Materials Literature
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Large area micro and sub-micrometer structuring of TCO thin film layers is performed using a laser based one-step procedure. The fabricated hexagonal arranged surface patterns with 800 nm spatial period show a higher performance in both transparency and diffraction properties compared to line-like textured and non-pat…
Efficient electron emission for energy conversion requires a low work function and a stable emitter material. The work function of graphene-based carbon materials can decrease significantly by intercalation with alkali metals, thus increasing their emission current. In this work, electron emission from potassium-inter…
To investigate the extent to which dynamic heterogeneity determines the relaxation features, we studied the effect of adding a viscosity-increasing, ∼2 nm size polyhederal oligomeric silsesquioxane (POSS) molecule on dielectric relaxation. Addition of POSS increased the relaxation time of the α-process, τ(m,α), and de…
The present study has been focused on environmentally friendly sol–gel-derived electrolytes based on a di-urethane cross-linked d-PCL(530)/siloxane network [where d represents di, PCL identifies the poly(ε-caprolactone) biopolymer, and 530 is the average molecular weight in grams per mole] doped with a wide range of c…
QA-RecombineIt provides a web interface to assess the quality of protein 3D structure models and to improve the accuracy of models by merging fragments of multiple input models. QA-RecombineIt has been developed for protein modelers who are working on difficult problems, have a set of different homology models and/or…
Polyunsaturated fatty acids (PUFAs) are made in some strains of deep-sea bacteria by multidomain proteins that catalyze condensation, ketoreduction, dehydration, and enoyl-reduction. In this work, we have used the Udwary-Merski Algorithm sequence analysis tool to define the boundaries that enclose the dehydratase (DH)…
The electronic and structural properties of small monomagnesium oxide clusters, MgO(x)(-) and MgO(x) (x = 1-4), have been investigated using a synergistic approach combining photoelectron imaging spectroscopy and first principles electronic structure calculations. The adiabatic detachment energy (ADE) and vertical det…
The preparation of platelike NaNbO 3 grains via single‐step molten salt synthesis using Bi 2 O 3 , Na 2 CO 3 , Nb 2 O 5 , and NaCl as reactants was examined. When a new alumina crucible was used, platelike NaNbO 3 grains were obtained, but a repeatedly used alumina crucible resulted in irregularly shaped NaNbO 3 grain…
Two modifications of the new Zintl compound Na2ZnSn5 were synthesized by direct reactions of the elements. hP-Na2ZnSn5, which is metastable under standard conditions, is obtained by fast cooling of a melt of stoichiometric composition. Slow cooling of such a melt or tempering of hP-Na2ZnSn5 (e.g., at 300 °C) leads to…
Water capillary bridges are prepared that span hydrophilic pinning features on parallel opposing smooth, flat, and hydrophobic surfaces. These bridges are distorted by shearing the parallel plates at a low rate. The capillary bridges lengthen and distort to balance Laplace pressure (equilibrate mean curvature) as the…
Microwave-assisted synthesis has been used to obtain the family of dodecanuclear Ni(II) complexes [Ni12(NO3)(MeO)12(MeC6H4CO2)9(MeOH)10(H2O)2][ClO4]2 (1), [Ni12(NO3)(MeO)12(BrC6H4CO2)9(MeOH)10(H2O)2][ClO4]2 (2), [Ni12(CO3)(MeO)12(MeC6H4CO2)9(MeOH)10(H2O)2]2[SO4] (3) and [Ni12(NO3)(MeO)12(MeC6H4CO2)9(MeOH)8(H2O)7][NO3]…
An extended set of coupled wave equations were derived to describe non-idealized lamellar multilayer grating structures with properties as obtained with state-of-the-art fabrication techniques. These generalized equations can include all relevant effects describing the influence of passivation and contamination layers…
Exchange bias is studied in thin film systems, in which three types of Heusler alloys (Ni2MnSn, Co2MnSn, and Co2FeSi) are in contact with an antiferromagnet. Magnetic exchange interactions between the constituting atoms (i.e., Ni-Mn, Mn-Mn, Co-Mn, and Co-Fe, or Co-Co) differ substantially in these Heusler alloys. We e…
Fatigue failure is a concern when high‐strength, high‐toughness silicon nitride ceramics are used in mechanical components and the growth of natural flaws will determine the usable upper bound strength. In this study a fracture resistance curve ( R ‐curve) model is incorporated into an established method for deducing…
The protection of steel against corrosion by nano-glass flake containing coatings has been evaluated in this article. Nano-glass flake was incorporated into epoxy vinyl ester resin by mechanical agitation, homogenizer and sonication process. The dispersion morphology and agglomeration degree of nanoadditives were anal…
Abstract Mesoporous silica nanoparticles (MSN) were coated by pH‐responsive polymer chitosan‐poly (methacrylic acid) (CS‐PMAA). This nano drug delivery system showed good application prospects and the polymer‐coated microspheres were promising site‐specific anticancer drug delivery carriers in biomedical field. A cont…
We have synthesized ZnO nanoparticles capped with butanethiol, octanethiol, and dodecanethiol. In all of the cases, the capped ZnO nanoparticles exhibit ferromagnetic-like behavior up to room temperature whose intrinsic origin has been demonstrated by using both X-ray magnetic circular dichroism (XMCD) and X-ray absor…
Many researchers are now working on composites systems where the fibers and polymers are either totally or predominantly based on renewable materials. The aim of this study is to develop renewable resource-based composites based on spinifex fibers and a polyurethane matrix prepared primarily from spinifex resin. Chemi…
Counter polyelectrolytes (PEs) having a degradable polyamide backbone and controlled thiolation are prepared. Their nanosized polyelectrolyte complexes (PECs) spontaneously crosslink under ambient conditions via bioreducible disulfide bonds. These PECs are regenerable after centrifugation, and resist degradation by pr…
The EMI shielding composites consisted of carbon fabric and nonwovens were developed based on needle punching and thermal bonding techniques, and their static and dynamic puncture resistances were also evaluated to resist against different puncture behaviors. The result shows that, needle-punched density and thermal b…