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Investigation of Polypyrrole-Based Iron Electrodes as Supercapacitors

Aziz Yağan2019-03-10International Journal of Electrochemical Science

Polypyrrole (PPy) was successfully electropolymerized potentiodynamically on prepassivated Fe electrode in an aqueous solution containing monomer and oxalic acid. Electropolymerization of PPy was performed between 0.3 V and 0.8 V vs SCE with a scan rate of 20 mV/s. Electrochemical properties of PPy coated Fe electrode…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsConducting polymers and applications

Activated Porous Carbon Nanofibers for High-Performance Supercapacitors

Moyinul Islam、Xing Lü2019-03-10International Journal of Electrochemical Science

The pursuit of high-capacitance carbon materials is urgently needed for supercapacitors, which are among the most promising energy storage devices. Herein, we developed an effective KOH-activation method to improve the porous structures of electrospun carbon nanofibers for high-performance supercapacitors. In detail,…

Supercapacitor Materials and FabricationConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Protein Powder Derived Porous Carbon Materials as Supercapacitor Electrodes

Ben Niu、Mengying Yuan、Feng Jiang 等 4 位作者2019-03-10International Journal of Electrochemical Science

Protein-based microporous carbon (PMC) with high nitrogen, sulfur content and the specific surface area was obtained from commercial protein powder (PP) by KOH activation. Many interconnected micropores and mesopores were formed in the carbonization process, the specific surface area of the PMC was up to 1117 m 1 g -1…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsConducting polymers and applications

Gas phase selective hydrogenation of phenylacetylene to styrene over Au/Al2O3

Xiaodong Wang、Mark A. Keane2019-03-10Journal of Chemical Technology & Biotechnology

Abstract BACKGROUND Trace quantities of phenylacetylene can poison styrene polymerisation catalysts. The phenylacetylene content must be less than 10 ppm and selective hydrogenation (to styrene) is viewed as a viable process solution. High styrene selectivities have been achieved in batch liquid phase operations while…

Catalytic Processes in Materials ScienceCatalysis for Biomass ConversionCatalysis and Hydrodesulfurization Studies

Effect of Size Polydispersity on the Pitch of Nanorod Cholesterics

H. H. Wensink2019-03-10Crystals

Many nanoparticle-based chiral liquid crystals are composed of polydisperse rod-shaped particles with considerable spread in size or shape, affecting the mesoscale chiral properties in, as yet, unknown ways. Using an algebraic interpretation of Onsager-Straley theory for twisted nematics, we investigate the role of le…

Liquid Crystal Research AdvancementsLipid Membrane Structure and BehaviorSurfactants and Colloidal Systems

Facile Solvothermal Preparation and Electrochemical Properties of Fe-doped CaTi2O4(OH)2 for Supercapacitors

Qifu Bao、Weixia Dong、Gu Xingyong 等 5 位作者2019-03-10International Journal of Electrochemical Science

Fe-doped CaTi2O4(OH)2 cathode materials for supercapacitors were synthesized by a facile hydrothermal method. The effects of Fe-doping ion content on the electrochemical performance of CaTi2O4(OH)2 were studied by galvanostatic charge/discharge and cyclic voltammetry measurements. The optimal Fe-doping ion content x w…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationCatalytic Processes in Materials Science

Evaluation of rare‐earth element dopants (Sm and Er) on ablation resistance of ZrB 2 /SiC‐sintered billets

Angel A. Peña、Jonathan P. Vernon、Rodney W. Trice2019-03-10Journal of the American Ceramic Society

Abstract In this paper, how rare‐earth element dopants (samarium and erbium) affect the scale development of sintered ZrB 2 /SiC (ZBS) samples during ablation testing was investigated. ZBS billets with five different Sm to Er ratios, with a nominal total amount of 3 mol% dopant incorporated, were prepared by sintering…

Advanced ceramic materials synthesisGlass properties and applicationsThermal properties of materials

Formation of Fe-Sn intermetallic layer and its effect on the corrosion of 304 stainless steel in high temperature water

Jianjun Guan、Hong-yuan Zhong、Feng Li 等 8 位作者2019-03-10International Journal of Electrochemical Science

Fe-Sn compound layer on interface was studied during the interaction between liquid Sn and 304 stainless steel (304 SS), and the effect of the intermetallics on the corrosion of 304 SS in 300 °C high temperature water was researched. The experimental results indicate that a (Fe, Cr)Sn2 compound layer forms at the Sn/3…

Hydrogen embrittlement and corrosion behaviors in metalsMetallurgical Processes and ThermodynamicsMaterial Properties and Failure Mechanisms

High Temperature Effectiveness of Ginger Extract as Green Inhibitor for Corrosion in Mild Steel

Muhammad Sohail、Fayaz Hussain、Ali Dad Chandio 等 4 位作者2019-03-10NUST Journal of Engineering Sciences

Corrosion is one of the major problems of mild steels in acidic medium. This can be minimized by the application of corrosion inhibitors, however; the most of inhibitors are toxic in nature. Therefore inhibitors from green sources are highly desirable to maintain the sustainability of the environmental system. Consequ…

Corrosion Behavior and InhibitionPolymer composites and self-healingConcrete Corrosion and Durability

Dawson-Type Vanadium-Substituted Tungstophosphate- Modified ITO Electrode: Preparation, Characterization and Electrochemical Determination of Dopamine

Xinming Wang、Yuanqing Zhao、Di Zhang 等 5 位作者2019-03-10International Journal of Electrochemical Science

