Materials Literature
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Abstract Magnetic dipole interactions are dominate in quasi one‐dimensional (1D) molecular magnetic materials, in which TbNcPc units (Tb 3+ =terbium(III) ion, Nc 2− =naphthalocyaninato, Pc 2− =phthalocyaninato) adopt a structure similar to TbPc 2 single‐molecule magnets (SMMs). The magnetic properties of the [TbNcPc]…
Nanocrystalline BaFe 2 O 4 has been prepared through low temperature pyrophoric reaction method. The structural, dielectric and electrical transport properties of BaFe 2 O 4 are investigated in detail. AC electrical properties have been studied over the wide range of frequencies with applied dc magnetic fields and tem…
Structural changes in tridymite have been investigated by molecular dynamics simulation. Two thermal processes were carried out, one cooling from the high-temperature hexagonal structure of tridymite (HP-tridymite) and the other heating from the low-temperature monoclinic structure of tridymite (MX1-tridymite). The fo…
ABSTRACT In order to overcome the brittle fracture characteristics of polyamides, the study on high efficiency toughening of polyamides is always a hot topic. In this article, n ‐ethyl‐ p ‐toluene sulfonamide (N‐PTSA) was used as the toughening agent in polyamide 6 (PA6) matrix. The PA6/N‐PTSA composites were prepared…
This paper describes the influence of electron scattering from disordered grain boundaries on the carrier transport in polycrystalline Al‐doped ZnO (AZO) thin films prepared with electron concentrations on the order of 10 20 cm −3 . It is found that in degenerate AZO thin films prepared on glass substrates by various…
A thermally highly stable molecular self-assembly (nanocube) in water, the decomposition temperature of which is 415 K, was developed by designing a gear-shaped amphiphile (GSA) with an indented hydrophobic surface, even though the nanocube is stabilized only by van der Waals (vdW) and cation-π interactions as well as…
Tetrapodal ZnO (T‐ZnO) and aerographite networks represent two highly open porous (94.6 and 99.96%, respectively) model materials on which the impact of an atmospheric‐pressure plasma was studied for the first time. The air plasma treatment by a surface barrier discharge caused remarkable surface modifications on the…
Abstract Constructing advanced functional nanomaterials with pre‐designed organized morphologies from low‐dimension synthetic and biological components is challenging. Herein, we report an efficient and universal amphiphilicity‐driven assembly strategy to construct “hairy” flexible hybrid nanosheets with a 1D cellulos…
Abstract Crystal structures, single‐molecule magnetic behavior, and ab initio calculations of four new phenoxo‐bridged dinuclear dysprosium complexes and their gadolinium(III) analogues are explored. Complexes [Dy 2 (DMOMP) 2 (DBM) 4 ] 2 ⋅ CHCl 3 ( 1 ; DMOMP=1‐methyl‐3,5‐dimethoxy‐4‐hydroxybenzene, DBM=1,3‐diphenylpro…
The polyaniline (PANI)‐coated functionalized multi‐walled carbon nanotubes (f‐CNTs) and silver nanoparticles (AgNPs) (PANI@f‐CNTs and PANI@AgNPs hybrid nanofillers) are synthesized by means of in situ polymerization of aniline monomer on the surface of f‐CNTs and AgNPs. The PANI@f‐CNTs and PANI@AgNPs hybrid nanofiller…
Abstract Diarylamine‐fused subporphyrins 1 a and 1 b were synthesized from β,β‐diiodo‐ meso ‐chloro subporphyrin 2 through a one‐pot procedure involving nucleophilic aromatic substitution and S RN 1‐type intramolecular fusion reaction as the first example of meso ‐nitrogen‐embedded subporphyrin. While non‐fused counte…
Abstract Ultra‐small superparamagnetic iron oxide (USPIO) nanoparticles provide a safer alternative to gadolinium‐based contrast agents (GBCAs) in T1‐weighted MR imaging. MRI contrast behavior of USPIOs depends on their magnetic properties, which in turn depend on their physicochemical composition. Identifying and tai…
A series of dicarboxylates bridged titanium-oxo clusters with {Ti 3 (μ 3 -O)} building units have been synthesized through facile one-step solvothermal reactions. It is interesting to find that the geometric characteristics of the obtained supramolecular structures highly depend on the configuration of the applied dic…
Theranostic-based nanomedicine plays a crucial role in the field of cancer therapy. This is due to having the capability to combine both therapy and diagnosis together in a single system. Herein a new class of metal–ligand-based nanocarrier in a norbornene backbone has been designed as a theranostic system. Fe 3+ -ter…
Superabsorbent polymer nanocomposites (SAPCs) are very promising and versatile materials for biomedical applications. In this research work, we focused on a novel nanocellulose‐based SAPC, poly(acrylic acid‐ co ‐2‐hyderoxy ethyl methacrylate)‐grafted cellulose nanocrystal (CNC) composite, P(AA‐ co ‐HEMA)‐ g ‐CNC as a…
Identification of insulation defects in gas insulated metal-enclosed switchgear (GIS) is important for partial discharge (PD) evaluation. This article proposes a polar coordinate pattern approach to characterize the different kinds of defect types. These defect types include floating electrodes, a fixed protrusion on…
Heat treatment of cubic YbZrF 7, after quenching from 1000 °C, leads to a material displaying precisely zero thermal expansion at ∼300 K and negative thermal expansion at lower temperatures. The zero thermal expansion is associated with a minimum in the lattice constant at ∼300 K. X-ray total scattering measurements a…
Shape-selective solution-phase nanocrystal growth is facilitated by capping agents, or structure-directing agents (SDAs), which guide shape evolution. It is often stated that these chemical additives impart shape selectivity by promoting nanocrystals with a majority of facets to which they bind most strongly. However,…
The accuracy of spatiotemporal control cargo delivery and release are primordial to enhance the therapeutic efficiency and decrease the undesirable effects, in this context a novel prodrug were developed based on biocompatible polyvinyl alcohol (PVA) substrate. PVA was conjugated to doxorubicin (PVA-DOX) via an acid-l…
Abstract A series of Ca 5 ( PO 4 ) 3 F:Dy 3+ , Eu 3+ phosphors was synthesized by a solid‐state reaction method. The XRD results show that all as‐prepared Ca 5 ( PO 4 ) 3 F:Dy 3+ , Eu 3+ samples match well with the standard Ca 5 ( PO 4 ) 3 F structure and the doped Dy 3+ and Eu 3+ ions have no effect on the crystal st…