Materials Literature
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The replacement of magnetite by hematite is not by octant sectors but is independent of sample coordinates and is penetrative to at least the scale of developed \[111\] parting. Anisotropy increases with depth into the octahedron. Hematite c-axis orientation perfection occurs 5 mm deep into the crystal. The replacemen…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAnionic ring-opening polymerization of thiolactonesCharles G. Overberger and Jurgen K. WeiseCite this: J. Am. Chem. Soc. 1968, 90, 13, 3533–3537Publication Date (Print):June 1, 1968Publication History Published online1 May 2002Published inissue 1 June 1968https://pubs.acs.or…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA new structural type for heteropoly anions. The crystal structure of (NH4)2H6(CeMo12O42).12H2ODavid D. Dexter and J. V. SilvertonCite this: J. Am. Chem. Soc. 1968, 90, 13, 3589–3590Publication Date (Print):June 1, 1968Publication History Published online1 May 2002Published…
Single crystals of Pb(Fe 1/2 Ta 1/2 )O 3 were grown from ternary melts with excess PbO. The crystals, having cubic perovskite structure at room temperature, undergo a ferroelectric phase transition at about 243°K, changing to rhombohedral structure. The dielectric constant passes through a maximum of nearly 9500 at 1…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMagnetic, Moessbauer, and structural studies on three modifications of FeMoO4A. W. Sleight, B. L. Chamberland, and J. F. WeiherCite this: Inorg. Chem. 1968, 7, 6, 1093–1098Publication Date (Print):June 1, 1968Publication History Published online1 May 2002Published inissue 1…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSilylene chemistry. I. The thermolysis of methoxypolysilanesWilliam H. Atwell and Donald R. WeyenbergCite this: J. Am. Chem. Soc. 1968, 90, 13, 3438–3443Publication Date (Print):June 1, 1968Publication History Published online1 May 2002Published inissue 1 June 1968https://pu…
Abstract Die Nitrierung und Denitrierung von α‐Eisen durch die Reaktion magnified image wurde in einer Durchströmungsapparatur an dünnen Eisenfolien zwischen 300 und 800 °C mit Hilfe von Widerstandsmessungen untersucht. Unter diesen Bedingungen werden Aussagen zur Kinetik der Oberflächenreaktionen erhalten. Die Reakti…
High frequency cyclic voltages on a specimen surface have been studied pictorially, in the scanning electron microscope, by applying the principle of the sampling oscilloscope. The electron beam in the microscope column is pulsed, and the phase varied with respect to that of the waveform on the specimen. With 10 ns el…
It is shown how the method of measuring fabric drape by supporting a circular specimen of fabric between smaller horizontal circular plates has been modified to allow a more sensitive test to be made on very stiff and very limp fabrics. The use of diverging light instead of parallel light is described, and the correct…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreexponential factors for solid-state thermal decompositionHerman F. CordesCite this: J. Phys. Chem. 1968, 72, 6, 2185–2189Publication Date (Print):June 1, 1968Publication History Published online1 May 2002Published inissue 1 June 1968https://doi.org/10.1021/j100852a052RIGH…
The optical absorption and fluorescence spectra of two spinels, ZnAl2O4:Cr3+ and MgAl2O4:Cr3+ have been measured at various temperatures between 2°K and room temperature. The data have been fitted to a crystal-field theory which includes spin-orbit coupling and the trigonal field of the D3d site. The parameters for a…
The thermal behavior of amorphous hydrated zirconium oxide and its coprecipitates with other oxides was studied. Solid solution with a limit of solubility seems to exist in the amorphous coprecipitates. A relation with the high‐temperature solid solution was established. The structure of the amorphous zirconia was stu…
Abstract Vermiculites and smectites in soils and sediments are frequently partially interlayered or “chloritized”. Dioctahedral expansible layer silicates are those most frequently interlayered, and hydroxy-Al appears to be the principal component of the non-exchangeable interlayer material. The most favorable soil co…
An electrostatic lens system which compensates for chromatic aberration has been tested in an electron spectrometer. The results indicate that this lens is suitable for comparisons of peak intensities in electron-impact spectra. Relative intensities in vibrational progressions that belong to a single electronic transi…
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