Materials Literature
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Near infrared broadband emission characteristics of bismuth-doped aluminophosphate glass have been investigated. Broad infrared emissions peaking at 1210nm, 1173nm and 1300nm were observed when the glass was pumped by 405nm laser diode (LD), 514nm Ar+ laser and 808nm LD, respectively. The full widths at half maximum (…
We report the nanoscale loading and confinement of aquated Gd3+n-ion clusters within ultra-short single-walled carbon nanotubes (US-tubes); these Gd3+n@US-tube species are linear superparamagnetic molecular magnets with Magnetic Resonance Imaging (MRI) efficacies 40 to 90 times larger than any Gd3+-based contrast agen…
Nanoparticles of WS2 and MoS2 with a closed cage structure (fullerene-like) that are termed IF phases are synthesized in large amounts in a pure form. These nanoparticles were shown to play a favorable role as solid lubricants under severe conditions where fluids are unable to support the heavy load and are squeezed a…
This paper deals with the physical and mathematical modelling description of drug release from matrix systems. In the introduction, matrix systems are considered in the wide frame of the controlled release systems and the concept of mathematical model is briefly discussed. Then, matrix structure and topology are match…
Part 1 Fundamentals of adhesive bonding: History of adhesive bonding What are adhesives and sealants and how do they work? Surfaces: how to assess Surfaces: How to treat. Part 2 Mechanical properties: Stress analysis Environmental (durability) effects Nondestructive testing Impact behaviour of adhesively bonded joints…
The interest in using cellulose fibres as reinforcing elements in composite materials based on polymeric matrices is constantly growing, mainly because of the many advantages associated with this renewable material. However, the preparation of cellulose-based composites is perturbed by the highly hydrophilic character…
During the last few decades liposomes have attracted great interest as ideal models for biological membranes as well as efficient carriers for drugs, diagnostics, vaccines, nutrients and other bioactive agents. The extensive and ever increasing literature covering the field of liposomology written by researchers with…
Basic mechanisms controlling orbital order and orbital fluctuations in transition metal oxides are discussed. The lattice driven classical orbital picture, e.g. like in manganites LaMnO3, is contrasted to the quantum behavior of orbitals in frustrated superexchange models as realised in pseudocubic titanites ATiO3 and…
The discovery in the late 1990s of ordered, high surface area silicas with pore sizes of 5 nm and above opened the way to the study of well-defined biomolecule–mesoporous silica hybrids. In particular, it has been possible to immobilize a range of small to medium size enzymes, such as proteases, lipases and peroxidase…
A mechanism of persistent luminescence that was proposed in 1996 for has been widely adopted to explain afterglow in many and codoped aluminates and silicates. The mechanism involves the thermally activated release of a hole from in its excited 5d state to the valence band which is subsequently trapped by . In this wo…
Abstract We report calculations of electron inelastic mean free paths (IMFPs) for 50–2000 eV electrons in 14 elemental solids (Li, Be, diamond, graphite, Na, K, Sc, Ge, In, Sn, Cs, Gd, Tb, and Dy) and for one solid (Al) using better optical data than in our previous work. The new IMFPs have also been used to test our…
The synthesis of inorganic materials by biological systems is characterized by processes that occur at close to ambient temperatures, pressures and neutral pH. This is exemplified by biosilicification in marine organisms such as diatoms while laboratory-based synthesis of silica involves extreme temperature and pH con…
The long cherished goal of targeting drugs to specific sites in the body, where the pharmacological action is desired and sparing other tissues has been actively pursued all these years. The concept of magic bullets given by Ehrlich has now seen a metamorphosis to magic wands, in the form of targeted drug delivery sys…
Spin-coating is widely employed for the highly reproducible fabrication of thin film coatings over large areas with high structural uniformity. Research in recent years has extended the scope of spin-coating by chemically engineering the interface of support and solution to obtain specific structural order in the resu…
We study the optical properties of metamaterials made from cut-wire pairs or plate pairs. We obtain a more pronounced optical response for arrays of plate pairs -- a geometry which also eliminates the undesired polarization anisotropy of the cut-wire pairs. The measured optical spectra agree with simulations, revealin…
This review describes the use of macroemulsions as templates for the production of porous materials. We focus on the use of high internal phase emulsions in order to produce interconnected open porous structures. The review encompasses porous hydrophobic polymers, hydrophilic polymers, composites, silica, metal oxides…
Cryoelectron microscopy of biological molecules is among the hottest growth areas in biophysics and structural biology at present, and Frank is arguably the most distinguished practitioner of this art. CryoEM is likely over the next few years to take over much of the structural approaches currently requiring X-ray cry…
The dissolution of high surface area silica with tetralkylammonium hydroxides at concentrations greater than 0.2 M, produces polyanionic cage structures, [R4N+][−OSiO1.5]x or Qx, where x = 6, 8 or 10. The value x depends on the type of alkyl or alkanol group. If R = Me or Me3NCH2CH2OH+ group (choline) x = 8 is favored…
The potentialities offered by EDOT as a building block for the synthesis of functional π-conjugated systems are reviewed. The first part underlines the specific advantages of the EDOT unit for the design of precursors of electrogenerated functional conducting polymers combining high reactivity and low polymerization p…
Unsymmetrical dendrimers, containing both mannose binding units and coumarin fluorescent units, have been prepared using click chemistry and shown to be highly efficient, dual-purpose recognition/detection agents for the inhibition of hemagglutination.