Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation, properties, and kinetics of the reaction of manganese(0) radicals Mn(CO)3(R3P)2 with tributyltin hydrideSharon B. McCullen and Theodore L. BrownCite this: J. Am. Chem. Soc. 1982, 104, 26, 7496–7500Publication Date (Print):December 1, 1982Publication History Publ…
From the measurement of three-probe resistivities, which are much larger than two-probe resistivities, we conclude that annealed, nominally pure and nearly stoichiometric NiO single crystals normally have a low-resistivity surface layer which masks the behaviour of the bulk in most electrical measurements. Bulk resist…
Improved one-tier and two-tier designs for a high-pressure–low-pressure (HPLP) apparatus are described together with some of their recent applications. These instruments are used for surface analysis and in situ monitoring of catalytic reactions on small samples with a geometrical surface area of 1 cm2. Catalytic reac…
The structure of cyclohexylsilanetriol C6H11Si(OH)3 has been determined by single-crystal x-ray diffraction methods. The molecule crystallizes in the monoclinic system, space group C2/m, with a=7.876(3), b=6.637(6), c=15.802(11) Å, β=95.51(3)° at −60 °C, and Z=4. The intensities of 1031 independent reflections were me…
The low-temperature phase transitions of tetramethyltetrathiafulvalene thiocyanate are described through magnetic and structural studies. A first transition, which occurs at 160 K, drives the electron gas into a localized state and is shown to be associated with a superstructure formation. Then, the condensation of an…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNMR spectroscopic studies on chalcogen compounds. 4. Carbon-13 isotope effect on selenium-77 and tellurium-125 nuclear shielding and its correlation with carbon-selenium bond distances. Tellurium-123 isotope effect on tellurium-125 nuclear shieldingWilly GomblerCite this: J.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTWet oxidation of acetic acid catalyzed by Co-Bi complex oxidesSeiichiro Imamura, Akihiro Hirano, and Nariyoshi KawabataCite this: Ind. Eng. Chem. Prod. Res. Dev. 1982, 21, 4, 570–575Publication Date (Print):December 1, 1982Publication History Published online1 May 2002Publis…
X-ray photoelectron spectra and electron-energy-loss spectra (EELS) are presented and interpreted for Pd${\mathrm{H}}_{\mathrm{\ensuremath{\sim}}0.8}$ prepared by in situ loading and cleaning of a 10-\ensuremath{\mu}m foil cooled to 80 K. Hydrogenation induces new states with considerable $d$ character 8 eV in the val…
We have previously reported that glucose can be phosphorylated by phospho-HPr and two sugar-specific pairs of proteins of the Escherichia coli and Salmonella typhimurium phosphoenolpyruvate:glycose phosphotransferase system. Each of the sugar-specific complexes comprises two proteins, lipid, and divalent cation, and e…
Ferroelectric thin films of BaTiO3 have been successfully deposited on n-type silicon substrates at temperatures above 500 °C by rf sputtering in an O2/Ar atmosphere. Analysis by x-ray diffraction patterns show that films deposited at room temperature are amorphous. At temperatures above 500 °C, crystalline BaTiO3 fil…
The widely held view that Al and Fe are transported from A2 to B horizons in podzols in the form of fulvate complexes cannot account satisfactorily for the formation of Bs horizons rich in allophane, although this can be the dominant illuvial horizon in Iron Podzols, and a major feature of the B horizon of Iron Humus…
Iron was ion implanted with He and deuterium (D) and then heated at a constant rate of 2 K/min. The evolving depth distribution of the D was monitored using the nuclear reaction 2D(3He,p)4He, and resulting data were analyzed by applying the diffusion equation with appropriate trapping terms. Two defect traps for D wer…
The phosphocarrier protein, IIIGlc, of the phosphoenolpyruvate:glycose phosphotransferase system (PTS) was purified to homogeneity by two methods. The first method utilized ion exchange and gel filtration chromatography, isoelectric focusing, and polyacrylamide gel electrophoresis, and required several weeks for compl…
Abstract High‐density polyethylene up to about 30% by weight was melt‐mixed with polypropylene and short‐glass‐fiber‐reinforced polypropylene. The presence of high‐density polyethylene and glass fibers in the polypropylene matrix affects its crystallization characteristics, which were studied with the help of differen…
The phosphorylation of Enzyme I is the first step in the phosphotransfer reaction sequence catalyzed by the phosphoenolpyruvate:glycose phosphotransferase system (PTS) from Salmonella typhimurium. The characterization of phospho approximately Enzyme I and the reactions in which it participates are described in this re…
Oxygen self‐diffusion in alumina single crystals was investigated, using the proton activation technique to measure the 18 O profiles after the samples had been exchanged with an 18 O‐enriched gaseous environment. In the temperature range 1750 to 1950 K, the diffusion coefficient for a set of Czoch‐ralski‐grown sample…
Recent work on zone‐melting recrystallization of Si on amorphous insulating substrates using a moveable‐strip heater oven is described in detail for the first time. A (100) texture is obtained if the Si is encapsulated with or a composite of . An encapsulation layer of prevents agglomeration and ensures a smooth surfa…
We derive the thickness profiles of metallic transmission-grating bars that maximize either the power throughput into the mth diffracted order or the ratio of the mth-order diffracted power to the total output power (in the soft-x-ray range). The derivation is performed for both general and symmetric bar shapes and fo…
The preparation of the cis and trans isomers of the kinetically labile bis glycinato copper(II) has a number of advantages including its facility, economy, ready theoretical interpretation, and biological relevance.
It was reported that the addition of a small amount of titanium (0.5 - 3.99%) to a Cu-13.93%Al-3.36%Ni ternary alloy resulted in a remarkable grain-refining. The original grain-size of about 750 microns under hot-rolled and quenched conditions of the ternary alloy was reduced to that of the order of about 100 microns…