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Aging of porous silicon and the origin of blue shift

Tevhit Karacalı、Bülent Çakmak、Hasan Efeoğlu2003-05-19Optics Express

Aging effects of porous silicon (PS) and the origin of blue shift are investigated. Photoluminescence (PL) measurements of the PS prepared with HF-EtOH solution showed a 210 meV blue shift after 1.5 months. It is found from deconvolution of the PL spectra that this shift is not fully related to the quantum confinement…

Silicon Nanostructures and PhotoluminescenceSemiconductor materials and devicesNanowire Synthesis and Applications

Acrylic rubber‐fluorocarbon rubber miscible blends: Effect of curatives and fillers on cure, mechanical, aging, and swelling properties

Md. Abdul Kader、Anil K. Bhowmick2003-05-19Journal of Applied Polymer Science

Abstract The cure characteristics and mechanical properties of gum and filled acrylic rubber (ACM), fluorocarbon rubber (FKM), and their blends of varying compositions were studied both under unaged and aged conditions. The rheometric study showed that optimum cure properties were obtained using a mixed curing system…

Tribology and Wear AnalysisOrthopaedic implants and arthroplastyPolymer Nanocomposites and Properties

Partial Regenerations in Diesel Particulate Filters

O. A. Haralampous、Grigorios Koltsakis、Zissis Samaras2003-05-19SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">In real-world driving, the exhaust gas conditions in the particulate filter may induce incomplete filter regenerations. The implications of such partial regenerations are examined in this paper in terms of pressure drop and filter thermal loading. The methodology followed is based…

Biodiesel Production and ApplicationsVehicle emissions and performanceCatalytic Processes in Materials Science

Synthesis of autophotosensitive hyperbranched polyimides based on 3,3′,4,4′‐benzophenonetetracarboxylic dianhydride and 1,3,5‐tris(4‐aminophenoxy)benzene via end capping of the terminal anhydride groups by ortho‐alkyl aniline

Huan Chen、Jie Yin2003-05-19Journal of Polymer Science Part A Polymer Chemistry

Abstract Benzophenone‐containing, anhydride‐terminated hyperbranched poly(amic acid)s were end‐capped by ortho ‐alkyl aniline in situ and then chemically imidized, yielding autophotosensitive hyperbranched polyimides. The polyimides were soluble in strong polar solvents, such as N ‐methyl‐2‐pyrrolidone, N ‐dimethylfor…

Dendrimers and Hyperbranched PolymersSynthesis and properties of polymersOrganic Electronics and Photovoltaics

Alternative interpretation of the sign reversal of secondary Bjerknes force acting between two pulsating gas bubbles

Masato Ida2003-05-19Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

It is known that in a certain case, the secondary Bjerknes force (which is a radiation force acting between pulsating bubbles) changes, e.g., from attraction to repulsion, as the bubbles approach each other. In this paper, a theoretical discussion of this phenomenon for two spherical bubbles is described. The present…

Ultrasound and Cavitation PhenomenaFluid Dynamics and MixingNuclear Physics and Applications

Interaction of copper and zinc with allophane and organic matter in the B horizon of an Andosol

Christelle Latrille、Laurence Denaix、I. Lamy2003-05-19European Journal of Soil Science

Summary Andosols developed on basaltic material are naturally rich in metals. Organic matter and allophane, the key colloids of these soils, have a strong affinity for trace metals, but are intimately mixed so that speciation of trace metal is difficult to determine. We used three complementary approaches, namely phys…

Heavy metals in environmentClay minerals and soil interactionsSoil and Unsaturated Flow

Emission Performance of Selected Biodiesel Fuels

R.N. McGill、John M. E. Storey、Robert Wagner 等 8 位作者2003-05-19SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">Because of the great interest in biodiesel fuels around the world, the International Energy Agency's Committee on Advanced Motor Fuels sponsored this project to determine emissions and performance of a number of biodiesel fuels with a special emphasis on unregulated emissions. Oak…

Catalytic Processes in Materials ScienceBiodiesel Production and ApplicationsAdvanced Combustion Engine Technologies

Evaluation of industrial by‐products as soil acidity amendments: chemical and mineralogical implications

Fernando Garrido、V. Illera、Carmen Vizcayno 等 4 位作者2003-05-19European Journal of Soil Science

Summary Lime, mined gypsum and some gypsum‐like by‐products have been frequently applied to soil to counter acidity. We have examined the changes in the chemical and mineralogical properties of three acid soils resulting from the application of three industrial by‐products (phosphogypsum, red gypsum and sugar foam). W…

Clay minerals and soil interactionsAluminum toxicity and tolerance in plants and animalsMine drainage and remediation techniques

Spin-phonon interaction and band effects in the high-T_C superconductor HgBa_2CuO_4

T. Jarlborg2003-05-19arXiv

Band calculations show that a stripe-like anti-ferromagnetic spin wave is enforced by a 'half-breathing' phonon distortion within the CuO plane of HgBa_2CuO_4. This spin-phonon coupling is increased further by shear distortion and by increased distance between Cu and apical oxygens. The effects from spin-phonon coupli…

Superconductivitycond-mat.dis-nnMaterials Science

Exploration of oxide-based diluted magnetic semiconductors toward transparent spintronics

T. Fukumura、Y. Yamada、H. Toyosaki 等 6 位作者2003-05-19arXiv

A review is given for the recent progress of research in the field of oxide-based diluted magnetic semiconductor (DMS), which was triggered by combinatorial discovery of transparent ferromagnet. The possible advantages of oxide semiconductor as a host of DMS are described in comparison with conventional compound semic…

Materials ScienceStrongly Correlated Electrons

Two-band second moment model and an interatomic potential for caesium

Graeme J. Ackland、Stewart K. Reed2003-05-19Physical review. B, Condensed matter

A semiempirical formalism is presented for deriving interatomic potentials for materials such as caesium or cerium which exhibit volume collapse phase transitions. It is based on the Finnis-Sinclair second-moment tight-binding approach, but incorporates two independent bands on each atom. The potential is cast in a fo…

Advanced Chemical Physics StudiesNuclear Materials and PropertiesThermodynamic and Structural Properties of Metals and Alloys

Effect of exchange interaction on superparamagnetic relaxation

H. Kachkachi2003-05-19arXiv

We use Langer's approach to calculate the reaction rate of a system of two (classical) spins interacting via the exchange coupling $J$ in a magnetic field $H$, with uniaxial anisotropy of constant $K$. We find a particular value of the exchange coupling, that is $j\equiv J/K = j_c\equiv 1-h^2$, where $h\equiv H/2K$, w…

Materials Sciencecond-mat.stat-mech

Guided modes in negative-refractive-index waveguides

Ilya V. Shadrivov、Andrey A. Sukhorukov、Yuri S. Kivshar2003-05-19OpenAlex

We study linear guided waves propagating in a slab waveguide made up of a negative-refractive-index material, the so-called left-handed waveguide. We reveal that the guided waves in left-handed waveguides possess a number of peculiar properties such as the absence of the fundamental modes, mode double degeneracy, and…

Advanced Antenna and Metasurface TechnologiesPhotonic Crystals and ApplicationsMetamaterials and Metasurfaces Applications

Accumulation of Ultrasmall Superparamagnetic Particles of Iron Oxide in Human Atherosclerotic Plaques Can Be Detected by In Vivo Magnetic Resonance Imaging

M. Eline Kooi、V.C. Cappendijk、K.B.J.M. Cleutjens 等 9 位作者2003-05-19OpenAlex

BACKGROUND: One of the features of high-risk atherosclerotic plaques is a preponderance of macrophages. Experimental studies with hyperlipidemic rabbits have shown that ultrasmall superparamagnetic particles of iron oxide (USPIOs) accumulate in plaques with a high macrophage content and that this induces magnetic reso…

Nanoparticle-Based Drug DeliveryCharacterization and Applications of Magnetic NanoparticlesCerebrovascular and Carotid Artery Diseases

Mineral surfaces and soil organic matter

Klaus Kaiser、Georg Guggenberger2003-05-19OpenAlex

Summary The organic carbon content of soil is positively related to the specific surface area (SSA), but large amounts of organic matter in soil result in reduced SSA as determined by applying the Brunauer–Emmett–Teller (BET) equation to the adsorption of N 2 . To elucidate some of the controlling mechanisms of this r…

Soil Carbon and Nitrogen DynamicsClay minerals and soil interactionsSoil and Unsaturated Flow

Non-adiabatic small polaron hopping in the n=3 Ruddlesden-Popper compound Ca4Mn3O10

J. Lago、P. D. Battle、M. J. Rosseinsky 等 5 位作者2003-05-18arXiv

Magnetotransport properties of the compound Ca4Mn3O10 are interpreted in terms of activated hopping of small magnetic polarons in the non-adiabatic regime. Polarons are most likely formed around Mn3+ sites created by oxygen substoichiometry. The application of an external field reduces the size of the magnetic contrib…

Materials Science

Linear and Second-order Optical Response from First Principles

S. Sharma、C. Ambrosch-Draxl2003-05-18arXiv

We present a full formalism for the calculation of the linear and second-order optical response for semiconductors and insulators. The expressions for the optical susceptibilities are derived within perturbation theory. As a starting point a brief background of the single and many particle Hamiltonians and operators i…

Materials Science

Wave Propagation in Generalized Gyrotropic Media

Jian Qi Shen2003-05-18arXiv

Wave propagation inside generalized gyrotropic media is considered in the present Letter. It is shown that in this type of materials, the left- and right- handed circularly polarized light can be coupled to each other, which may possess some potential applications to quantum information.

Materials Science

Hidden Transition in the “Unfreezable Water” Region of the PVP−Water System

M. J. A. de Dood、Jeroen Kalkman、Chris Strohhöfer 等 5 位作者2003-05-17The Journal of Physical Chemistry B

Poly(vinylpyrrolidone)−water solutions of 60−80 wt % PVP apparently do not freeze when cooled far below the expected freezing point. Such solutions remain highly viscous liquids and ultimately become glasses. It has been reported before that when small-angle X-ray scattering from these solutions is measured, occasiona…

Hydrogels: synthesis, properties, applicationsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Syntheses of New 1 → (2 + 1) C-Branched Monomers for the Construction of Multifunctional Dendrimers

George R. Newkome、Hyung J. Kim、Charles N. Moorefield 等 5 位作者2003-05-17Macromolecules

For the purpose of providing a route to multifunctionalized dendrimers, new types of 1 → (2 + 1) C -branched monomers, possessing either ester and protected hydroxy groups or mixed esters, were designed and synthesized. Thus, di- tert -butyl 4-(3-[X]oxypropyl)-4-aminoheptanedioate (X = MeCO, 4; X = CH 2 CH 2 CN, 6; X…

Dendrimers and Hyperbranched PolymersRNA Interference and Gene DeliveryChemical Synthesis and Analysis