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Synthesis, characterization and conductivity measurements of polyaniline and polyaniline/fly‐ash composites

Himanshu Narayan、Hailemichael Alemu、Emmanuel I. Iwuoha2006-10-19physica status solidi (a)

Abstract Polyaniline (PANI) and polyaniline/fly ash (PANI/FA) composites with various concentrations of fly ash (20%, 40% and 50%) were synthesized by the process of in‐situ polymerization. The samples were characterized by powder X‐ray diffraction, thermogravimetric analysis, infrared spectroscopy, and scanning elect…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Effects of Particle Size on Melt Viscoelastic Properties During Capillary Extrusion of Glass Bead-filled LDPE Composites

Ji‐Zhao Liang2006-10-19Journal of Thermoplastic Composite Materials

ABSTRACT: In this study, the viscoelastic properties of a low-density polyethylene (LDPE) filled with glass beads (GBs) are measured at 150 C by means of a capillary rheometer to identify the effect of the particle size on the melt viscoelasticity. The volume fraction of the GB was 8.4%. The surface of the particles h…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Structure and properties of polyurethane foams obtained from rapeseed oil polyols

Uldis Stirna、Irina Sevastyanova、Maria Misane 等 5 位作者2006-10-19Proceedings of the Estonian Academy of Sciences Chemistry

By transesterifying rapeseed oil with tr iethanolamine or glycerol, polyols with a hydroxyl number of 290-310 mg KOH/g were synthesized. Water-blown rigid polyurethane foams (PUFs) with an isocyanate index of 150-250 were obtained from rapeseed oil polyols. Studies on the effect of the concentration of potassium oleat…

Polymer composites and self-healing

Recycling of PP-based Sandwich Panels with Continuous Fiber Composite Skins

Paolo Corvaglia、Alessandra Passaro、O. Manni 等 5 位作者2006-10-19Journal of Thermoplastic Composite Materials

ABSTRACT: In this article, a procedure for recycling of polypropylene (PP)-based sandwich panels is presented. PP/glass laminates as the skins and PP foam as the core material are used. The waste panel is converted into short-fiber composite material. The panel is first ground by a mill and homogenized in a mixer or a…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Variation of the Network Anisotropy of Cholesteric Side Chain Elastomers

Christian Bourgerette、Bin Chen、Heino Finkelmann 等 6 位作者2006-10-19Macromolecules

A series of cholesteric side chain elastomers with odd and even numbers of atoms along the spacer chain were prepared. Varying the content of odd and even spacer groups resulted in anisotropic main chain conformations changing from prolate to oblate. The conformation anisotropy was characterized by temperature-depende…

Polymer Nanocomposites and PropertiesBlock Copolymer Self-AssemblyNanofabrication and Lithography Techniques

Fine‐grained erbium‐doped strontium hexaferrite

N. Rezlescu、Corneliu Doroftei、E. Rezlescu 等 4 位作者2006-10-19physica status solidi (a)

Abstract In the present work the Er‐substituted Sr hexaferrite, SrFe 12– x Er x O 19 , prepared by sol–gel self combustion and subsequent heat treatments, is investigated. The combusted powders were annealed at 800, 900 and 1000 °C for 5, 10, 20, 40, 80, 160 and 320 min. The influence of annealing temperature and time…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesMagnetic Properties of Alloys

A DFT Study on the Electronic and Redox Properties of [PW11O39(ReN)]n–(n = 3, 4, 5) and [PW11O39(OsN)]2–

Li‐Kai Yan、Zhuo Dou、Wei Guan 等 5 位作者2006-10-19European Journal of Inorganic Chemistry

Abstract DFT calculations were carried out to investigate the electronic and redox properties of nitrido‐functionalized polyoxometalate species, [PW 11 O 39 (ReN)] n – ( n = 3, 4, 5) and [PW 11 O 39 (OsN)] 2– . The rhenium‐ and osmium‐nitrido effectively modify the electronic properties. The LUMOs in fully oxidized [P…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

In-plane anisotropy in the magnetic and transport properties of manganite ultrathin films

P. Orgiani、A. Yu. Petrov、Carolina Adamo 等 10 位作者2006-10-19Physical Review B

To analyze the conducting and magnetic properties near the film and substrate interface in manganites, ultrathin films $(\mathrm{thickness}\ensuremath{\le}100\phantom{\rule{0.3em}{0ex}}\mathrm{\AA{}})$ of ${\mathrm{La}}_{0.7}{\mathrm{Sr}}_{0.3}{\mathrm{MnO}}_{3}$ were epitaxially grown by molecular-beam epitaxy on sin…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Synergistic Flame Retardant Effect of SiO2in LLDPE/EVA/ATH Blends

Ping Wei、Zhidong Han、Xu Xiaonan 等 4 位作者2006-10-19Journal of Fire Sciences

SiO 2 has long been recognized as an inert diluent and usually used as an enhancing agent in thermoplastic polymers. Few reports are presented about its use as additive flame retardant. In this article, the flame retardant synergistic effect of SiO 2 with aluminum hydroxide (ATH) on linear low density polyethylene and…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesFlame retardant materials and properties

Nanometer-Scale Decomposition of Ultrathin Multilayered Polyelectrolyte Films

Nathaniel J. Fredin、Jingtao Zhang、David M. Lynn2006-10-19Langmuir

We report that ultrathin multilayered films fabricated from plasmid DNA and synthetic polyamines undergo nanometer-scale transformations that resemble spinodal decomposition when incubated in aqueous media. The patterns and structures generated by this transformation are similar to those observed for the spinodal dewe…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Analysis of the complex thermal behavior of poly(L‐lactic acid) film. II. Samples crystallized from the melt

Xiaoyun Ling、Joseph E. Spruiell2006-10-19Journal of Polymer Science Part B Polymer Physics

Abstract The complex thermal behavior of poly( l ‐lactic acid) films crystallized from the melt, either isothermally or nonisothermally, was studied by differential scanning calorimetry (DSC), wide angle X‐ray diffraction, and small angle X‐ray scattering. The variation of the thermal behavior with crystallization tem…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionCarbon dioxide utilization in catalysis

Injection Molding of Postconsumer Wood–Plastic Composites II: Mechanical Properties

Ryan Gosselin、Denis Rodrigue、Bernard Riedl2006-10-19Journal of Thermoplastic Composite Materials

ABSTRACT: In the first part of this study, fiber-reinforced microcellular foams were produced via injection molding to study their morphological properties as a function of mold temperature as well as wood, blowing agent, and coupling agent concentrations. Yellow birch wood fibers are added to a recycled postconsumer…

Natural Fiber Reinforced CompositesCellular and Composite StructuresPolymer Foaming and Composites

Solubiliy of Sodium Cefotaxime in Aqueous 2-Propanol Mixtures

Haitao Zhang、Jingkang Wang、Ying Chen 等 4 位作者2006-10-19Journal of Chemical & Engineering Data

Using a laser monitoring observation technique, the solubilities of sodium cefotaxime (A) in binary water (B) + 2-propanol (C) solvent mixtures were determined by the synthetic method from 278.15 K to 308.15 K and in the solvent composition ( ) range from 0.025 to 1.000. The results of these measurements were correlat…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous SolutionsPharmacological Effects of Natural Compounds

Synthesis and Characterization of Ppy-PVS, Ppy-pTS, and Ppy-DBS Composite Films

V.K. Gade、Dhammanand J. Shirale、P.D. Gaikwad 等 7 位作者2006-10-19International Journal of Polymeric Materials

Composite films of polypyrrole-poly(vinyl sulphonic acid) (Ppy-PVS), polypyrrole-p-toluene sulphonic acid (Ppy-pTS) and polypyrrole-dodecylbenzene sulphonic acid (Ppy-DBS) were synthesized on ITO coated glass, using electrochemical polymerization. The synthesized films were characterized using electrochemical techniqu…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Structural, magnetic, and transport properties of the single-layered perovskitesLa2−xSrxCoO4(x=1.0–1.4)

A. Chichev、M. Dlouhá、S. Vratislav 等 11 位作者2006-10-19Physical Review B

The layered cobaltites ${\mathrm{La}}_{2\ensuremath{-}x}{\mathrm{Sr}}_{x}\mathrm{Co}{\mathrm{O}}_{4}$ have been complexly studied over the range of mixed ${\mathrm{Co}}^{3+∕4+}$ valency and their properties discussed in comparison with cubic perovskites ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}\mathrm{Co}{\ma…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsThermal Expansion and Ionic Conductivity

Effective immobilization of subunit protein in mesoporous silica modified with ethanol

Tetsuji Itoh、Ryo Ishii、Takeo Ebina 等 8 位作者2006-10-19Biotechnology and Bioengineering

Ethoxylated FSM-type mesoporous silica (folded-sheet mesoporous material) with a pore diameter of 6.2 nm (FSM6.2) remarkably enhances rigidly of the structure in aqueous solutions. The esterified material could be used successfully as an adsorbent to accommodate subunit protein, methemoglobin (Fe(3+)). Furthermore, me…

Electrochemical sensors and biosensorsMesoporous Materials and CatalysisAnalytical Chemistry and Chromatography

Injection Molding of Postconsumer Wood–Plastic Composites I: Morphology

Ryan Gosselin、Denis Rodrigue、Bernard Riedl2006-10-19Journal of Thermoplastic Composite Materials

In this study, fiber-reinforced microcellular foams are produced via injection molding and studied as a function of mold temperature as well as wood, blowing agent, and coupling agent concentrations. Birch wood fibers are added to a post-consumer recycled HDPE/PP matrix (85: 15 ratio) in proportions ranging from 0 to…

Natural Fiber Reinforced CompositesCellular and Composite StructuresPolymer Foaming and Composites

Origin of ferromagnetism in semiconducting(In1−x−yFexCuy)2O3−σ

Zhi Yu、Jun He、Shifa Xu 等 10 位作者2006-10-19Physical Review B

We systematically measure and analyze x-ray absorption fine structure and the anomalous Hall effect of recently discovered room-temperature ferromagnetic semiconductor thin films, ${({\mathrm{In}}_{1\ensuremath{-}x\ensuremath{-}y}{\mathrm{Fe}}_{x}{\mathrm{Cu}}_{y})}_{2}{\mathrm{O}}_{3\ensuremath{-}\ensuremath{\sigma}}…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsCopper-based nanomaterials and applications

Synthesis and Structure of Ultrathin Aluminosilicate Films

Darı́o Stacchiola、Sarp Kaya、Jonas Weissenrieder 等 9 位作者2006-10-19Angewandte Chemie International Edition

Making films: Ordered aluminosilicate films are grown on a Mo(112) substrate, and their structures are determined through high-resolution experiments and density functional theory calculations. At low Al/Si ratios, aluminum atoms partially replace the silicon atoms of the silica structure. The resulting aluminosilicat…

Advanced ceramic materials synthesisSemiconductor materials and devicesMesoporous Materials and Catalysis

Dynamic–Mechanical Properties of Wood–Fiber Reinforced Polylactide: Experimental Characterization and Micromechanical Modeling

Karin M. Bogren、E. Kristofer Gamstedt、R. Cristian Neagu 等 5 位作者2006-10-19Journal of Thermoplastic Composite Materials

Wood-fiber reinforced polylactide is a biodegradable composite where both fibers and matrix are from renewable resources. When designing new materials of this kind, it is useful to measure the influence of fiber–matrix interface properties on macroscopic mechanical properties. In particular, a quantitative measure of…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites