− + X → NO + X + e,have been measured from 193 to 506°K for X as He, Ne, H2, NO, CO, CO2, N2O, and NH3. The data fit Arrhenius plots kd=Ae−E/kT with both A and E showing large variations with X. From equilibrium constant considerations, electron attachment rates to N…

Atmospheric chemistry and aerosolsCatalytic Processes in Materials ScienceSpectroscopy and Laser Applications

Spin density distribution in iron-silicon alloys

J Moss、P. J. Brown1972-03-01Journal of Physics F Metal Physics

The spin density distributions in two alloys of iron and silicon (approximate compositions Fe3Si and Fe4Si) have been determined by polarized neutron diffraction. The observed data have been corrected for the effects of extinction and have been analysed by the standard Fourier method and also by expressing the density…

Rare-earth and actinide compoundsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

The Structure of Electroplated and Vapor-Deposited Copper Films

A. Gangulee1972-03-01Journal of Applied Physics

The structures of electroplated and vapor-deposited copper films have been studied by x-ray diffraction. While there was no evidence of stacking faults in any of these films, the electroplated films were characterized by presence of twins, large thickness-dependent microstrains, and small particle sizes. The vapor-dep…

Metal and Thin Film MechanicsElectrodeposition and Electroless CoatingsCopper Interconnects and Reliability

Production of High Quasipermanent Charge Densities on Polymer Foils by Application of Breakdown Fields

G. M. Sessler、J. E. West1972-03-01Journal of Applied Physics

Charge deposition on 2–25-μ m polyethylene terephthalate (PET), polyfluoroethylenepropylene (FEP), and polycarbonate (PC) foils by application of fields up to, and exceeding breakdown strength in the polymers is reported. The greatest negative or positive charge densities on PET foils metalized on one side are in exce…

High voltage insulation and dielectric phenomenaElectrostatic Discharge in ElectronicsElectrohydrodynamics and Fluid Dynamics

Interpretation of Fractographs of SCC in Hexagonal Metals

I. J. R. Aitchison、B. Cox1972-03-01CORROSION

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Facebook Twitter LinkedIn Email Tools Icon Tools Get Permissions Cite Icon Cite Search Site Citation I. AITCHISON, B. COX; Interpretation of Fractographs of SCC in Hexagonal Metals. CORROSION 1 March 1972; 28…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Pyrochlores. VII. The Oxides of Antimony: an X-Ray and Mössbauer Study

David J. Stewart、Osvald Knop、Conrad Ayasse 等 4 位作者1972-03-01Canadian Journal of Chemistry

Antimonic acid cannot be dehydrated by heating in air to give products of constant and reproducible weight without simultaneous reduction of some of the Sb V to Sb III . Neither anhydrous Sb 2 O 5 nor the hydroxy oxide Sb 3 O 6 OH postulated by Dihlström and Westgren can be obtained by this method. Two well-defined pr…

Glass properties and applicationsCrystal Structures and PropertiesNuclear materials and radiation effects

EPR Studies of Ti3+–H+ Centers in X-Irradiated α-Quartz

H. Rinneberg、John A. Weil1972-03-01The Journal of Chemical Physics

Two titanium centers (A–Ti–H and B–Ti–H) are formed in equal concentrations by reaction of hydrogen atoms with Ti4+ in the α-quartz lattice at 120°K. Above 150°K, B–Ti–H transforms into A–Ti–H. The spin Hamiltonians, including 47,49Ti hyperfine and nuclear quadrupole terms, have been determined by 9.850-GHz EPR at 20°…

Solid-state spectroscopy and crystallographyAmmonia Synthesis and Nitrogen ReductionChemical Synthesis and Characterization

Dynamisches Verhalten und Kinetik der Kohlenmonoxid‐Oxidation am Platin‐Katalysator

P. Hugo、Manuel Jakubith1972-03-01Chemie Ingenieur Technik

Abstract In einem Durchfluß‐Kreislaufreaktor wurden bei der CO‐Oxidation an Platin unter isothermen Bedingungen sprunghafte Instabilitäten und periodisches Verhalten beobachtet. Die sprunghaften Instabilitäten lassen sich mit der gemessenen Formalkinetik deuten. Die Deutung des periodischen Reaktionsablaufes wird unte…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

A phenomenological theory of dielectric and mechanical properties of improper ferroelectric crystals

J. Kobayashi、Y. Enomoto、Y. Sato1972-03-01physica status solidi (b)

Abstract A phenomenological theory has been developed for explaining the anomalous dielectric and electro‐mechanical properties of some improper ferroelectrics. An ordering parameter 8, which plays the role of a trigger for the onset of the spontaneous polarization P is introduced into the thermodynamical potential fu…

Crystal Structures and PropertiesAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

New Noncrystalline Germanium which Crystallizes ``Explosively'' at Room Temperature

Takeshi Takamori、R. Messier、Rustum Roy1972-03-01Applied Physics Letters

We report herein the preparation of a form of noncrystalline Ge film by rf sputtering on to various substrates, which crystallizes with ``explosive'' velocities when triggered by a localized transient energy pulse. The films show this phenomenon only when they are thicker than about 10 μ. The crystallization wave appe…

Photorefractive and Nonlinear OpticsSilicon Nanostructures and PhotoluminescencePhase-change materials and chalcogenides

Characterization of the structure and organization of β‐form crystals in type III and type IV isotactic polypropylene spherulites

Robert J. Samuels、R. Y. Yee1972-03-01Journal of Polymer Science Part A-2 Polymer Physics

Abstract Anisotropic growth of β‐form crystals of isotactic polypropylene in type III and type IV spherulites has made possible microanalysis of the unit cell structure, optical properties, and crystal arrangement within the spherulites. Micro x‐ray studies of the type III and type IV spherulites show that interspheru…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Neutron-Scattering Analysis of the Linear-Displacement Correlations in KTaO3

R. Comès、G. Shirane1972-03-01Physical review. B, Solid state

In view of recent x-ray experiments which detected a surprisingly strong diffuse scattering in the {100} reciprocal sheets of KTa${\mathrm{O}}_{3}$, a new neutron-scattering investigation was performed to determine the origin of this scattering. It was found that a strong anisotropy in the dispersion of the low-lying…

Ferroelectric and Piezoelectric MaterialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Spin Relaxation in Nematic Solvents

Pier Luigi Nordio、G. Rigatti、Ulderico Segre1972-03-01The Journal of Chemical Physics

The electron spin relaxation processes for oblate and prolate symmetric top paramagnetic probes dissolved in liquid crystals are studied by solving the diffusion equation for molecules subjected to an orienting potential, expressed as a series expansion of Legendre polynomials. The line shape variations upon ordering…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesMolecular spectroscopy and chirality

Electron Microscope Image Contrast for Thin Crystal

J. M. Cowley、Sumio Iijima1972-03-01Zeitschrift für Naturforschung A

Abstract High resolution electron microscope images showing the detailed distribution of metal atoms within the unit cells of complex oxide structures have been recorded recently and as a first approximation may be interpreted as amplitude-object images if obtained with the degree of defocus corresponding to the "opti…

Advanced Electron Microscopy Techniques and ApplicationsAdvanced X-ray Imaging TechniquesElectron and X-Ray Spectroscopy Techniques

Carbon Monoxide Oxidation on a Pt(110) Single Crystal Surface

H.P. Bonzel、R. Ku1972-03-01Journal of Vacuum Science and Technology

The catalytic reaction between CO and O2 on a Pt (110) surface is investigated by residual gas analysis for different partial pressures of CO and O2 and various temperatures. The surface cleanliness of the Pt crystal is monitored by Auger electron spectroscopy. The results of the reaction study are generally in agreem…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Spin Dynamics in the One-Dimensional Antiferromagnet(CD3)4NMnCl3

M. T. Hutchings、G. Shirane、R. J. Birgeneau 等 4 位作者1972-03-01Physical review. B, Solid state

Recent studies of the instantaneous magnetic correlations in ${(\mathrm{C}{\mathrm{D}}_{3})}_{4}$NMn${\mathrm{Cl}}_{3}$ using quasielastic-neutron-scattering techniques have shown that the Mn${\mathrm{Cl}}_{3}$ chains in this compound exhibit purely one-dimensional paramagnetic behavior down to 1.1 \ifmmode^\circ\else…

Physics of Superconductivity and MagnetismTheoretical and Computational PhysicsMagnetism in coordination complexes

On the magnetizations of the phase in alnico alloys

G. Bégin、A. Dubé1972-03-01IEEE Transactions on Magnetics

The electrochemical properties of the Alnico alloys are shown to be sensitive to their state of precipitation. These properties thus are used as an indirect means for evaluating the individual properties of the ferromagnetic phases in these alloys. Results are then compared with recent findings and are shown to agree…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Magnetomechanical Damping and Magnetic Properties of Iron Alloys

J. Robert Birchak、G. Smith1972-03-01Journal of Applied Physics

This work investigates experimentally a recent model of magnetomechanical damping based on a distribution of internal stresses, verifies some predictions and extends the model. Damping results are reported for cast irons and iron alloyed with silicon or germanium. As predicted, the maximum magnetomechanical damping ψm…

Electric Motor Design and AnalysisMicrostructure and Mechanical Properties of SteelsMagnetic Properties and Applications