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Seed/catalyst-free growth of zinc oxide nanostructures on multilayer graphene by thermal evaporation

Nurul Fariha Ahmad、Nurul Izni Rusli、Mohamad Rusop Mahmood 等 5 位作者2014-02-18Nanoscale Research Letters

We report the seed/catalyst-free growth of ZnO on multilayer graphene by thermal evaporation of Zn in the presence of O2 gas. The effects of substrate temperatures were studied. The changes of morphologies were very significant where the grown ZnO structures show three different structures, i.e., nanoclusters, nanorod…

Graphene research and applicationsZnO doping and propertiesGas Sensing Nanomaterials and Sensors

Effect of silane integrated sol–gel derived in situ silica on the properties of nitrile rubber

Bharat P. Kapgate、Chayan Das、Debdipta Basu 等 6 位作者2014-02-18Journal of Applied Polymer Science

ABSTRACT Nitrile rubber/silica composites are prepared by a sol–gel process using tetraethoxysilane as precursor in the presence of γ‐mercaptopropyltrimethoxysilane as a silane coupling agent. Here, we follow a novel processing route where the silica particles are generated inside the rubber matrix before compounding…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Purification of Carbon Nano-Onions Fabricated by Arc Discharge

Chao Ruan、Yongfu Lian2014-02-18Fullerenes Nanotubes and Carbon Nanostructures

Soot containing carbon nano-onions was synthesized by traditional electric arc-discharge method with nickel powder as catalyst. After heating at 400°C for 2 h, the arc discharged soot was soaked in hydrochloric acid solution 8 h, and then ultrasonically dispersed into sodium cholate solution. Such obtained dispersion…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

Nanoporous Nonwoven Fibril-Like Morphology by Cooperative Self-Assembly of Poly(ethylene oxide)-block-Poly(ethyl acrylate)-block-Polystyrene and Phenolic Resin

Guodong Deng、Zhe Qiang、Willis Lecorchick 等 5 位作者2014-02-18Langmuir

Cooperative self-assembly of block copolymers with (in)organic precursors effectively generates ordered nanoporous films, but the porosity is typically limited by the need for a continuous (in)organic phase. Here, a network of homogeneous fibrous nanostructures (≈20 nm diameter cylinders) having high porosity (≈ 60%)…

Mesoporous Materials and CatalysisBlock Copolymer Self-AssemblyCovalent Organic Framework Applications

Dynamic mechanical properties and correlation with dynamic fragility of sisal reinforced composites

Heitor Luiz Ornaghi、Ademir J. Zattera、Sandro Campos Amico2014-02-18Polymer Composites

In this study, the reinforcement effect in sisal/polyester composites containing distinct reinforcement content was studied ranging from fragile to strong classification. The results indicate that the reduced storage modulus changes steadily, and the loss modulus and the tan δ peak are broader for composites containin…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesBamboo properties and applications

Optical properties of boride ultrahigh-temperature ceramics for solar thermal absorbers

Elisa Sani、Marco Meucci、Luca Mercatelli 等 7 位作者2014-02-18Journal of Photonics for Energy

It is a known rule that the efficiency of thermodynamic solar plants increases with the working temperature. At present, the main limit in temperature upscaling is the absorber capability to withstand high temperatures. The ideal solar absorber works at high temperatures and has both a low thermal emissivity and a hig…

Advanced ceramic materials synthesisSilicon and Solar Cell TechnologiesThermal properties of materials

Osmium-Promoted Dehydrogenation of Amine–Boranes and B–H Bond Activation of the Resulting Amino–Boranes

Miguel A. Esteruelas、Israel Fernández、Ana M. López 等 5 位作者2014-02-18Organometallics

The five-coordinate osmium complex OsH(SH)(CO)(P i Pr 3 ) 2, containing an electrophilic center bonded to the soft hydrogen sulfide ligand, promotes dehydrogenation of amine–boranes and captures the amino–borane products, forming hydrogenaminothioborate complexes.

Hydrogen Storage and MaterialsOrganoboron and organosilicon chemistryAmmonia Synthesis and Nitrogen Reduction

Electromagnetically induced transparency like transmission in a metamaterial composed of cut-wire pairs with indirect coupling

Yasuhiro Tamayama、Kanji Yasui、Toshihiro Nakanishi 等 4 位作者2014-02-18Physical Review B

We theoretically and numerically investigate metamaterials composed of coupled resonators with indirect coupling. First, we theoretically analyze a mechanical model of coupled resonators with indirect coupling. The theoretical analysis shows that an electromagnetically induced transparency (EIT)-like phenomenon with a…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

Effect of the Cu Source on Optical Properties of CuZnO Films Deposited by Ultrasonic Spraying

Chih-Hung Hsu、Lung‐Chien Chen、Xiuyu Zhang2014-02-18Materials

CuZnO (CZO) films have received considerable attention, owing to their potential applications in semiconductor devices, including gas sensors or solar cells. However, exactly how these films affect the properties of CZO films by using different Cu sources has seldom been investigated. This study demonstrates the feasi…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

The Role of Shape on Electronic Structure and Charge Transport in Faceted PbSe Nanocrystals

Ananth P. Kaushik、Binit Lukose、Paulette Clancy2014-02-18ACS Nano

We have determined the effect of shape on the charge transport characteristics of nanocrystals. Our study looked at the explicit determination of the electronic properties of faceted nanocrystals that essentially probe the limit of current computational reach, i.e., nanocrystals from 1.53 to 2.1 nm in diameter. These…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Generalized Effective Medium Theory to Extract the Optical Properties of Two-Dimensional Nonspherical Metallic Nanoparticle Layers

Yann Battie、Aotmane En Naciri、William Chamorro 等 4 位作者2014-02-18The Journal of Physical Chemistry C

A new effective medium theory is introduced to describe the optical properties of a two-dimensional array of metallic nanoislands. This model which takes into account both the nanoisland orientation and their shape distribution is successfully used to interpret the ellipsometric measurements performed on gold nanoisla…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Char barrier effect of graphene nanoplatelets on the flame retardancy and thermal stability of high‐density polyethylene flame‐retarded by brominated polystyrene

Shiya Ran、Chao Chen、Zhenghong Guo 等 4 位作者2014-02-18Journal of Applied Polymer Science

ABSTRACT Graphene nanoplatelets (GNPs) with the char barrier effect were combined with brominated polystyrene (BPS) and antimony trioxide (Sb 2 O 3 ) to improve the flame retardancy and thermal stability of high‐density polyethylene. Thermogravimetric analysis, limited oxygen index (LOI) testing, and vertical burning…

Polymer Nanocomposites and PropertiesFire dynamics and safety researchFlame retardant materials and properties

Mechanical and water binding properties of carboxymethyl cellulose/multiwalled carbon nanotube nanocomposites

Seyed Mohammad Mahdi Dadfar、Gholamreza Kavoosi2014-02-18Polymer Composites

Carboxymethyl cellulose (CMC) composite films were prepared from CMC solutions (2% w/v) containing multiwalled carbon nanotubes (MWCNT) as nanofiller and glycerol (25% w/w CMC) as plasticizer. Tensile strength, elongation at break (EAB), young's modulus, water solubility, water swelling, water uptake, and water vapor…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

Role of Steric Hindrance in the Newman-Kwart Rearrangement and in the Synthesis and Photophysical Properties of Arylsulfanyl Tetrapyrazinoporphyrazines

Veronika Novakova、Miroslav Miletín、Tereza Filandrová 等 6 位作者2014-02-18The Journal of Organic Chemistry

Conditions for the Newman-Kwart rearrangement of phenols into thiophenols were investigated in relation to the bulkiness of substituents at the 2 and 6 positions of the starting phenol derivative with an emphasis on eliminating side reactions. Thiophenols with different 2,6-disubstitution patterns (including hydrogen,…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesOxidative Organic Chemistry Reactions

Dual Agent Loaded PLGA Nanoparticles Enhanced Antitumor Activity in a Multidrug-Resistant Breast Tumor Xenograft Model

Yan Chen、Xuelian Zheng、Dailong Fang 等 10 位作者2014-02-18International Journal of Molecular Sciences

Multidrug-resistant breast cancers have limited and ineffective clinical treatment options. This study aimed to develop PLGA nanoparticles containing a synergistic combination of vincristine and verapamil to achieve less toxicity and enhanced efficacy on multidrug-resistant breast cancers. The 1:250 molar ratio of VCR…

Nanoparticle-Based Drug DeliveryDrug Transport and Resistance MechanismsPharmacological Effects and Toxicity Studies

A 2.2 Å resolution structure of the USP7 catalytic domain in a new space group elaborates upon structural rearrangements resulting from ubiquitin binding

Katrina L. Molland、Qing Zhou、Andrew D. Mesecar2014-02-18Acta Crystallographica Section F Structural Biology Communications

A sparse-matrix screen for new crystallization conditions for the USP7 catalytic domain (USP7CD) led to the identification of a condition in which crystals grow reproducibly in 24-48 h. Variation of the halide metal, growth temperature and seed-stock concentration resulted in a shift in space group from P21 with two m…

DNA Repair MechanismsEnzyme Structure and FunctionBiochemical and Molecular Research

Length scales and self-organization in dense suspension flows

Gustavo Düring、Edan Lerner、Matthieu Wyart2014-02-18Physical Review E

Dense non-Brownian suspension flows of hard particles display mystifying properties: As the jamming threshold is approached, the viscosity diverges, as well as a length scale that can be identified from velocity correlations. To unravel the microscopic mechanism governing dissipation and its connection to the observed…

Material Dynamics and PropertiesGranular flow and fluidized bedsSports Dynamics and Biomechanics

Modeling a seeded continuous crystallizer for the production of active pharmaceutical ingredients

Maximilian O. Besenhard、Roland Hohl、Aden Hodžić 等 5 位作者2014-02-18Crystal Research and Technology

The approximation of a well mixed reactor is prevalent when it comes to the modeling of a crystallization process. Since temperature, concentration, and mass content vary due to inhomogeneous mixing, this approximation is a very loose one. The continuously operated seeded tubular crystallizer system developed in our g…

Surfactants and Colloidal SystemsCoagulation and Flocculation StudiesCrystallization and Solubility Studies

Diamond magnetometry of superconducting thin films

A. Waxman、Yechezkel Schlussel、David Groswasser 等 7 位作者2014-02-18Physical Review B

In recent years, diamond magnetometers based on the nitrogen-vacancy (NV) center have been of considerable interest for applications at the nanoscale. An interesting application which is well suited for NV centers is the study of nanoscale magnetic phenomena in superconducting materials. We employ NV centers to interr…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Antiferro Quadrupole Orders in Non-Kramers Doublet Systems

Kazumasa Hattori、Hirokazu Tsunetsugu2014-02-18Journal of the Physical Society of Japan

We investigate antiferro quadrupole orders in systems with non-Kramers doublet ground state with total angular momentum J=4 in T_d point group symmetry. We demonstrate that a pure O_2^2 antiferro quadrupole order is impossible in general crystalline-electric field potential and should be accompanied by ferro O_2^0 qua…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics