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Synthesis and Mechanical Character of Hexagonal Phase δ−WN

Changchun Wang、Qiang Tao、Shushan Dong 等 5 位作者2017-03-22Inorganic Chemistry

In this work, high-quality bulk WC-structured WN (δ−WN) was synthesized via an untraditional method and the structure was accurately determined by X-ray diffraction and Rietveld refinement. In the process of synthesizing δ−WN, W 2 N 3 and melamine were used as tungsten source and nitrogen source, respectively. The res…

Advanced ceramic materials synthesisInorganic Chemistry and MaterialsX-ray Diffraction in Crystallography

On‐axis versus off‐axis Transmission Kikuchi Diffraction technique: application to the characterisation of severe plastic deformation‐induced ultrafine‐grained microstructures

Hui Yuan、Etienne Brodu、Cai Chen 等 6 位作者2017-03-22Journal of Microscopy

A new configuration for Transmission Kikuchi Diffraction (TKD) in a scanning electron microscope is presented; called 'on-axis TKD'. Compared to the usual off-axis configuration, the scintillator is placed perpendicular to the incident beam under the electron-transparent sample, not in vertical position. In this way,…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsAluminum Alloy Microstructure Properties

Controlled Design and Fabrication of SERS–SEF Multifunctional Nanoparticles for Nanoprobe Applications: Morphology-Dependent SERS Phenomena

Sehoon Chang、Shannon L. Eichmann、Ting-Yun Huang 等 5 位作者2017-03-22The Journal of Physical Chemistry C

Abstract Dual-mode surface-enhanced Raman scattering (SERS)–surface-enhanced fluorescence (SEF) composite nanoparticles have been developed for possible use as oil reservoir tracers. These composite nanoparticles are composed of metal Ag nanostructured cores, specific dye molecules, and a SiO2 shell coating. Herein, w…

Gold and Silver Nanoparticles Synthesis and ApplicationsBiosensors and Analytical DetectionNanocluster Synthesis and Applications

Hybrid Core-Shell (HyCoS) Nanoparticles produced by Complex Coacervation for Multimodal Applications

Donatella Vecchione、Anna Grimaldi、Ernesto Forte 等 6 位作者2017-03-22Scientific Reports

Multimodal imaging probes can provide diagnostic information combining different imaging modalities. Nanoparticles (NPs) can contain two or more imaging tracers that allow several diagnostic techniques to be used simultaneously. In this work, a complex coacervation process to produce core-shell completely biocompatibl…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsLanthanide and Transition Metal Complexes

Dopant size effects on novel functionalities: High-temperature interfacial superconductivity

Y. Eren Suyolcu、Yi Wang、Federico Baiutti 等 10 位作者2017-03-22Scientific Reports

Abstract Among the range of complex interactions, especially at the interfaces of epitaxial oxide systems, contributing to the occurrence of intriguing effects, a predominant role is played by the local structural parameters. In this study, oxide molecular beam epitaxy grown lanthanum cuprate-based bilayers (consistin…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Simulation and measurement of optimized microwave reflectivity for carbon nanotube absorber by controlling electromagnetic factors

Danfeng Zhang、Zhifeng Hao、Yannan Qian 等 7 位作者2017-03-22Scientific Reports

Heat-treatments may change the defect and surface organic groups of carbon nanotubes (CNTs), and lead to significant changes in the microwave electromagnetic parameter of CNTs. In this paper, the effect of heat-treatment time and temperature on the complex dielectric constant and permeability as well as the microwave…

Electromagnetic wave absorption materialsFlame retardant materials and propertiesAdvanced Antenna and Metasurface Technologies

Applications of Three Dithienylpyrroles-Based Electrochromic Polymers in High-Contrast Electrochromic Devices

Yuh-Shan Su、Jui-Cheng Chang、Tzi‐Yi Wu2017-03-22Polymers

Three dithienylpyrroles (1-(4-(methylthio)phenyl)-2,5-di(thiophen-2-yl)-pyrrole (MPS), 1-(4-methoxyphenyl)-2,5-di(thiophen-2-yl)-pyrrole (MPO), and 4-(2,5-di(thiophen-2-yl)-pyrrol-1-yl)benzonitrile (ANIL)) were synthesized and their corresponding polydithienylpyrroles (PSNS) were electrosynthesized using electrochemic…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Ultrathin, wafer-scale hexagonal boron nitride on dielectric surfaces by diffusion and segregation mechanism

Sushant Sonde、Andrei Dolocan、Ning Lü 等 8 位作者2017-03-222D Materials

Abstract Chemical vapor deposition (CVD) of two-dimensional (2D) hexagonal boron nitride (h-BN) is at the center of numerous studies for its applications in novel electronic devices. However, a clear understanding of the growth mechanism is lacking for its wider industrial adoption on technologically relevant substrat…

Graphene research and applications2D Materials and ApplicationsThermal properties of materials

Eutectic pattern transition under different temperature gradients: A phase field study coupled with the parallel adaptive-mesh-refinement algorithm

Ang Zhang、Zhengxiao Guo、Shilin Xiong2017-03-22Journal of Applied Physics

Eutectic pattern transition under an externally imposed temperature gradient was studied using the phase field method coupled with a novel parallel adaptive-mesh-refinement (Para-AMR) algorithm. Numerical tests revealed that the Para-AMR algorithm could improve the computational efficiency by two orders of magnitude a…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaMetallurgy and Material Forming

Laser-induced photochemical synthesis of branched Ag@Au bimetallic nanodendrites as a prominent substrate for surface-enhanced Raman scattering spectroscopy

Linlin Xu、Shuang Li、Hua Zhang 等 5 位作者2017-03-22Optics Express

M. The pronounced feature should be attributed to the noticeable small-sized branches (<10 nm) and unique pronounced inter-metallic synergies. Our results have a promising potential for developing SERS-based ultrasensitive probes in biomedical application.

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesLaser-Ablation Synthesis of Nanoparticles

Porous Layered Double Hydroxides Synthesized using Oxygen Generated by Decomposition of Hydrogen Peroxide

Pablo Gonzalez Rodriguez、Mark de Ruiter、Tom Wijnands 等 4 位作者2017-03-22Scientific Reports

Abstract Porous magnesium-aluminium layered double hydroxides (LDH) were prepared through intercalation and decomposition of hydrogen peroxide (H 2 O 2 ). This process generates oxygen gas nano-bubbles that pierce holes in the layered structure of the material by local pressure build-up. The decomposition of the perox…

Advanced Photocatalysis TechniquesPolyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and Applications

Fast MAS 1H NMR Study of Water Adsorption and Dissociation on the (100) Surface of Ceria Nanocubes: A Fully Hydroxylated, Hydrophobic Ceria Surface

Lance Gill、Ariana Beste、Banghao Chen 等 7 位作者2017-03-22The Journal of Physical Chemistry C

1 H nuclear magnetic resonance (NMR) spectroscopy was used to study hydroxylic surface species on ceria nanocubes, a crystalline, high-surface-area CeO 2 that presents mostly (100) facets. Water adsorption and desorption experiments in combination with fast magic angle spinning (MAS, 20–40 kHz) 1 H NMR provide high-re…

Catalytic Processes in Materials ScienceRadioactive element chemistry and processingAdvanced Condensed Matter Physics

Persistent photoconductivity in ZnO nanowires: Influence of oxygen and argon ambient

Manfred Madel、Florian Huber、Rainer Müller 等 7 位作者2017-03-22Journal of Applied Physics

ZnO nanowires typically show persistent photoconductivity (PPC), which depends in their temporal behaviour on the ambient. We investigate ZnO nanowires in oxygen and argon ambient and analyze the PPC both on the short and on the long time scale to sort out the underlying mechanisms. Wavelength dependent excitation sho…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsElectronic and Structural Properties of Oxides

The role of surface active species in the fabrication and functionality of edible solid lipid particles

Ioanna Zafeiri、J.E. Norton、Paul Smith 等 5 位作者2017-03-22Journal of Colloid and Interface Science

Lipid particles are very promising candidates for utilisation as Pickering stabilisers, and fabrication of these species has been attracting considerable academic and industrial research. Nonetheless, current understanding of these systems is hindered by the fact that, as a whole, studies reporting on the fabrication…

Proteins in Food SystemsAdvancements in Transdermal Drug DeliveryPickering emulsions and particle stabilization

Crystallization of iron‐containing sodium aluminosilicate glasses in the NaAlSiO4‐NaFeSiO4 join

Mostafa Ahmadzadeh、José Marcial、John S. McCloy2017-03-22Journal of Geophysical Research Solid Earth

Abstract Although natural materials are the subject of most Earth science articles, fundamental studies on analogous synthetic materials, produced under laboratory‐controlled conditions, can provide significant insight into expected behavior of natural systems. Iron, a common element in natural aluminosilicates as wel…

Geological and Geochemical AnalysisClay minerals and soil interactionsIron oxide chemistry and applications

Field Emission From Metal Surfaces Irradiated With Helium Plasmas

Dogyun Hwangbo、Shin Kajita、N. Ohno 等 4 位作者2017-03-22IEEE Transactions on Plasma Science

Field electron emission from metal (tungsten, molybdenum, and tantalum) surfaces with different surface morphology was measured. Fuzz and loop samples had small increment in the emission current, whereas bubble samples marked huge increment in the current, accompanied by breakdown. The emission current became greater…

Fusion materials and technologiesNuclear Materials and PropertiesVacuum and Plasma Arcs

Research Update: Fast and tunable nanoionics in vertically aligned nanostructured films

Shinbuhm Lee、Judith L. MacManus‐Driscoll2017-03-22APL Materials

This review provides the design principles to develop new nanoionic applications using vertically aligned nanostructured (VAN) thin films, incorporating two phases which self-assemble in one film. Tunable nanoionics has attracted great attention for energy and device applications, such as ion batteries, solid oxide fu…

ZnO doping and propertiesPerovskite Materials and ApplicationsSemiconductor materials and devices

Deformable Discoidal Polymeric Nanoconstructs for the Precise Delivery of Therapeutic and Imaging Agents

Anna Lisa Palange、Roberto Palomba、Ilaria Francesca Rizzuti 等 5 位作者2017-03-22Molecular Therapy

Over the last 15 years, a plethora of materials and different formulations have been proposed for the realization of nanomedicines. Yet drug-loading efficiency, sequestration by phagocytic cells, and tumor accumulation are sub-optimal. This would imply that radically new design approaches are needed to propel the clin…

Bone Tissue Engineering MaterialsNanoparticle-Based Drug DeliveryGraphene and Nanomaterials Applications

Substitutional Electron and Hole Doping of WSe2: Synthesis, Electrical Characterization, and Observation of Band-to-Band Tunneling

Rupam Mukherjee、Hsun‐Jen Chuang、Michael Köehler 等 7 位作者2017-03-22Physical Review Applied

Electronic applications of transition-metal dichalcogenides (TMDs) might require $p$-type or $n$-type doping. Heavy doping of TMDs also facilitates the formation of low-resistance ohmic contacts, which is essential for both device applications and fundamental study of electrical transport in these materials. The autho…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Synthesis, Characterization, and the Antioxidant Activity of Double Quaternized Chitosan Derivatives

Lijie Wei、Qing Li、Wenqiang Tan 等 6 位作者2017-03-22Molecules

With the specialty of improving the water solubility of chitosan, quaternary ammonium salts have broadened the application of this polysaccharide in food, medicine and pesticides. To identify the effect of quaternary ammonium salts’ quantity, single quaternized chitosan N-phenmethyl-N,N-dimethyl chitosan (PDCS), doubl…

Nanoparticles: synthesis and applicationsNanocomposite Films for Food PackagingPomegranate: compositions and health benefits