In this work, we describe a robust composite film-modified indium tin oxide (ITO) electrode with improved detection capabilities for an example neurotransmitter, dopamine (DA). The composite film was developed by the combination of a Dawson-type vanadium tungstophosphate, α2- K7P2W17VO62·18H2O (P2W17V), and cationic c…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Performance Analysis of a Direct Carbon Fuel Cell Cogeneration System Combined with a Two-Stage Thermoelectric Generator

Jiahui Liu、Houcheng Zhang、Jiatang Wang 等 8 位作者2019-03-10International Journal of Electrochemical Science

A new cogeneration system model consisting of a DCFC (direct carbon fuel cell), a TTEG (two-stage thermoelectric generator) and a regenerator is proposed, where the DCFC directly and efficiently converts the chemical energy of carbon into electricity and waste heat, and the TTEG harvests the waste heat for additional…

Advanced Battery Materials and TechnologiesFuel Cells and Related MaterialsAdvanced Thermoelectric Materials and Devices

Corrosion Inhibition Effect of some Pyridopyrimidine Derivatives for Carbon Steel in 0.5 M HCl Solution

Samar Y. Al‐nami2019-03-10International Journal of Electrochemical Science

The impact of some Pyridopyrimidine derivatives on the corrosion of carbon steel (CS) in 0.5M HCl was examined utilizing mass loss (ML), potentiodynamic polarization (PP), AC impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. The inhibition efficiency (IE) increases with increasing…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsConcrete Corrosion and Durability

Corrosion Behavior of Aluminum in Carbon Dioxide Aqueous Solution at 50 oC

Daoyu Li、Zhen Shi、Huaping Xu 等 10 位作者2019-03-10International Journal of Electrochemical Science

In this work, the corrosion behavior of aluminum in carbon dioxide solutions with different concentrations at high temperature (50 o C) was studied. The corrosion of aluminum in the carbon dioxide solutions was inhibited to a certain extent compared to the corrosion in deionized water. It was found that an aluminum el…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Development of transferrin-modified poly(lactic-co-glycolic acid) nanoparticles for glioma therapy

Jinning Mao、Xiangfu Meng、Chao Zhao 等 5 位作者2019-03-10Anti-Cancer Drugs

Glioma is a primary intracranial malignant tumor with poor prognosis. In this study, we aimed to develop transferrin (Tf)-modified poly(lactic-co-glycolic acid) (PLGA) nanoparticles to deliver temozolomide (TMZ) to glioma and evaluate their efficacy to kill glioma. TMZ-loaded nanoparticles were prepared by nanoprecipi…

Nanoparticle-Based Drug DeliveryGlioma Diagnosis and TreatmentNanoplatforms for cancer theranostics

A Brief Communication on the Improved Mechanism of Graphene on Zinc-Rich Coatings

Xiao Wang、Si Chen、Rui Ding 等 9 位作者2019-03-10International Journal of Electrochemical Science

Gallic acid-based epoxy resin monomer was synthesized by the natural extract of gallnut for the efficient dispersion of graphene in epoxy resin. The graphene zinc-rich anticorrosion coatings were further prepared on the basis of the graphene / gallic acid-based epoxy resin monomer dispersion system. Electrochemical ex…

Graphene research and applicationsCorrosion Behavior and InhibitionElectrodeposition and Electroless Coatings

Electrical and Optical Properties of a Transparent Conductive ITO/Ga2O3/Ag/Ga2O3 Multilayer for Ultraviolet Light-Emitting Diodes

Siwei Liang、Quanbin Zhou、Xianhui Li 等 5 位作者2019-03-10Nanomaterials

We fabricated an indium tin oxide (ITO)/Ga2O3/Ag/Ga2O3 multilayer as a transparent conductive electrode for ultraviolet light-emitting diodes (UV LEDs). The electrical and optical properties of the multilayer were improved by optimizing the annealing temperature of the ITO contact layer and the whole ITO/Ga2O3/Ag/Ga2O…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Synthesis and mechanical properties of para‐aramid nanofibers

Morgana M. Trexler、Christopher M. Hoffman、Douglas A. Smith 等 10 位作者2019-03-10Journal of Polymer Science Part B Polymer Physics

ABSTRACT Scalable, bottom‐up chemical synthesis and electrospinning of novel Cl ‐ substituted poly( para ‐phenylene terephthalamide) (PPTA) nanofibers are herein reported. To achieve Cl‐PPTA nanofibers, the chemical reaction between the monomers was precisely controlled, and dissolution of the polymer into solvent was…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsFiber-reinforced polymer composites

Determination of Crystal Growth Geometry Factors and Nucleation Site Densities of Electrodeposited Ferromagnetic Cobalt Nanowire Arrays

Ryusei Saeki、Takeshi Ohgai2019-03-10Crystals

The time-dependence of electrochemical reduction current, which was observed during the one-dimensional (1-D) crystal growth of ferromagnetic cobalt nanowire arrays, was analyzed by Johnson–Mehl–Avrami–Kolmogorov (JMAK) theory. Textured hcp-Co nanowire arrays were synthesized by potentio-static electrochemical reducti…

Electrodeposition and Electroless CoatingsAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Electrochemical Studies of the Inhibition Effect of Vitamin B1 and Bromide Ion on the Carbon Steel Corrosion in Phosphoric Acid Solution

Yan-Ju Yang、Y. Li、Lin Wang 等 6 位作者2019-03-10International Journal of Electrochemical Science

This paper investigates the inhibition effects of Vitamin B1 without and with bromide ion on carbon steel corrosion in 1.0 mol/L phosphoric acid solution using potentiodynamic polarization and electrochemical impedance spectroscopy techniques. The results indicate that combination of Vitamin B1 and bromide ion perform…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability