Materials Literature
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The electrochemical synthesis of polypyrrole films on aluminum surfaces from aqueous solutions containing tartaric acid and pyrrole was performed using cyclic voltammetry and galvanostatic techniques. A mechanism that considers a porous aluminum oxide layer growing in parallel with the polymeric film explains the poly…
Oxidation decomposition of unsaturated fatty acids with singlet oxygen generated from a photosensitizing agent was investigated in liposome bilayer membranes under a light irradiation condition. The liposome of which the bilayer membrane was composed of L-alpha-dipalmitoylphosphatidylcholine (DPPC), protoporphyrin IX…
Imidazolium-based amphiphilic hexa-peri-hexabenzocoronenes were synthesized and shown to undergo ordered columnar self-assembly in solid-state as well as in solution to yield defined nanofibers upon solution drop casting onto solid substrate.
Chiral cyclic compounds exhibited light-driven twisting by means of trans-cis photoisomerization in 1,4-dioxane solution, a neat film, and a liquid-crystalline host.
Protonation of the interlayer aminopropyl groups of a synthesized organo-functionalized 2 : 1 trioctahedral magnesium phyllosilicate was used to prepare exfoliated cationic organoclay dispersions that were subsequently re-assembled in the presence of anionic guest molecules, such as ibuprofen, epigallocatechin gallate…
Three types of porous MnO 2 : ordered mesoporous β - MnO 2 ( OMMnO 2 ) , disordered mesoporous γ - MnO 2 ( DMMnO 2 ) , and disordered porous α - MnO 2 ( DPMnO 2 ) were synthesized using hard template, self-assembly, co-precipitation methods, respectively. The electrochemical capacitance profiles have been evaluated in…
A model to estimate the viscosity of aluminosilicate melts, including alkali oxides, was constructed in the present study. The model is based on an earlier model, and considers the bonding state of oxygen in molten silicate and the flow mechanism of melts with a network structure. The straightforward method of Susa et…
The question of how the texture and structure of carbon nanofilaments (CNTs) are determined during growth is addressed via their preparation using the vapour phase method over Ni–Cu–Mg–Al catalysts. The CNTs formed and the related catalyst particles were investigated by high resolution transmission electron microscopy…
Starch, one of the most commonly used polysaccharides, has been adopted for the first time as morphology-directing agent to the electrochemical synthesis of polypyrrole (PPy) nanowires on various electrodes.
A 3-ferrocenylazobenzene monolayer on an ITO electrode exhibits reversible azobenzene isomerization using a single green light source, assisted by electrochemical control of the ferrocene redox state.
The authors have investigated the magnetic, electrical, and structural properties of MnxGe1−x (on Ge substrate) nanostructured films produced by a nanopattern assisted Mn implantation followed by annealing. The semiconducting property and hole-mediated ferromagnetism mechanism enabled them to control the magnetic phas…
Indian bentonite collected from two different sources, namely Barmer district, Rajasthan and Cutch district, Gujarat was screened and purified using the well-known Stoke's law of sedimentation by dispersing different concentrations of bentonite (0.5, 1, 2, 3 and 4%) in deionized water. Chemical composition and cation…
A single crystal X-ray diffraction method is the most powerful technique for the crystal structure determination of both organic and inorganic compounds. However, a number of organic compounds crystallize in a form of polycrystalline powder rather than a single crystal of suitable size and quality for X-ray crystallog…
Summary: A brief review of the standard Johnson-Cook model is presented. Three optional strain-rate forms are introduced and calibrated to laboratory data for A36 steel. Next a brief description of the LS-DYNA implementation of the new strain-rate forms within the existing viscoplastic formulation of the JohnsonCook m…
Removal of methanol molecules from the interstices of a metal-organic framework based on a 2-D hexagonal Mn(II)-TCNQF(4) net results in stronger magnetic interactions and leads to a glassy magnetically ordered state; the magnetic behavior can be reversibly cycled upon solvation-desolvation of the material.
The inhibitive effect of exudate gum from Dacroydes edulis in the corrosion of aluminium in HCl solutions was studied using weight loss and thermometric methods at 30-60 o C. The results reveal that the exudate gum acts as an inhibitor for corrosion of aluminium in HCl solution. The inhibition efficiency increases wit…
Iron addition was attempted in this study to improve the pseudo-capacitive property of Mn oxides. The oxides were prepared on graphite substrates by anodic deposition. The deposition solutions were manganese acetate aqueous solutions with various amount of (up to ). Crystal structure and surface morphology of the depo…
MgO insulation coating with thickness of ca. 50nm was evaporated on the surface of iron powder and fabricated soft magnetic composite(SMC) with low iron loss. The MgO insulation coating had greater heat resistance than conventional phosphate insulation coating, which enabled stress relieving annealing at higher temper…
Two photochromic dithiazolylethene-based derivatives (1a and 2a) incorporating a push–pull structural motif D–π–A are synthesized and structurally characterized. The photochemical reactions, which reversibly modify the connection between the electron donor and acceptor, result in simultaneous and effective photo-modul…
Our goal is to develop the functionalized superparamagnetic iron oxide nanoparticles (SPIONs) demonstrating the capacities to be delivered in liver specifically and to be dispersed in physiological environment stably. For this purpose, SPIONs were coated with polyvinylbenzyl-O-beta-D-galactopyranosyl-D-gluconamide (PV…