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Control of polishing of diamond films using microactuation and an atmospheric pressure plasma

Matthew Scott Detrick、Gregory Washington、V. V. Subramaniam2003-03-01IEEE/ASME Transactions on Mechatronics

In this work, the diamond deposited by hot filament chemical vapor deposition (CVD) is polished using an atmospheric pressure plasma. In order to position the film relative to the plasma, a microactuator system is designed using a stack of domed piezoelectric actuators. A dynamic model based on the physical system is…

Diamond and Carbon-based Materials ResearchTribology and Lubrication EngineeringAdvanced Surface Polishing Techniques

Study of release and consumption of agents from active polymer packaging into food using dimensionless numbers

Mhammed El Kouali、M. Salouhi、F. Labidi 等 5 位作者2003-03-01Plastics Rubber and Composites Macromolecular Engineering

In protecting food, packagings are shifting from passive protection to taking an active role in improving food quality. The active packaging, consisting of a polymer liner with an active agent in it, is able to produce a desired effect on the food. A wide variety of active agents exist, such as antimicrobials, which c…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesAntimicrobial agents and applications

Low friction of a diamond/H-terminated Si

Hideki Masuda、Fuminori Honda2003-03-01IEEE Transactions on Magnetics

Hydrogen-terminated Si [111] surfaces have been studied for tribological performance in the sliding of a diamond slider to obtain fundamental information on contact problems between an Si memory disk and the slider. The authors focus on the tribological role of the atoms on the contact surfaces and observe an extraord…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

Deactivation of a Cu/Al2O3 Catalyst in a N2O Decomposition Reaction

Katsutoshi Tanaka、Atsushi Shimizu、Maiko Fujimori 等 5 位作者2003-03-01Bulletin of the Chemical Society of Japan

Abstract Dinitrogen oxide (nitrous oxide, N2O), a non-CO2 greenhouse gas, is produced as a by-product in the oxidation of cyclohexanone and cyclohexanol with nitric acid in adipic acid production plants. A Cu/Al2O3 catalyst has been used to decompose N2O to nitrogen and oxygen. We investigated the rate of deactivation…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Effects of Degree of Recycling on the Rheology and Processability of Thermoplastic Polymers

Aude-Héloïse Bonardi、R. Cilloni、V. Paganuzzi 等 4 位作者2003-03-01Journal of Polymer Engineering

The effects of recycling on the processability of two injection molding grade thermoplastic polymers has been investigated. Recycling of a Polypropylene (PP) and a Polyamide (Nylon 6, PA6) has been simulated by repeated injection molding cycles, followed by blending of the processed materials with the virgin polymer.…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

METALLOMESOGENS DERIVED FROM CHELATING SCHIFFS BASES CONTAINING 1,3,4-OXADIAZOLE AND 1,3,4-THIADIAZOLE: SYNTHESIS, CHARACTERIZATION AND STUDY OF MESOMORPHIC PROPERTIES

MARIA PARRA、Silvia Doñate Hernández、Joel B. Alderete2003-03-01Journal of the Chilean Chemical Society

The preparation of copper (II) and palladium (II) complexes derived from ligands of Schiff’s bases (L¹, L², L³, L4) incorporating 1,3,4-oxadiazole and 1,3,4-thiadiazole rings are reported. The thermal behaviour of the complexes was characterized by DSC, TGA and polarizing optical microscopy. Only the complexes derived…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesLanthanide and Transition Metal Complexes

Analysis of chemical bonding in the α and β modifications of zinc diphosphide from X-ray diffraction data

Igor E. Zanin、K. B. Aleĭnikova、Mikhail Yu. Antipin2003-03-01Crystallography Reports

With the aim of studying the characteristic features of chemical interactions between atoms in the α (red tetragonal) and β (black monoclinic) modifications of zinc diphosphide, the maps of deformation electron-density distribution at the P-P and P-Zn bonds were constructed from precision X-ray diffraction data. The P…

Boron and Carbon Nanomaterials ResearchSemiconductor materials and interfacesX-ray Diffraction in Crystallography

Characterization of the structure of porous germanium layers by high-resolution X-ray diffractometry

A. A. Lomov、V. A. Bushuev、V. A. Karavanskiǐ 等 4 位作者2003-03-01Crystallography Reports

The surface morphology and the structure of porous germanium layers obtained by chemical etching of n -type single-crystal Ge(111) substrates with their subsequent annealing in hydrogen atmosphere are studied by high-resolution X-ray diffractometry. It is established that upon etching a 1.5 to 2.0-μm-thick porous germ…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

A comparison of vapour pressure measurements of quinizarin and leuco‐quinizarin via transpiration and thermogravimetry

D. G. Hinks、Mohammed Rafiq、Duncan M. Price 等 5 位作者2003-03-01Coloration Technology

The vapour pressure of solids can be obtained using a number of methods, including the Knudsen effusion method, the Knudsen torque‐effusion method and a transpiration method. Each method has benefits and disadvantages. Reported is a comparison of vapour pressure data for two compounds, quinizarin and leuco ‐quinizarin…

Thermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structurethermodynamics and calorimetric analyses

Technical note : Anticorrosive behaviour of octadecylamine for protection of boiler surfaces

A. Rohani-Rad、J. Mofidi、Z. Modaress-Tehrani2003-03-01Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

The anticorrosive behaviour of octadecylamine (ODA) films has been investigated via weight loss and electrochemical methods. Tests were conducted on specimens of carbon steel, brass, and austenitic stainless steel in the presence and absence of amine films. Inhibitor efficiency values in excess of 94·5% were obtained…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilitySynthesis and properties of polymers

