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Controlled Pore Sizes in Monolayer C2N Act as Ultrasensitive Probes for Detection of Gaseous Pollutants (HF, HCN, and H2S)

Kalishankar Bhattacharyya、Saied Md Pratik、Ayan Datta2018-01-10The Journal of Physical Chemistry C

Porous two-dimensional monolayers have gained interest both in theoretical and experimental research because of their controlled pore size and evenly distributed holes within the basal plane. Herein, we have investigated the efficient trapping of three pollutants (HF, HCN, and H 2 S) on the recently synthesized porous…

Graphene research and applications2D Materials and ApplicationsGas Sensing Nanomaterials and Sensors

Study of electropolymerized PEDOT:PSS transducers for application as electrochemical sensors in aqueous media

Abdel Mohsen Benoudjit、Mamoun M. Bader、Wan Wardatul Amani Wan Salim2018-01-10Sensing and Bio-Sensing Research

Electropolymerized poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) onto screen-printed platinum electrodes was tested for stable charge/discharge cycle using cyclic voltammetry (CV) in aqueous media and its adhesion to the electrode surface was also examined. Electropolymerized PEDOT:PSS maintaine…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Removal of Hardness from Water Samples by a Carbonation Process with a Closed Pressure Reactor

Min Cheol Ahn、Chilakala Ramakrishna、Choon Han 等 4 位作者2018-01-10Water

One of the undesirable characteristics of some ground and natural water sources is hardness. Hard water can cause many problems around the world, including increased scaling on water pipes, boilers, atopic eczema and odd-tasting drinking water. Hardness in natural water is caused by dissolved minerals, mainly calcium…

Groundwater and Isotope GeochemistryCalcium Carbonate Crystallization and InhibitionMine drainage and remediation techniques

Origin of Photoluminescence of Ag25(SR)18– Nanoparticles: Ligand and Doping Effect

K. L. Dimuthu M. Weerawardene、Christine M. Aikens2018-01-10The Journal of Physical Chemistry C

Recent theoretical insights into the origin of photoluminescence of thiolate-protected gold nanoclusters raise the question of whether the observed luminescence mechanism is valid for related silver nanoparticles. To this end, we perform density functional theory (DFT) and time-dependent density functional theory (TDD…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Development and biocompatibility evaluation of biodegradable bacterial cellulose as a novel peripheral nerve scaffold

Yuanjing Hou、Xinyu Wang、Jing Yang 等 6 位作者2018-01-10Journal of Biomedical Materials Research Part A

Abstract Peripheral nerve injury is a serious medical problem and severely affects normal life of patient. Bacterial cellulose (BC) is considered as a novel promising biomaterial for tissue engineering, but the poor biodegradability limits its application. In this study, biodegradable bacterial cellulose scaffolds wer…

Advanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical ApplicationsWound Healing and Treatments

A prebiotic template-directed peptide synthesis based on amyloids

Saroj K. Rout、Michael P. Friedmann、Roland Riek 等 4 位作者2018-01-10Nature Communications

Abstract The prebiotic replication of information-coding molecules is a central problem concerning life’s origins. Here, we report that amyloids composed of short peptides can direct the sequence-selective, regioselective and stereoselective condensation of amino acids. The addition of activated DL-arginine and DL-phe…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsOrigins and Evolution of Life

Charge-Transfer-Induced p-Type Channel in MoS2 Flake Field Effect Transistors

Sung‐Wook Min、Minho Yoon、Sung Jin Yang 等 5 位作者2018-01-10ACS Applied Materials & Interfaces

The two-dimensional transition-metal dichalcogenide semiconductor MoS 2 has received extensive attention for decades because of its outstanding electrical and mechanical properties for next-generation devices. One weakness of MoS 2, however, is that it shows only n-type conduction, revealing its limitations for homoge…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Compatibility between Co-Metallized PbTe Thermoelectric Legs and an Ag–Cu–In Brazing Alloy

Dana Ben-Ayoun、Yatir Sadia、Yaniv Gelbstein2018-01-10Materials

In thermoelectric (TE) generators, maximizing the efficiency of conversion of direct heat to electricity requires the reduction of any thermal and electrical contact resistances between the TE legs and the metallic contacts. This requirement is especially challenging in the development of intermediate to high-temperat…

Advanced Thermoelectric Materials and DevicesElectronic Packaging and Soldering TechnologiesHeusler alloys: electronic and magnetic properties

Introduction of Boron Functionalities into Silsesquioxanes: Novel Independent Methodologies

Joanna Kaźmierczak、Krzysztof Kuciński、Hanna Stachowiak 等 4 位作者2018-01-10Chemistry - A European Journal

Owing to their versatile application possibilities, silsesquioxanes (SQs) are of considerable interest for creating hybrid inorganic-organic materials. In this report, two novel and independent strategies for the direct attachment of boron functionalities to silsesquioxanes are presented. Encouraged by our previous wo…

Advanced ceramic materials synthesisOrganoboron and organosilicon chemistrySilicone and Siloxane Chemistry

Mechanism of fast lattice diffusion of hydrogen in palladium: Interplay of quantum fluctuations and lattice strain

Hajime Kimizuka、Shigenobu Ogata、Motoyuki Shiga2018-01-10Physical review. B./Physical review. B

Understanding the underlying mechanism of the nanostructure-mediated high diffusivity of H in Pd is of recent scientific interest and also crucial for industrial applications. Here, we present a decisive scenario explaining the emergence of the fast lattice-diffusion mode of interstitial H in face-centered cubic Pd, b…

Hydrogen Storage and MaterialsNuclear Physics and ApplicationsQuantum, superfluid, helium dynamics

Halloysite Nanotubes for Cleaning, Consolidation and Protection

Giuseppe Cavallaro、Giuseppe Lazzara、Stefana Milioto 等 4 位作者2018-01-10The Chemical Record

Herein, we report our recent research concerning the development of halloysite based protocols for cleaning, consolidation and protection purposes. Surface modification of halloysite cavity by anionic surfactants was explored to fabricate inorganic micelles able to solubilize hydrophobic contaminants. Hybrid dispersio…

Clay minerals and soil interactionsIron oxide chemistry and applicationsTherapeutic Uses of Natural Elements

Adsorption of tetracycline from water using glutaraldehyde-crosslinked electrospun nanofibers of chitosan/poly(vinyl alcohol)

Aliyeh Yousefi Abdolmaleki、Hamid Zilouei、Saied Nouri Khorasani 等 4 位作者2018-01-10Water Science & Technology

In this work, the preparation and characterization of glutaraldehyde-crosslinked electrospun nanofibers of chitosan/poly(vinyl alcohol) (GCCPN) as a new adsorbent for tetracycline (TC) is reported. Electrospun nanofibers of chitosan/poly(vinyl alcohol) (PVA) were prepared by employing a 75:25 volumetric ratio of chitos…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsGraphene and Nanomaterials Applications

NiCu magnetic nanoparticles: review of synthesis methods, surface functionalization approaches, and biomedical applications

Irena Ban、Janja Stergar、Uroš Maver2018-01-10Nanotechnology Reviews

Abstract Magnetic nanoparticles (MNPs) have attracted extensive interest in recent years because of their unique magnetic, electronic, catalytical, optical, and chemical properties. Lately, research on bimetallic MNPs based on nickel and copper (NiCu MNPs) gained momentum owing to their desired properties for use in b…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsCharacterization and Applications of Magnetic Nanoparticles

Nonlinear primary resonance of micro/nano-beams made of nanoporous biomaterials incorporating nonlocality and strain gradient size dependency

Saeid Sahmani、M.M. Aghdam2018-01-10Results in Physics

A wide range of biological applications such as drug delivery, biosensors and hemodialysis can be provided by nanoporous biomaterials due to their uniform pore size as well as considerable pore density. In the current study, the size dependency in the nonlinear primary resonance of micro/nano-beams made of nanoporous…

Composite Structure Analysis and OptimizationThermoelastic and Magnetoelastic PhenomenaNonlocal and gradient elasticity in micro/nano structures

Flax stems: from a specific architecture to an instructive model for bioinspired composite structures

Christophe Baley、Camille Goudenhooft、Marianne Gibaud 等 4 位作者2018-01-10Bioinspiration & Biomimetics

The present paper proposes to carefully study and describe the reinforcement mechanisms within a flax stem, which is an exceptional natural model of composite structure. Thanks to accurate microscopic investigations, with both optical and SEM method, we finely depicted the flax stem architecture, which can be view as…

Natural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical ApplicationsAdvanced Materials and Mechanics

Continuously Tuning Epitaxial Strains by Thermal Mismatch

Lei Zhang、Yakun Yuan、Jason Lapano 等 8 位作者2018-01-10ACS Nano

Strain engineering of thin films is a conventionally employed approach to enhance material properties and to energetically prefer ground states that would otherwise not be attainable. Controlling strain states in perovskite oxide thin films is usually accomplished through coherent epitaxy by using lattice-mismatched s…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

A Three-Dimensional Mixed Finite Element for Flexoelectricity

Feng Deng、Qian Deng、Shengping Shen2018-01-10Journal of Applied Mechanics

Flexoelectric effect is a universal and size-dependent electromechanical coupling between the strain gradient and electric field. The mathematical framework for flexoelectricity, which involves higher-order gradients of field quantities, is difficult to handle using traditional finite element method (FEM). Thus, it is…

Vibration Control and Rheological FluidsMechanical and Optical ResonatorsNonlocal and gradient elasticity in micro/nano structures

CO2-Switchable Cellulose Nanocrystal Hydrogels

Anna Lena Oechsle、Lev Lewis、Wadood Y. Hamad 等 5 位作者2018-01-10Chemistry of Materials

A carbon-dioxide-switchable (CO 2 -switchable) hydrogel was prepared by adding imidazole to a suspension of cellulose nanocrystals (CNCs). Sparging of CO 2 through the imidazole-containing CNC suspension led to gelation of the CNCs, which was reversible by subsequent sparging with nitrogen (N 2 ) to form a low-viscosi…

Advanced Cellulose Research StudiesPickering emulsions and particle stabilizationAerogels and thermal insulation

Maternal engineered nanomaterial inhalation during gestation alters the fetal transcriptome

Phoebe A. Stapleton、Quincy A. Hathaway、C.E. Nichols 等 11 位作者2018-01-10Particle and Fibre Toxicology

The integration of engineered nanomaterials (ENM) is well-established and widespread in clinical, commercial, and domestic applications. Cardiovascular dysfunctions have been reported in adult populations after exposure to a variety of ENM. As the diversity of these exposures continues to increase, the fetal ramificat…

Nanoparticles: synthesis and applicationsAir Quality and Health ImpactsPregnancy and Medication Impact

Large‐Area Atomic Layers of the Charge‐Density‐Wave Conductor TiSe2

Hong Wang、Yu Chen、Martial Duchamp 等 11 位作者2018-01-10Advanced Materials

Abstract Layered transition metal (Ti, Ta, Nb, etc.) dichalcogenides are important prototypes for the study of the collective charge density wave (CDW). Reducing the system dimensionality is expected to lead to novel properties, as exemplified by the discovery of enhanced CDW order in ultrathin TiSe 2 . However, the s…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials