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Phase Separation by Spinodal Decomposition in the Tetragonal System

V. S. STUBIČAN、A. H. Schultz1970-04-01Journal of the American Ceramic Society

Coherent spinodal curves for the [001] and [100] directions were calculated for the system TiO 2 ‐SnO 2 . Inside the [001] spinodal curve, the crystalline solutions decomposed by a modulated phase composed of TiO 2 ‐rich and SnO 2 ‐rich plates perpendicular to the [001] direction. No modulation of structure was observ…

Solidification and crystal growth phenomenaMetallurgical Processes and Thermodynamicsnanoparticles nucleation surface interactions

Specific Heat of Antimony and Bismuth between 0.03 and 0.8 K

H. Collan、M. Krusius、G. R. Pickett1970-04-01Physical review. B, Solid state

The specific heats of the semimetals antimony and bismuth have been measured from 0.03 to 0.8 K. The best fit to the antimony data yields ${C}_{p}=4.55{T}^{\ensuremath{-}2}+119T+180{T}^{3}$ \ensuremath{\mu}J/mole K. The ${T}^{\ensuremath{-}2}$ term associated with the nuclear quadrupole interaction is in good agreemen…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermodynamic and Structural Properties of Metals and Alloys

Mechanical Relaxations in Mixed Alkali Silicate Glasses: II, Discussion*

James E. Shelby、Delbert E. Day1970-04-01Journal of the American Ceramic Society

The internal friction of mixed Li‐Na, Li‐K, Li‐Rb, Li‐Cs, Na‐K, Na‐Rb, Na‐Cs, and K‐Rb silicate glasses is interpreted on the basis of the various explanations proposed for the mixed alkali effect. A direct correlation was found between the mechanical loss peak due to the stress‐induced movement of the alkali ions, i.…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsMicrowave Dielectric Ceramics Synthesis

Surface Treatment of Polypropylene for Adhesive Bonding

H. Schonhorn、F. W. Ryan、R. H. Hansen1970-04-01The Journal of Adhesion

The CASING (crosslinking by activated species of inert gases) treatment of polypropylene film in both oxygen and nitrous oxide is shown to be an effective surface treatment for conventional adhesive bonding. A crosslinked surface extending to a depth of about 300 Å, apparently independent of exposure time, is produced…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAnalytical Chemistry and Sensors

Mass spectral evidence for catenanes formed via a "Moebius-strip" approach

David A. Ben-Efraim、Christopher Batich、E. Wasserman1970-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMass spectral evidence for catenanes formed via a "Moebius-strip" approachDavid A. Ben-Efraim, C. Batich, and E. WassermanCite this: J. Am. Chem. Soc. 1970, 92, 7, 2133–2135Publication Date (Print):April 1, 1970Publication History Published online1 May 2002Published inissue…

Diatoms and Algae ResearchHistory and advancements in chemistry

Preparation of a polyimide foam

William J. Farrissey、James S. Rose、P.S. Carleton1970-04-01Journal of Applied Polymer Science

Abstract The reaction of phenyl isocyanate with phthalic anhydride to form N‐phenylphthalimide is strongly solvent dependent and catalyzed by tertiary amines. Water and alcohol promote imide formation, but Lewis acids and organometallic compounds are ineffective. In DMSO solvent, benzophenone tetracarboxylic dianhydri…

Flame retardant materials and propertiesCarbon dioxide utilization in catalysisSynthesis and properties of polymers

Tunneling States of Defects in Solids

V. Narayanamurti、R. O. Pohl1970-04-01Reviews of Modern Physics

The various optical, caloric, dielectric, elastic, and microwave investigations which have been used to study the tunneling states connected with the motion of atomic and molecular impurities in alkali halides are reviewed.

Photorefractive and Nonlinear OpticsThermal properties of materialsSolid-state spectroscopy and crystallography

Effects of monomer impurities on the emulsion polymerization of chloroprene and properties of polychloroprene. II. Effect of monovinylacetylene

Miloslav Sufčák1970-04-01Journal of Applied Polymer Science

Abstract The free‐radical emulsion polymerization of chloroprene containing monovinylacetylene in concentrations from 0% to 10% has been studied. It was found that in the presence of monovinylacetylene, a polymer with a great gel content, increased values of plasticity, and deteriorated physical and mechanical propert…

Material Properties and Applications

Calcination von Aluminiumhydroxid in einer zirkulierenden Wirbelschicht

Lothar Reh1970-04-01Chemie Ingenieur Technik

Abstract Steigende Qualitätsanforderungen an das für die Schmelzfluß‐Elektrolyse zur Aluminium‐Gewinnung benötigte Aluminiumoxid führten zur Entwicklung eines neuen Wirbelschichtverfahrens zur Entwässerung von Aluminiumhydroxid. Das Verfahren, in dessen aus Wirbelschichtofen und Rückführzyklon gebildeten Hochtemperatu…

Advanced ceramic materials synthesisElectrophoretic Deposition in Materials Science

Ionic Relations of Marine Algae II. Griffithsia: Ionic Fluxes

GP Findla、AB Hope、EJ Williams1970-04-01Australian Journal of Biological Sciences

Measurements were made of ionic fluxes in cells of the marine algae G. monile and G. pulvinata. The data for sodium and chloride fluxes appear to be consistent with the usually proposed model for the plant cell in which the vacuolar, cytoplasmic, and external compartments are in series, with the cytoplasm bounded on t…

Marine and coastal plant biologyDiatoms and Algae ResearchScientific Research and Discoveries

Lifetime of the 4T2g state of chromium(III) complexes

Shou-Nan Chen、Gerald B. Porter1970-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleLifetime of the 4T2g state of chromium(III) complexesShou-Nan Chen and Gerald B. PorterCite this: J. Am. Chem. Soc. 1970, 92, 7, 2189–2190Publication Date (Print):April 1, 1970Publication History Published online1 May 2002Published inissue 1 April 1970https://pubs.acs.org/doi/10…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesChemical Thermodynamics and Molecular Structure

Magnetic Properties of RXO4 System

H. Saji、T. Yamadaya、M. Asanuma1970-04-01Journal of the Physical Society of Japan

The magnetizations of phosphates and vanadates of rare-earth elements RXO 4 (R=Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er and Yb, and X=P and V) were studied in the temperature range of 1.9°K to 630°K. There were not found any magnetic transitions between 4.2°K and 630°K for all system, while F. F. Y. Wang et al. reported som…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Purification and properties of threonine aldolase from Clostridium pasterianum

R.H. Dainty1970-04-01Biochemical Journal

1. Threonine aldolase was purified about 200-fold in 10% yield from Clostridium pasteurianum and its properties were examined. The final preparation gave three bands after ionophoresis on polyacrylamide gel. 2. The purified enzyme was shown to produce glycine and acetaldehyde in stoicheiometric amounts from threonine.…

Enzyme Structure and FunctionEnzyme function and inhibitionAmino Acid Enzymes and Metabolism

High molecular weight boron sulfides. V. Vaporization behavior of the boron-sulfur system

Horng-Yih Chen、Paul W. Gilles1970-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh molecular weight boron sulfides. V. Vaporization behavior of the boron-sulfur systemHorng-Yih Chen and Paul W. GillesCite this: J. Am. Chem. Soc. 1970, 92, 8, 2309–2312Publication Date (Print):April 1, 1970Publication History Published online1 May 2002Published inissue…

Graphene research and applications2D Materials and ApplicationsMolecular Junctions and Nanostructures

Zum IR‐Spektrum des Nitrosodicyanmethanid‐Ions [ONC(CN)2]−

Alfred Kolbe、Helmut Köhler1970-04-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Das IR‐Spektrum von [ONC(CN) 2 ] − wird beschrieben. Die Zuordnung der Banden geschieht mit Hilfe von partieller 15 N‐Substitution. Bildet dieses Anion Komplexe, so verschieben sich seine IR‐Banden. Die Verschiebungen werden angegeben und die möglichen Bindungsverhältnisse diskutiert. Ferner wird ein unerwart…

Magnetism in coordination complexesNonlinear Optical Materials ResearchOrganic and Molecular Conductors Research

Interstitial Order-Disorder Transformation in the Ti-O Solid Solution. IV. A Neutron Diffraction Study

S. Yamaguchi、Kenzi Hiraga、Makoto Hirabayashi1970-04-01Journal of the Physical Society of Japan

Interstitial order-disorder transformation regarding oxygen atoms dissolved in alpha-titanium has been studied by neutron diffraction on single crystals in the range from 17 to 28 at% O. Occupation probabilities of the oxygen atoms in the octahedral interstitial sites are determined quantitatively with the variation o…

Intermetallics and Advanced Alloy PropertiesNuclear Materials and PropertiesTitanium Alloys Microstructure and Properties

Spin Arrangement in the Pyrite, MnTe2

J. M. Hastings、L. M. Corliss、M. Blume 等 4 位作者1970-04-01Physical review. B, Solid state

An inconsistency between M\"ossbauer and neutron-diffraction measurements on Mn${\mathrm{Te}}_{2}$ is resolved. A new generalization of magnetic ordering of the first kind preserves the characteristic neighbor relationships of that scheme and at the same time accounts for the M\"ossbauer results.

Crystal Structures and PropertiesAdvanced Condensed Matter PhysicsIron-based superconductors research

Some filler effects on diffusion in silicone rubber

Clark F. Most1970-04-01Journal of Applied Polymer Science

Abstract The diffusion of ethyl p ‐aminobenzoate in silicone rubber membranes containing varying amounts of a high surface area fumed silica filler is described, as is a new apparatus for assaying multiple samples. It is shown that increased filler loading results in what appears to be a linear decrease in transmissio…

Polymer Nanocomposites and PropertiesAnalytical Chemistry and ChromatographyAnalytical Chemistry and Sensors

Response of Cracks to Impact

B. Steverding、Siegfried H. Lehnigk1970-04-01Journal of Applied Physics

The equation of motion for cracks which are subjected to stress pulses is derived by the Lagrangian method. An asymptotic solution is used to determine terminal crack velocity. The time in which essentially constant velocity will be reached is determined. The equation is further used to formulate a dynamic stability c…

Fluid Dynamics Simulations and InteractionsHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads