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Photo-Ionization of Krypton Between 300 and 1500 eV. Relative Subshell Cross Sections and Angular Distributions of Photoelectrons

Manfred O. Krause1969-01-05Physical Review

Energy spectra of electrons ejected from $M$ and $N$ subshells of krypton by characteristic x rays of 300 to 1500 eV energy have been measured with an electrostatic analyzer. Krypton was irradiated in the gas phase and electrons were detected perpendicular to the x-ray beam. From these spectra, relative subshell contr…

Atomic and Molecular PhysicsX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Thermal decomposition of cyclopentyl and cyclohexyl acetates

Titus O. Bamkole、E. U. Emovon1969-01-01Journal of the Chemical Society B Physical Organic

The rate constants k1(sec.–1) for the thermal decompositions of cyclopentyl and cyclohexyl acetates in the presence of cyclohexene are 1012·89 exp (–44,110/RT) at 315–367° and 1012·59 exp (–45,190/RT) at 337–398° respectively. The decompositions are homogeneous and unimolecular in the seasoned Pyrex vessel. The relati…

Biodiesel Production and ApplicationsInsect Pheromone Research and ControlThermal and Kinetic Analysis

Fractographic Studies on the Cleavage Fracture of Single Crystals of Iron

K. Kitajima、Kōji Futagami1969-01-01OpenAlex

A critical experiment is presented for the mechanisms of initiation and propagation of cleavage crack in iron. At first, precise fractographic observations are made on the type of the origin of crack observed on single crystals of iron with notch. A number of cleavage facets are started from the boundary of a twin, an…

Microstructure and Mechanical Properties of SteelsFatigue and fracture mechanicsMaterial Properties and Failure Mechanisms

The Utility of Linear Polarization Method For The Determination of The Corrosion Rate

S. ÜNERİ1969-01-01Communications Faculty Of Science University of Ankara Series B Chemistry and Chemical Engineering

Bu çalışma linear polarizasyon metodunun bu günkü durumunu ve bugüne kadar korozyon hızı tayinine uygulanmasını göstermektedir. Bu metodun çok pra¬tik ve faydalı olduğu gösterilmiştir. Metodun genel bir uygulama alanı göstermesi ve uygulanmasının kolay olması büyük bir avantaj sağlamaktadır. Bu metotla ko¬laylıkla kor…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

On Quench Sensitivity of Cu-Cr Alloys

Shiro Sato、K oji Nagata1969-01-01Journal of the Japan Institute of Metals and Materials

A study was made on the quench sensitivity of Cu-0.3∼1.5%Cr alloys. The time-temperature-precipitation curve (T-T-P curve) was drawn by plotting the electrical conductivity of specimens which were solution treated and then directly quenched over the temperature range of isothermal heat treatment. The quench sensitivit…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsCopper Interconnects and Reliability

The Role of Wire Size in Negative Electrical Discharge at High Temperature

C.C. Shale、J. H. Holden1969-01-01IEEE Transactions on Industry and General Applications

Negative corona onset and sparkover voltages in air are shown to be affected by temperature, density, and the pipe-to-wire ratio of radii when using concentric cylindrical electrodes. Use of large wires at high temperatures demonstrates that onset of electrical discharge occurs at voltages significantly less than thos…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaAerosol Filtration and Electrostatic Precipitation

Analytic Form of Stress Fields, Displacements, and Dilation for the 〈111〉Dislocation in Anisotropic Elasticity

J. W. Steeds1969-01-01physica status solidi (b)

Abstract Screw, edge, and mixed dislocations are treated by a new method which is simple to handle. Labour saving equations are derived which further shorten the algebraic processes. The results emphasize the need for anisotropic expressions in the case of common cubic materials, and are presented in a form which show…

Microstructure and mechanical propertiesMetallurgy and Material FormingX-ray Diffraction in Crystallography

Differential Reflection Spectra of Heavily Doped Silicon and Germanium in the Ultraviolet Spectral Region

A. A. Vol'Fson、V. K. Subashiev1969-01-01physica status solidi (b)

Abstract The effect of heavy doping on the reflection spectra of silicon and germanium is investigated by measuring the fractional change in reflectance, Δ R / R , between pure and doped materials. This effect arises from the narrowing of the forbidden gap in heavily doped materials. The form of the Δ R / R spectrum a…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceSemiconductor materials and interfaces

Metal–halogen vibrational spectra of the five-co-ordinate complexes of indium trichloride and tribromide with diethyl ether and diethyl sulphide

C. A. Evans、Michael J. Taylor1969-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

Low-frequency i.r. and Raman spectra of InCl3,2Et2O, InBr3,2Et2O, InCl3,2Et2S, and InBr3,2Et2S are given and interpreted in terms of D3h skeletal symmetry.

Crystal structures of chemical compoundsSolid-state spectroscopy and crystallographyChemical Thermodynamics and Molecular Structure

On the Magnetic Properties of Dy3+ Ion in Dysprosium Ethylsulfate Single Crystal

S. P. Taneja1969-01-01physica status solidi (b)

Abstract Principal magnetic susceptibilities of single crystal of dysprosium ethylsulfate have been computed in the temperature range of liquid‐nitrogen to room temperature, assuming that the crystal field has C 3h symmetry around the Dy 3+ ion. It is observed that magnetic anisotropy increases with the decrease of te…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyMolecular spectroscopy and chirality

Temperature Change Experiments during Secondary Creep of the Intermetallic Compound MgZn2

D. Hinz、P. Paufler、G. E. R. Schulze1969-01-01physica status solidi (b)

Abstract From temperature change experiments (between 260 and 435°C) during secondary creep of the intermetallic compound MgZn 2 an activation enthalpy Δ H = (2.25 ± 0.20) eV for basal slip has been derived. The shear strain rate γ can best be described by the empirical relation γ = 7 × 10 11 s −1 × τ 5.5 ± 1.0 exp (‐…

Magnesium Alloys: Properties and ApplicationsRare-earth and actinide compoundsAluminum Alloys Composites Properties

Some investigations concerning the structure of ultraphosphates

J. Bernard Gill、Sara Riaz1969-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

Controlled hydrolytic degradation of ultraphosphate glasses at their branching sites has indicated that these compounds, with a ratio of univalent-cation to phosphorus between 0·7–1·0, consist of random arrangements of trimetaphosphate rings, polyphosphate chains, and branched chains. No ring structures larger than tr…

Glass properties and applicationsFlame retardant materials and propertiesPigment Synthesis and Properties

Evidence for the Coulomb Interaction of Be Valence Electrons by Compton Scattering Cross‐Section Measurements

W. Schülke、U.E.P. Berg、O. Brümmer1969-01-01physica status solidi (b)

Abstract The effect of Coulomb interaction on the Compton scattering cross‐section (CSCS) of a free electron gas has been calculated theoretically by Ohmura and Matsudaira within the framework of the random phase approximation (RPA). These calculations have shown that plasmon emission during the scattering process dim…

Advanced Chemical Physics StudiesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Precipitation in Beryllium-Iron Alloys

Shōtaro Morozumi、Nobuo Tsuno、Shigeyasu Koda1969-01-01Transactions of the Japan Institute of Metals

Hardness measurements and microscopic observations by both optical and transmission electron microscopy were carried out mainly on a beryllium-3wt% iron alloy.The alloy was solution-treated at 1150°C, followed by oil-quenching, and aged at 400° to 700°C for a various time. In the quenched specimens, helices and loops…

Fusion materials and technologiesIntermetallics and Advanced Alloy PropertiesNuclear Materials and Properties

Electromotive Force Investigation of the Bismuth-Tellurium System

Chung-Chiun Liu、John C. Angus1969-01-01Journal of The Electrochemical Society

The bismuth‐tellurium alloy system was investigated by electromotive force measurements, coulometric titrations, x‐ray diffraction, and differential thermal analyses. The thermodynamic properties of the system have been obtained from the electromotive force measurements. The partial molar free energy, enthalpy, and en…

Advanced Thermoelectric Materials and DevicesIntermetallics and Advanced Alloy PropertiesThermodynamic and Structural Properties of Metals and Alloys

The Influence of Microstructure on the Fracture Topography of Titanium Alloys

J. C. Williams、Rodney R. Boyer、M. J. Blackburn1969-01-01OpenAlex

A survey is presented of the fracture topography observed in titanium and titanium alloys. Ductile fracture by microvoid nucleation, growth, and coalescence is of widespread occurrence in these alloys. It is usually possible to qualitatively relate the dimple size to the macroscopic ductility of the alloy. Titanium al…

Hydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and PropertiesAdvanced materials and composites

EFFECTIVE DIFFUSIVITY OF MULTI-COMPONENT GASEOUS REACTION SYSTEM

Hiroshi Kubota、Yoko Yamanaka、I. G. Dalla Lana1969-01-01JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

It was illustratively shown that the use of a definition of the effective diffusivity for a multi -component gaseous reaction system easily gives a sufficiently accurate approximate solution for diffusion through a stagnant gas film. In order to apply the same idea for approximate estimation of the effectiveness facto…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies