Materials Literature
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A binuclear ion ([NH(3))5RuN(2)Ru(NH(3))(5)](5)+ is formed by the direct reaction of N(2) with an aqueous solution of (NH(3))(5)RuOH(2)(2+) at room temperature. The binuclear ion is also formed by the reversible reaction of (NH(3))5RuOH(2)(2+) with (NH(3))(5)RuN(2)(2+). Solid [(NH(3))(5)RuN(2)Ru(NH(3))(5)] (BF(4))(4)…
The infrared absorption spectrum of KH2PO4, KD2PO4, and KH2AsO4 single crystals has been measured from 3000-1000 cm−1 over a temperature range from 20°-300°K. Three broad absorptions are found at 2670, 2360, and 1720 cm−1 which are associated with the hydrogen bonds. The two upper frequencies are stronger for light po…
Mössbauer spectra of naturally occurring mineral chalcopyrite have been studied over a temperature range 300°–448°K. The spectra showed a typical pattern of six absorption lines due to the internal magnetic field. The Q.S. have values which are independent of temperature whereas the magnitudes of the internal magnetic…
Measurements of the galvanomagnetic properties of single-crystal graphite were made at 4.2\ifmmode^\circ\else\textdegree\fi{}K in pulsed magnetic fields up to 160 kG. With the magnetic field parallel to the $c$ axis, the transverse magnetoresistance is approximately proportional to the magnetic field strength, and the…
Absolute-reflectance measurements of single-crystal Re${\mathrm{O}}_{3}$ in the spectral range 0.2-22 eV are analyzed by Kramers-Kronig relations to give the real and imaginary parts of the dielectric constants. The dielectric constant is characteristic of free-electron behavior below the sharp plasma edge at 2.1 eV,…
Potassium nitrite frequently contains significant nitrate impurity, detectable by vibration spectroscopy. Analyses based independently on infrared and Raman band intensities permit a quantitative determination of the nitrate impurity. Reassignment of some previously reported vibrational frequencies is discussed.
Shock-wave compression measurements from 20 to 300 kbar are reported for hexagonal boron nitride. A phase transition occurs at 122 kbar and 230°C in good agreement with static data. The volume decrease is approximately 19% and the estimated slope of the phase line for the solid–solid transition is −3.6 × 10−2kbar °C−1…
Frequency assignments for the vibrational modes of species Bu in CaWO4 and CaMoO4 are made. Bu modes are both infrared inactive and Raman inactive in unstrained material, but become infrared active and exhibit Eu characteristics under xz or yz shear strain and Au characteristics under xy shear strain. In the present p…
The infrared spectra of rare earth acetates have been studied to examine the metal-acetate bonding. The thermal decomposition of rare earth acetates as well as lead and copper acetates have been investigated in detail by employing thermogravimetric analysis and differential thermal analysis. Thermal decomposition of c…
The temperature dependence of the resistance of iron has been measured in the range 1 to 4.2\ifmmode^\circ\else\textdegree\fi{}K. Single-crystal iron specimens 100 to 300 \ensuremath{\mu} in diameter with residual resistance ratios up to 2100 were used in the experiments. The dominant temperature dependence in this ra…
The exact eigenvalue spectrum and thermodynamic properties of the spin Hamiltonian $\mathcal{H}=2|J|\ensuremath{\Sigma}\stackrel{\frac{N}{2}}{i=1}({\mathrm{S}}_{2i}\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{S}}_{2i\ensuremath{-}1}+a{\mathrm{S}}_{2i}\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{S}}_{2i+1})…
Received 20 November 1967DOI:https://doi.org/10.1103/PhysRevLett.20.59©1968 American Physical Society
The anodic behavior of Fe-Si alloys containing 2∼22% Si in deaerated H2SO4 solution (20°C) was studied by the potentiostatic method. The effects of the Si content on the corrosion potential Ecorr., passivation potential Ep, passivation current density Ip and passive current density ik were determined. The effects of c…
The preparation and properties of silver tripolyphosphate have been investigated. It has been found that silver tripolyphosphate dihydrate decomposes on heating, first into anhydrous silver tripolyphosphate forms I and II, and subsequently into crystalline silver pyrophosphate together with a glass containing ortho-,…
Three broad types of natural graphites are recognized: flake, vein, and amorphous. The compaction of graphite powders, representing these types, into coherent binderless artifacts at room temperature and pressures up to 125, 000 psi has been studied. The graphite powders were characterized as to their particle size di…
The chemical structures of the color reaction products (Ib and Ic) obtained from butyl-and p-tolyl-urea with diacetyl monoxime and glucuronolactone in phosphoric acid were elucidated by their physical properties. Ib develops immediately a red color in phosphoric acid and is thought to be one of the main reaction produ…
Tests are described on the adhesive strength of gold films deposited on glass substrate under tensile loads. Through a flat-topped rivet fixed by an adhesive onto the film the force to pull the film was transmitted normally to the substrate surface. This force was measured by a spring balance at two increasing rates o…
Magnesium ammonium phosphate hexahydrate MgNH4PO4,6H2O and magnesium hydrogen phosphate trihydrate MgHPO4,3H2O have been heated to temperatures up to 1220° and X-ray powder photographs taken of the products. Both substances decompose during the process and gradually change first into an amorphous phase and then into c…
Résultats de spectrométrie α pour 224Ac 27 raies, 223Ac 25 raies, 220Fr 15 raies, 219Fr 6 raies.
L'afghanite, nouvel alumino˗silicate de sodium, calcium et potassium, a été découverte dans la mine de lapis-lazuli de Sar-e-Sang, Badakhshan, Afghanistan. Hexagonale avec a = 12,77, c = 21,35 Å, V = 3015 ų, les groupes de symétrie possible étant P6₃/mmc, P6₃mc ou P[-6]2c. Z = 3 (Na,Ca,K)₁₂ (Si, Al)₁₆ O₃₄ (Cl, SO₄, C…