Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
We study high-pressure polyamorphism of B2O3 glass using x-ray diffraction up to 10 GPa in the 300-700 K temperature range, in situ volumetric measurements up to 9 GPa, and first-principles simulations. Under pressure, glass undergoes two-stage transformations including a gradual increase of the first B-O (O-B) coordi…
Silver nanoparticles stabilized by a well-known antibacterial surfactant benzyldimethyl[3-(myristoylamino)propyl]ammonium chloride (Myramistin(®)) were produced for the first time by borohydride reduction of silver chloride sol in water. Stable aqueous dispersions of silver nanoparticles without evident precipitation…
Double impact: The use of both azide and di-2-pyridylketone-derived ligands has provided new Mn24 (left) and Mn26 complexes (right) with loop and dumbbell structures that are made up of two covalently linked Mn12 and Mn13 units, respectively. Both complexes are single-molecule magnets, and the Mn26 complex displays th…
Reactive honeycomb-structured porous films are obtained using amphiphilic block copolymer microwells. This one-step process leads to high functionality inside the pores suitable for the attachement of proteins. As a result, a regular streptavidin array is created by using simple breath figure methology (see figure).
We report the synthesis of silver nanoparticles with grain sizes down to electron Fermi wavelength. These nanoparticles exhibit bright luminescence and large Raman enhancement effect. The number of photons emitted from these nanoparticles exceeded that from quantum dots or dye molecules by approximately 2 or 5 orders…
The methanolothermal reaction of (S)-1,4-diallyl-2-methylpiperazine (DAMP) with an excess CuBr affords a novel homochiral 3D framework (DAMP)3(Cu4Br4)2(H2O)3 (1) in which Cu4Br4 cubane acts as a connecting node to mimic the pure inorganic role in the ferroelectricity to enhance the remnant polarization value which is…
Purpose The paper aims to introduce an efficient contact detection algorithm for smooth convex particles. Design/methodology/approach The contact points of adjacent particles are defined according to the common‐normal concept. The problem of contact detection is formulated as 2D unconstrained optimization problem that…
Novel thermo-responsive cellulose (filter paper) surfaces of N-isopropylacrylamide (NIPAAm) and pH-responsive cellulose surfaces of 4-vinylpyridine (4VP) have been achieved via surface-initiated ATRP. Dual-responsive (pH and temperature) cellulose surfaces were also obtained through the synthesis of block-copolymer br…
We studied the influence of oxygen on the electronic trap states in a pentacene thin film. This was done by carrying out gated four-terminal measurements on thin-film transistors as a function of temperature and without ever exposing the samples to ambient air. Photooxidation of pentacene is shown to lead to a peak of…
Self-assembled InAs quantum dots (QDs) grown on GaAs(001) surface by molecular beam epitaxy under continuous and growth-interruption modes exhibit two families of QDs, quasi-3D (Q3D) and 3D QDs, whose volume density evolution is quantitatively described by a rate-equation kinetic model. The volume density of small Q3D…
International audience
In the two-dimensional superfluidity, the proliferation of the vortices and the anti-vortices results in a new class of phase transition, Berezinskii-Kosterlitz-Thouless (BKT) transition. This class of the phase transitions is also anticipated in the two-dimensional magnetic systems. However, its existence in the real…
We report pressure-induced superconductivity in a single crystal of CaFe 2 As 2 . At atmospheric pressure, this material is antiferromagnetic below 170 K but under an applied pressure of 0.69 GPa becomes superconducting, with a transition temperature T c exceeding 10 K. The rate of T c suppression with applied magneti…
The development of new low-molecular-weight gelators for organic solvents is motivated by several potential applications of gels as advanced functional materials. In the present study, we developed simple dipeptide-based organogelators with a minimum gelation concentration (MGC) of 6-0.15 %, w/v in aromatic solvents.…
Pressure induced structural and electronic transitions of Se helical chains confined inside nano-channels are studied. Raman scattering and optical absorption experiments show strong evidence of band gap reduction under high pressure. Ab initio calculations reveal that under hydrostatic compression, the Se chains shou…
A 64-nuclear cubic cage with corners of a propeller-like FeIII8 cluster and anti-anti HCOO- edges displays strong antiferromagnetism resulting in a zero spin ground state.
We carry out a first-principles theoretical study of the magnetically induced polarization in orthorhombic TbMnO3, a prototypical material in which a cycloidal-spin structure generates an electric polarization via the spin-orbit interaction. We compute both the electronic and the lattice-mediated contributions to the…
We report a first principles analysis of electronic transport characteristics for (n,n) carbon nanotube bundles. When n is not a multiple of 3, inter-tube coupling causes universal conductance suppression near Fermi level regardless of the rotational arrangement of individual tubes. However, when n is a multiple of 3,…
The electronic structure of pulsed laser deposited Mo1-xFexO2 (x=0, 0.02 and 0.05) thin films has been investigated using resonant photoemission spectroscopy near Mo-4p absorption edge. In all the samples a broad Fano- like resonance peak at ~46 eV is observed in the whole area of the valence band which indicates the…
We study the visibility of Aharonov-Bohm interference in an electronic Mach-Zehnder interferometer (MZI) in the integer quantum Hall regime. The visibility is controlled by the filling factor $ν$ and is observed only between $ν\approx 2.0$ and 1.0, with an unexpected maximum near $ν=1.5$. Three energy scales extracted…