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Twinning‐Mediated Growth of Al2O3 Nanobelts and Their Enhanced Dielectric Responses

Xiangming Fang、C.‐H. Ye、Li Zhang 等 4 位作者2005-07-01Advanced Materials

The twinning-mediated growth of Al2O3 nanobelts (see Figure) is successfully achieved by simple thermal evaporation. The as-synthesized Al2O3 nanobelts are composed of deformation twins along their entire length. The particular structures of these Al2O3 nanobelts apparently mimic those of plants such as bamboo, and th…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisAnodic Oxide Films and Nanostructures

Magnetic, transport and magnetotransport properties ofMn3+xSn1−xCandMn3ZnySn1−yCcompounds

Yameng Li、W. F. Li、Wei Feng 等 5 位作者2005-07-01Physical Review B

The magnetic, transport, and magnetotransport properties of ${\mathrm{Mn}}_{3+x}{\mathrm{Sn}}_{1\ensuremath{-}x}\mathrm{C}$ $(0\ensuremath{\leqslant}x\ensuremath{\leqslant}0.4)$ and ${\mathrm{Mn}}_{3}{\mathrm{Zn}}_{y}{\mathrm{Sn}}_{1\ensuremath{-}y}\mathrm{C}$ $(0\ensuremath{\leqslant}y\ensuremath{\leqslant}0.9)$ comp…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsThermal Expansion and Ionic Conductivity

Recent Developments in Crosslinking of Elastomers

Abi Santhosh Aprem、Kuruvilla Joseph、Sabu Thomas2005-07-01Rubber Chemistry and Technology

Abstract The recent developments in the vulcanization of elastomers, major types of crosslinking, and mechanism of crosslinking have been reviewed. Attention has been made to sum up the accelerated vulcanization. Possible mechanisms by which the reaction is taking place are discussed. The role of accelerators, activat…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymers

Temperature Dependence of Order, Disorder, and Defects in Laterally Confined Diblock Copolymer Cylinder Monolayers

Matthew R. Hammond、Eric W. Cochran、Glenn H. Fredrickson 等 4 位作者2005-07-01Macromolecules

Monolayer arrays of polystyrene−poly(2-vinylpyridine) diblock copolymer cylinders with excellent orientational order and a very low density of dislocations are prepared by cooling slowly from above the bulk order−disorder temperature (ODT) ∼212 °C within silicon oxide channels one cylinder spacing a in depth and 2 μm…

Organic Electronics and PhotovoltaicsThermal properties of materialsBlock Copolymer Self-Assembly

The Microstructure of Copper Zinc Oxide Catalysts: Bridging the Materials Gap

Thorsten Ressler、Benjamin Kniep、Igor Kasatkin 等 4 位作者2005-07-01Angewandte Chemie International Edition

Approaching reality: Copper zinc oxide catalysts that were prepared similarly to industrial catalysts were studied by high-resolution electron microscopy. The microstructure of the Cu/ZnO catalysts (see picture) deviates considerably from that of idealized copper model systems. Future model systems for copper catalyst…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCopper-based nanomaterials and applications

Borate crystal chemistry in terms of the extended OD theory: topology and symmetry analysis

Е. Л. Белоконева2005-07-01Crystallography Reviews

The crystal chemical analysis of the class of borates has been carried out using the extended Dornberger-Schiff order–disorder (OD) theory based on the recognition of building blocks of various dimensions. All of the borate structures are built from several fundamental building blocks typical for every group of hexa-,…

Crystallography and molecular interactionsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Role of the diffuse layer of the ionic charge on the impedance spectroscopy of a cell of liquid

G. Barbero、A. L. Alexe‐Ionescu2005-07-01Liquid Crystals

We investigate the role of the diffuse layer of the ionic cloud on impedance spectroscopy measurements. The analysis is performed assuming that the ions have equal mobility, the electrodes are perfectly blocking and adsorption phenomenon can be neglected. We find that the dielectric permittivity, in the limit of high…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical StudiesElectrostatics and Colloid Interactions

A Single-Chain Magnet Formed by a Twisted Arrangement of Ions with Easy-Plane Magnetic Anisotropy

Takashi Kajiwara、Motohiro Nakano、Yukihiro Kaneko 等 10 位作者2005-07-01Journal of the American Chemical Society

A unique "single-chain quantum magnet" was formed by an alternating arrangement of high-spin FeII/low-spin FeIII ions. Although the predominant spin-carrier components (high-spin FeII) possess easy-plane magnetic anisotropy (D > 0), twisted arrangement of easy-planes along the chain axis defines a novel class of one-d…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications

Electron transport in ZnO thin films

T. Makino、Y. Segawa、A. Tsukazaki 等 5 位作者2005-07-01Applied Physics Letters

Epitaxial n-type ZnO films grown by a laser molecular-beam epitaxy method were investigated by the temperature-dependent Hall-effect technique. The 300K carrier concentration and mobility were about ns∼1016cm−3 and 440cm2∕Vs, respectively. Transport characteristics are calculated by solving the Boltzmann transport equ…

ZnO doping and propertiesQuantum and electron transport phenomenaChemical and Physical Properties of Materials

Iterated stretching and multiple beads-on-a-string phenomena in dilute solutions of highly extensible flexible polymers

Mónica Oliveira、Gareth H. McKinley2005-07-01Physics of Fluids

The dynamics of elastocapillary thinning in high molecular weight polymer solutions are reexamined using high-speed digital video microscopy. At long times, the evolution of the viscoelastic thread deviates from self-similar exponential decay and the competition of elastic, capillary, and inertial forces leads to the…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferAdhesion, Friction, and Surface Interactions

Self‐Assembly of Semifluorinated Janus‐Dendritic Benzamides into Bilayered Pyramidal Columns

Virgil Percec、Mohammad R. Imam、Tushar Kanti Bera 等 6 位作者2005-07-01Angewandte Chemie International Edition

Two faces: Semifluorinated Janus-dendritic benzamides self-assemble into supramolecular bilayered pyramidal columns with diameters over twofold greater than those of columns generated from twin-dendritic benzamides (see model). The Janus-dendritic benzamides are synthesized by selectively replacing the aliphatic chain…

Liquid Crystal Research AdvancementsSupramolecular Self-Assembly in MaterialsDendrimers and Hyperbranched Polymers

Dependence of zinc oxide thin film properties on filtered vacuum arc deposition parameters

T. David、S. Goldsmith、R.L. Boxman2005-07-01Journal of Physics D Applied Physics

The micro-properties (structure and composition) and macro-properties (electrical and optical properties) of zinc oxide thin films deposited on glass substrates using a filtered vacuum arc deposition system were investigated as a function of oxygen pressure (0.37–0.5 Pa) and arc current (100–300 A). The films were pol…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsElectronic and Structural Properties of Oxides

Nontrivial dependence of dielectric stiffness on bias field in relaxors and dipole glasses

S. A. Prosandeev、I. P. Raevski、A. S. Emelyanov 等 8 位作者2005-07-01Journal of Applied Physics

Dielectric permittivity studies in the field-cooled mode show a linear dependence of dielectric stiffness (inverse dielectric permittivity) on the dc bias in (1−x)PbMg1∕3Nb2∕3O3−xPbTiO3 crystals. We explain this unusual result in the framework of a theory of transverse, hydrodynamic-type instability of local polarizat…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis

Bacteriostasis and Skin Innoxiousness of Nanosize Silver Colloids on Textile Fabrics

Hoon Joo Lee、Sung Hoon Jeong2005-07-01Textile Research Journal

This research deals with the bacteriostasis and the skin-innoxiousness of a nanosize silver colloidal solution used as an agent for the antibacterial treatment of textile fabrics. We placed nanosize silver colloidal solutions and the textile fabrics treated with the same solutions on germ-containing agar plates, respe…

Nanoparticles: synthesis and applicationsPharmaceutical and Antibiotic Environmental ImpactsAntimicrobial agents and applications

Progress in computer simulations of liquid crystals

Mark R. Wilson2005-07-01International Reviews in Physical Chemistry

This article reviews some of the recent progress in the simulation of liquid crystals across a range of length and time scales. Simulators now have an extensive range of models at their disposal, ranging from fully atomistic studies where each atom is represented in a simulation, via hard or soft anisotropic potential…

Liquid Crystal Research AdvancementsPolymer Surface Interaction StudiesAdvanced Materials and Mechanics

Dynamic regimes of fluids simulated by multiparticle-collision dynamics

Marisol Ripoll、K. Mussawisade、Roland G. Winkler 等 4 位作者2005-07-01Physical Review E

We investigate the hydrodynamic properties of a fluid simulated with a mesoscopic solvent model. Two distinct regimes are identified, the "particle regime" in which the dynamics is gaslike and the "collective regime" where the dynamics is fluidlike. This behavior can be characterized by the Schmidt number, which measu…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesLattice Boltzmann Simulation Studies

Size effect on the crystal structure of barium titanate nanoparticles

Masatomo Yashima、Takuya Hoshina、Daiju Ishimura 等 7 位作者2005-07-01Journal of Applied Physics

A size effect on crystal structure has been investigated for barium titanate (BaTiO3) nanoparticles of 40-, 140-, and 430-nm sizes, by means of neutron and high-resolution synchrotron x-ray powder-diffraction and Raman-scattering techniques. These samples were prepared by a modified two-step thermal decomposition meth…

Ferroelectric and Piezoelectric MaterialsHigh-pressure geophysics and materialsX-ray Diffraction in Crystallography

Ultra-narrow bright spatial solitons interacting with left-handed surfaces

A. D. Boardman、Larry Velasco、Neil King 等 4 位作者2005-07-01Journal of the Optical Society of America B

A vectorial finite-difference time-domain (FDTD) method is used to present a numerical study of very narrow spatial solitons interacting with the surface of what has become known as a left-handed medium. After a comprehensive discussion of the background and the family of surface modes to be expected on a left-handed…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsNonlinear Photonic Systems

Negative Refraction in Perspective

A. D. Boardman、Neil King、L. Velasco2005-07-01Electromagnetics

The concept of negative refraction is attracting a lot of attention. The initial ideas and the misconceptions that have arisen are discussed in sufficient detail to understand the conceptual structure that binds negative refraction to the existence of backward wave and forward wave phenomena. A presentation of the pro…

Metamaterials and Metasurfaces ApplicationsAdvanced Optical Imaging TechnologiesOptical and Acousto-Optic Technologies

Incorporation of cobalt into ZnO nanoclusters

Igor Ozerov、Francoise Chabre、Wladimir Marine2005-07-01arXiv

The structural, optical and magnetic properties of nanostructured ZnO films co-doped with cobalt and aluminium have been studied. The nanocrystalline films, with cluster sizes in range 50 - 100 nm, were deposited by pulsed laser ablation in a mixed atmosphere of oxygen and helium. The nanocrystallites have the wurtzit…

Materials Sciencecond-mat.other