Catalytic decomposition of perfluoropolyether lubricants

Jianwei Liu、Michael Stirniman、Jing Gui2003-03-01IEEE Transactions on Magnetics

With the ongoing decrease in magnetic spacing, the chemical durability of the lubricant film on magnetic recording media becomes a major factor in the reliability of the head-disk interface. There are several reports in the literature that have attributed deterioration of lubricant film to catalytic decomposition, and…

Electronic Packaging and Soldering TechnologiesElectron and X-Ray Spectroscopy TechniquesPolymer Nanocomposite Synthesis and Irradiation

Growth of filamentary KDP crystals from solution with the addition of Al(NO3)3 · 9H2O

Dmitry A. Vorontsov、E. L. Kim、V. N. Portnov 等 4 位作者2003-03-01Crystallography Reports

To elucidate the mechanism of nucleation and growth of filamentary crystals on the bipyramid faces of KH 2 PO 4 (KDP) crystals from solution with the addition of Al(NO 3 ) 3 · 9H 2 O, the growth rates and transverse dimensions of the crystals were measured at various supersaturations, temperatures, and impurity concen…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchCrystallization and Solubility Studies

Thermal Aging of Twaron Fibers

Anjana Jain、Kalyani Vijayan2003-03-01High Performance Polymers

The residual effects of thermal aging on Twaron fibers have been studied using X-ray diffraction, weight analysis, scanning electron microscopy and tensile testing. X-ray data from isothermally aged fibers indicate the introduction of changes at the level of the crystal lattice, which include reduction in crystallinit…

Natural Fiber Reinforced CompositesTextile materials and evaluationsPlant Surface Properties and Treatments

Effect of hydrogen on the magnetic characteristicsof Nd2Fe14B single crystal

С.А. Никитин、И. С. Терешина、N. Yu. Pankratov 等 7 位作者2003-03-01physica status solidi (a)

Magnetic characteristics of the Nd2Fe14BHx single crystals and polycrystalline samples were investigated in the temperature range 4.2–750 K. It is established that hydrogen absorption does not change the crystal structure of these compounds but is accompanied by an expansion of a unit cell volume. The obtained data sh…

Magnetic Properties of Alloys

Treatment of thermoplastic rubberwith chlorine bleach as an alternative halogenation treatment in the footwear industry

C.M. Cepeda-Jiménez、M. Mercedes Pastor‐Blas、José Miguel Martín‐Martínez 等 4 位作者2003-03-01The Journal of Adhesion

Avoidance of solvents in bonding operations is a current demand in the footwear industry. Halogenation of rubber soles with solutions of trichloroisocyanuric acid (TCI) in different solvents has been successfully used to improve bonding to the leather uppers. In this study, the use of chlorine bleach as an alternative…

Polymer Nanocomposites and Properties

Silica agglomeration and elastomer reinforcement: Influence of surface modifications

J. Scott Parent、M. I. Mrkoci、S. L. Hennigar2003-03-01Plastics Rubber and Composites Macromolecular Engineering

The properties of precipitated silica modified with hexadecylamine, dodecanol, 9-decen-1-ol and γ-mercaptopropyltrimethoxysilane have been characterised and related to elastomer reinforcement capability. Extensive modification with these agents decreased the specific surface area and the critical surface energy of sil…

Asphalt Pavement Performance EvaluationPolymer Nanocomposites and PropertiesSilicone and Siloxane Chemistry

Optical Properties and Electronic Structure of Oxidized and Reduced Single-Crystal Strontium Titanate

A. Frye、Roger H. French、Dawn A. Bonnell2003-03-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract The measured optical and transport properties of single-crystal SrTiO3 have been determined as a function of oxidation and reduction using spectroscopic ellipsometry, Hall and resistivity measurements. A decrease in the valence to conduction band transitions across the band gap, from O 2p to Ti 3d states, is…

ZnO doping and propertiesFerroelectric and Piezoelectric MaterialsElectronic and Structural Properties of Oxides

The Crystallographic Restriction, Permutations, and Goldbach's Conjecture

John Bamberg、Grant Cairns、Devin Kilminster2003-03-01American Mathematical Monthly

Goldbach’s conjecture, the crystallographic restriction, and the orders of the elements of the symmetric group. First recall that for an element g of a group G the order Ord(g) of g is defined to be the smallest natural number such that g Ord(g) = id if such a number exists, and Ord(g) =∞otherwise. In dimension n, the…

Analytic Number Theory ResearchQuasicrystal Structures and PropertiesHistory and advancements in chemistry

Fluorine as a Donor Dopant in Barium Titanate Ceramics

Darko Makovec、Miha Drofenik、J. E. Baker2003-03-01Journal of the American Ceramic Society

We have studied the electrical properties and microstructure of fluorine‐doped BaTiO 3 ceramics. The samples were prepared using a classical ceramic technology that involved the calcination of intimately mixed powders of BaCO 3 , TiO 2 , and BaF 2 . When the samples were sintered in untreated ambient air, the fluorine…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisThermal Expansion and Ionic Conductivity

Steric‐Factor‐Directed Alternating Supramolecular Copolymer Composed of Hydrogen‐Bonded Cyclohexanetricarboxamide Units

Ryoichi Takasawa、Kazutoshi Murota、Isao Yoshikawa 等 4 位作者2003-03-01Macromolecular Rapid Communications

Abstract Hydrogen‐bonded supramolecular copolymers were easily prepared by mixing cyclohexanetricarboxamides with three ( 1 ) and six ( 2 ) alkylsilyl groups, and supramolecular fibers were fabricated. When the composition of 1 and 2 was at or close to equimolarity, the supramolecular copolymer chain was found to have…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials