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Multilayer graphene functionalized through thermal 1,3-dipolar cycloadditions with imino esters: a versatile platform for supported ligands in catalysis

Marcos Ferrándiz-Saperas、Alessio Ghisolfi、Diego Cazorla‐Amorós 等 5 位作者2019-01-01Chemical Communications

Multilayer graphene (MLG), obtained by mild sonication of graphite in NMP or pyridine, was fully characterized via atomic force microscopy (AFM), transmission electron microscopy (TEM), Raman spectroscopy and X-ray photoemission spectroscopy (XPS). Then, it was functionalized via 1,3-dipolar cycloaddition with azometh…

Graphene research and applications2D Materials and ApplicationsMolecular Junctions and Nanostructures

Oxidation of Powdered Aluminum after Surface Modification with Mn, Fe, Co, and Ni Formates

В. Г. Шевченко、В. Н. Красильников、D. A. Yeselevich 等 4 位作者2019-01-01Protection of Metals and Physical Chemistry of Surfaces

Abstract The effect of small additives of manganese, iron, cobalt, and nickel oxides on the oxidation of aluminum powder of ASD-4 grade while heating in air is studied. Composites of Al/MOx were prepared by impregnating the metal powder with saturated solutions of M(HCOO)2 ⋅ 2H2O (M = Mn, Fe, Co, and Ni) formates and…

Energetic Materials and CombustionThermal and Kinetic AnalysisMaterial Properties and Applications

Effect of hybrid SiO 2 @Ag nanoparticles with raspberry-like morphology on the excited states of the photosensitizers Rose Bengal and riboflavin

Joaquín E. Martínez Porcel、María Belén Rivas Aiello、Valeria B. Arce 等 6 位作者2019-01-01New Journal of Chemistry

Ag <sup>+</sup> is released due to a charge transfer process from the triplet state of adsorbed riboflavin to the silver nanoparticles.

Electrochemical sensors and biosensorsQuantum Dots Synthesis And PropertiesPorphyrin and Phthalocyanine Chemistry

Heteroatom-doped hollow carbon spheres made from polyaniline as an electrode material for supercapacitors

Haiyan Liu、Mei Han、Jinzong Zuo 等 9 位作者2019-01-01RSC Advances

and excellent rate capability. The excellent electrochemical performance can be attributed to the heteroatom-doping and hollow carbon nanostructure of the HHCSs electrodes. Heteroatom groups in the HHCSs not only improve the wettability of the carbon surface, but also enhance the capacitance by addition of a pseudocap…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesConducting polymers and applications

Hydroxyapatite Coating on Fluorine-treated Magnesium Alloy by Hydrothermal Method and Its Electrochemical Corrosion Behaviour in Hank’s Solution

Chunyan Zhang、Yanlong Ma、Liu Chenglong2019-01-01Protection of Metals and Physical Chemistry of Surfaces

Abstract In order to improve the corrosion resistance and biocompatibility of magnesium alloys, hydroxyapatite (HA) coating with an outer chrysanthemum-like crystals layer and an inner needle-like crystals layer was successfully prepared on fluorine-treated AZ31 magnesium alloy by hydrothermal treatment. The needle-li…

Magnesium Alloys: Properties and ApplicationsHydrogen Storage and MaterialsMXene and MAX Phase Materials

Study of the structural and morphological properties of copper catalysts supported on Al2O3 and TiO2 synthesized by the impregnation method

Germana Arruda de Queiroz、Celmy Barbosa2019-01-01Matéria (Rio de Janeiro)

Aluminum oxide and titanium oxide are widely used as catalytic support. Due to their characteristics and properties, they have several applications such as chemical processes, photocatalysis and pollution control. In this work, the catalytic supports of Al2O3 and TiO2 were impregnated with 2% of copper oxide by the me…

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

High-valence-state manganate( v ) Ba 3 Mn 2 O 8 as an efficient anode of a proton-conducting solid oxide steam electrolyzer

Hajime Toriumi、Taisei Kobayashi、Satoshi Hinokuma 等 9 位作者2019-01-01Inorganic Chemistry Frontiers

High-valence-state Mn( <sc>v</sc> ) oxide Ba <sub>3</sub> Mn <sub>2</sub> O <sub>8</sub> exhibits good performances for the anodic OER on H <sup>+</sup> -SOEC.

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsAdvanced battery technologies research

Improving hygiene performance of microfiber synthetic leather base by mixing polyhydroxybutyrate nanofiber

Yongchao Duo、Xiaoming Qian、Baobao Zhao 等 5 位作者2019-01-01Journal of Engineered Fibers and Fabrics

Compared with natural leather, microfiber synthetic leather has many excellent properties such as chemical resistance and physical and mechanical properties. However, the preparation of high performance microfiber synthetic leather with excellent water vapor transmission rate, moisture absorption, and wearing comfort…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Varying oxygen coverage on Cu 55 and its effect on CO oxidation

Li Ma、Jaakko Akola2019-01-01Physical Chemistry Chemical Physics

(100) have been studied as a function of oxygen coverage. The CO oxidation reaction barrier is rather insensitive to the oxygen coverage regardless of the support, indicating a small increase in activity with the number of surface oxygen atoms.

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Liposomes; from synthesis to targeting macrophages

D.A. Powers、Nasim Nosoudi2019-01-01Biomedical Research

Liposomes are a proposed tool to use for cell and tissue specific drug targeting. Because of their phospholipid membranes and carrying capacity within their spheres, liposomes are of particular interest for clinical applications. Stealth liposomes are especially important for these clinical applications because they a…

Nanoparticle-Based Drug DeliveryLipid Membrane Structure and BehaviorRNA Interference and Gene Delivery

The influence of organically intercalated montmorillonites on the interfacial tension and structure of oil-in-water nanoemulsions

Fangfang Peng、Yangchuan Ke、Yi Zhao 等 5 位作者2019-01-01RSC Advances

% w/v OMt. In addition, light transmission measurements showed that the transmission of the nanoemulsions varied with temperature, and the process was reversible. The mechanisms of these phenomena were analyzed and confirmed by TEM.

Surface Modification and SuperhydrophobicitySurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Unexpected hydrolytic transformation of new type hybrid bromobismuthates with methylpyrazinium dications

Vitalii Yu. Kotov、Andrey B. Ilyukhin、Petr A. Buikin 等 8 位作者2019-01-01Dalton Transactions

) are low in comparison with those for similar systems which is most likely due to the cooperative effect involving the nature of the corresponding cations together with the features of the supramolecular structures of the complexes.

Crystallography and molecular interactionsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Modeling Conformationally Flexible Proteins With X-ray Scattering and Molecular Simulations

Kyle T. Powers、Melissa Gildenberg、M. Todd Washington2019-01-01Computational and Structural Biotechnology Journal

Proteins and protein complexes with high conformational flexibility participate in a wide range of biological processes. These processes include genome maintenance, gene expression, signal transduction, cell cycle regulation, and many others. Gaining a structural understanding of conformationally flexible proteins and…

Protein Structure and DynamicsDNA Repair MechanismsEnzyme Structure and Function

Low Temperature Thermal Conductivity of Heavily Boron-Doped Synthetic Diamond: Influence of Boron-Related Structure Defects

D. D. Prikhodko、С. А. Тарелкин、В. С. Бормашов 等 9 位作者2019-01-01Journal of Superhard Materials

Thermal conductivity of single-crystal boron-doped diamonds (BDD) with ∼2 × 10 19 cm −3 (∼120 ppm) and 5 × 10 19 cm −3 (∼300 ppm) boron content was studied by a steady-state method in a temperature range of 20–400 K. The obtained data were analyzed within Callaway model framework. The values of dislocation density obt…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchThermal properties of materials

A label-free ratiometric fluorescence nanoprobe for ascorbic acid based on redox-modulated dual-emission signals

Yuhao Sheng、Tingwei Cao、Yan Xiao 等 6 位作者2019-01-01The Analyst

could combine with the surface ligands of AuNCs, accompanied by a reduction in the luminescence intensity of the AuNCs. Therefore, the fluorescence intensity ratio of PFO dots to AuNCs would be related to the concentration of AA. The nanoprobe enabled highly sensitive analysis of AA with a detection limit of 1.9 μM an…

Electrochemical sensors and biosensorsCarbon and Quantum Dots ApplicationsElectrochemical Analysis and Applications

Tailoring the interparticle distance in Langmuir nanoparticle films

Monika Hofbauerová、Ana Hološ、Peter Nádaždy 等 11 位作者2019-01-01Physical Chemistry Chemical Physics

The ability to control the interparticle distance in self-assembled arrays of nanoparticles plays an important role in a large number of applications, which require tunable electronic and photonic properties. Importantly, practical applications in real devices rely on arrays satisfying more stringent requirements of l…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesGas Sensing Nanomaterials and Sensors

Understanding the interaction of gold and silver nanoparticles with natural organic matter using affinity capillary electrophoresis

Adam T. Sutton、R. Dario Arrua、Stuart C. Thickett 等 5 位作者2019-01-01Environmental Science Nano

Nanoparticles (NPs) undergo a number of changes in environmental systems which are often influenced by their interaction with natural organic matter (NOM).

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical Analysis and Applications