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Effect of degree of hydrolysis of polyvinyl alcohol on the corrosion inhibition of steel: theoretical and experimental studies

Savıour A. Umoren、I.B. Obot、A. Madhankumar 等 4 位作者2014-12-02Journal of Adhesion Science and Technology

Two grades of polyvinyl alcohol (PVA) namely partially hydrolyzed (designated as PVA-I) and fully hydrolyzed (designated as PVA-II) were studied with the aim of determining the influence of PVA degree of hydrolysis on the corrosion inhibition effect of mild steel in HCl medium. The investigation was carried out using…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Origin of major donor states in In–Ga–Zn oxide

Motoki Nakashima、Masashi Oota、Noritaka Ishihara 等 10 位作者2014-12-02Journal of Applied Physics

To clarify the origin of the major donor states in indium gallium zinc oxide (IGZO), we report measurement results and an analysis of several physical properties of IGZO thin films. Specifically, the concentration of H atoms and O vacancies (VO), carrier concentration, and conductivity are investigated by hard X-ray p…

ZnO doping and propertiesThin-Film Transistor TechnologiesGa2O3 and related materials

High Temperature Nanoplasmonics: The Key Role of Nonlinear Effects

Alessandro Alabastri、Andréa Toma、Mario Malerba 等 5 位作者2014-12-02ACS Photonics

In this work we show the effect of high temperature on the plasmonic properties of metallic nanorods. Within this context, the dielectric function of metal has been modified to keep into account both the electron–electron and electron–phonon temperature dependent scattering mechanisms. In fact, the mentioned damping p…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNonlinear Optical Materials Studies

Gold Nanoparticles Stabilized with MPEG-Grafted Poly(l-lysine): in Vitro and in Vivo Evaluation of a Potential Theranostic Agent

Alexei Bogdanov、Suresh Gupta、Nadezhda V. Koshkina 等 7 位作者2014-12-02Bioconjugate Chemistry

As the number of diagnostic and therapeutic applications utilizing gold nanoparticles (AuNPs) increases, so does the need for AuNPs that are stable in vivo, biocompatible, and suitable for bioconjugation. We investigated a strategy for AuNP stabilization that uses methoxypolyethylene glycol-graft-poly(l-lysine) copoly…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranostics

Porous Polyurea Network Showing Aggregation Induced White Light Emission, Applications as Biosensor and Scaffold for Drug Delivery

Subhajit Bhunia、Nabanita Chatterjee、Subhadip Das 等 5 位作者2014-12-02ACS Applied Materials & Interfaces

We have designed a urea functionalized novel nanoporous material, POP-PU, which showsaggregation induced white light emission in the presence of suitable polar solvents. This nanomaterial has been explored as a pseudowhite light emitter where the polymeric luminogen moiety can interact with the suitable polar solvent,…

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

Amphiphilic poly(ethylene glycol)-poly(ε-caprolactone) AB 2 miktoarm copolymers for self-assembled nanocarrier systems: synthesis, characterization, and effects of morphology on antitumor activity

Kwonhyeok Yoon、Han Chang Kang、Li Li 等 8 位作者2014-12-02Polymer Chemistry

Miktoarm-structured PEG-PCL <sub>2</sub> copolymers with morphological versatility for drug delivery.

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Microemulsion Systems for Fiber Deconstruction into Cellulose Nanofibrils

Carlos A. Carrillo、Janne Laine、Orlando J. Rojas2014-12-02ACS Applied Materials & Interfaces

A new method to produce cellulose nanofibrils (CNF) is proposed to reduce the energy demand during deconstruction of precursor fibers suspended in aqueous media. Microemulsions were formulated with aqueous solutions of urea or ethylenediamine and applied to disrupt interfibril hydrogen bonding. Compared to typical fib…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Solid Lipid Nanoparticles: Promising Therapeutic Nanocarriers for Drug Delivery

Dipti Thukral、Shweta Dumoga、Anil K. Mishra2014-12-02Current Drug Delivery

Development of colloidal delivery systems has opened new avenues/frontiers for improving drug delivery. Solid lipid nanoparticles have come up as the latest development in the arena of lipid based colloidal delivery systems after nanoemulsion and liposomes ever since their introduction in the early 1990s. In this revi…

Nanoparticle-Based Drug Delivery

Facile and surfactant-free synthesis of Pd nanoparticles by the extract of the fruits of Piper longum and their catalytic performance for the Sonogashira coupling reaction in water under ligand- and copper-free conditions

Mahmoud Nasrollahzadeh、S. Mohammad Sajadi、Mehdi Maham 等 4 位作者2014-12-02RSC Advances

This work reports a facile synthesis of palladium nanoparticles (Pd NPs) by the extract of the fruits of <italic>Piper longum</italic> without any stabilizer or surfactant.

Electrocatalysts for Energy ConversionNanoparticles: synthesis and applicationsPiperaceae Chemical and Biological Studies

Dextran-Gated, Multifunctional Mesoporous Nanoparticle for Glucose-Responsive and Targeted Drug Delivery

Arjyabaran Sinha、Atanu Chakraborty、Nikhil R. Jana2014-12-02ACS Applied Materials & Interfaces

Design of drug delivery nanocarrier having targeted recognition followed by bioresponsive controlled release, especially via glucose-responsive release, is a challenging issue. Here, we report magnetic mesoporous silica (MMS)-based drug delivery nanocarrier that can target specific cell and release drug via glucose-re…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesGraphene and Nanomaterials Applications

Plasmon Modes and Hot Spots in Gold Nanostar–Satellite Clusters

Amane Shiohara、Sergey M. Novikov、Diego M. Solís 等 6 位作者2014-12-02The Journal of Physical Chemistry C

Gold nanostars display strong electromagnetic field enhancement at their tips, and tip plasmon resonances can be tuned within the visible and near-infrared, which has been applied toward plasmonic molecular sensing. However, the sensitivity can be further increased by linking gold nanostars to other plasmonic nanopart…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Magnetically Separable Microporous Fe–Porphyrin Networks for Catalytic Carbene Insertion into N–H Bonds

Jin Yoo、Nojin Park、Joon Hyun Park 等 10 位作者2014-12-02ACS Catalysis

Microporous organic networks (MONs) are a new class of porous materials. This work shows the application of MON chemistry for the preparation of magnetically separable catalytic systems. By the Sonogashira coupling of Fe III –tetrakis(4-ethynylphenyl)porphyrin and 1,4-diiodobenzene, Fe 3 O 4 nanoparticles were coated…

Metal-Organic Frameworks: Synthesis and ApplicationsAdenosine and Purinergic SignalingCovalent Organic Framework Applications

Atomic Structure of Epitaxial Graphene Sidewall Nanoribbons: Flat Graphene, Miniribbons, and the Confinement Gap

Irene Palacio、Arlensiú Celis、Maya Narayanan Nair 等 13 位作者2014-12-02Nano Letters

Graphene nanoribbons grown on sidewall facets of SiC have demonstrated exceptional quantized ballistic transport up to 15 μm at room temperature. Angular-resolved photoemission spectroscopy (ARPES) has shown that the ribbons have the band structure of charge neutral graphene, while bent regions of the ribbon develop a…

Carbon Nanotubes in CompositesGraphene research and applicationsSurface and Thin Film Phenomena

Controllable Morphology and Conductivity of Electrodeposited Cu2O Thin Film: Effect of Surfactants

Ying Yang、Juan Han、Xiaohui Ning 等 6 位作者2014-12-02ACS Applied Materials & Interfaces

Both the morphology and conductivity of Cu2O films are controlled in a facile electrodeposition process by tuning the concentration of surfactants. With the increase of the concentration of sodium dodecyl sulfate (SDS) in the plating solution, the average size of Cu2O crystals increases, and the electrical conductivit…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Nucleation and growth of crystals at the intermediate stage of phase transformations in binary melts

Dmitri V. Alexandrov2014-12-02Philosophical Magazine Letters

An exact analytical solution of integro-differential equations, which describe the phase transitions in supercooled binary melts, is constructed with allowance for fluctuating rates of crystal growth. A complete solution of the corresponding Fokker–Planck and balance equations is found for arbitrary nucleation kinetic…

Material Dynamics and PropertiesSolidification and crystal growth phenomenananoparticles nucleation surface interactions

Manipulation of Phosphorescence Efficiency of Cyclometalated Iridium Complexes by Substituted o‐Carboranes

Young Hoon Lee、Jihyun Park、Song‐Jin Jo 等 7 位作者2014-12-02Chemistry - A European Journal

A series of [(C^N)2 Ir(acac)] complexes [{5-(2-R-CB)ppy}2 Ir(acac)] (3 a-3 g; acac=acetylacetonate, CB=o-carboran-1-yl, ppy=2-phenylpyridine; R=H (3 a), Me (3 b), iPr (3 c), iBu (3 d), Ph (3 e), CF3 C6 H4 (3 f), C6 F5 (3 g)) with various 2-R-substituted o-carboranes at the 5-position in the phenyl ring of the ppy liga…

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistry

Ring-opening homo- and co-polymerization of lactides and ε-caprolactone by salalen aluminum complexes

Alessia Pilone、Nicolina De Maio、Konstantin Press 等 9 位作者2014-12-02Dalton Transactions

Aluminum complexes of non-chiral-salalen ligands were investigated in the catalysis of ring-opening polymerization (ROP) of lactide and ε-caprolactone and in their copolymerization. The aluminum-salalen complexes were found to polymerize all varieties of lactide, namely: l-, d-, rac- and meso-lactide, and showed moder…

biodegradable polymer synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis

The role of oxygen vacancies and their location in the magnetic properties of Ce 1−x Cu x O 2−δ nanorods

Maria Inês Basso Bernardi、Alexandre Mesquita、Fanny Béron 等 7 位作者2014-12-02Physical Chemistry Chemical Physics

Ceria (CeO2) is a promising dilute magnetic semiconductor. Several studies report that the intrinsic and extrinsic structural defects are responsible for room temperature ferromagnetism in undoped and transition metal doped CeO2 nanostructures; however, the nature of the kind of defect necessary to promote and stabili…

Catalytic Processes in Materials ScienceMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Nanotechnology: nature's gift or scientists' brainchild?

Michael F. Hochella、Michael G. Spencer、Kimberly Jones2014-12-02Environmental Science Nano

The answer to the compelling question of whether nanomaterials are new or not is debated by leading scientists.

Carbon Nanotubes in CompositesNanoparticles: synthesis and applicationsNanotechnology research and applications