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A Novel Way to Prepare Hollow Sphere Ceramics

Fei Qi、Xingxing Xu、Jie Xu 等 5 位作者2014-07-24Journal of the American Ceramic Society

Recent developments in the fabrication of hollow spheres have allowed our group to prepare a new type of macroporous ceramics: hollow sphere ceramics ( HSC s). Alumina hollow spheres were first produced by centrifugal spray‐drying of particle‐stabilized foam slurry. The obtained hollow spheres were sintered together t…

Advanced ceramic materials synthesisCellular and Composite StructuresHeat and Mass Transfer in Porous Media

Growth and development of the barnacleAmphibalanus amphitrite: time and spatially resolved structure and chemistry of the base plate

Daniel K. Burden、Christopher M. Spillmann、Richard K. Everett 等 9 位作者2014-07-24Biofouling

The radial growth and advancement of the adhesive interface to the substratum of many species of acorn barnacles occurs underwater and beneath an opaque, calcified shell. Here, the time-dependent growth processes involving various autofluorescent materials within the interface of live barnacles are imaged for the firs…

Polymer Surface Interaction StudiesCalcium Carbonate Crystallization and InhibitionMarine Biology and Environmental Chemistry

Growth, structural and mechanical analysis of a single crystal of l -prolinium tartrate: a promising material for nonlinear optical applications

Kanika Thukral、N. Vijayan、Budhendra Singh 等 10 位作者2014-07-24CrystEngComm

A single crystal of L-prolinium tartrate (LPT), which is an organic non linear optical material, was successfully synthesized and grown using a slow evaporation solution growth technique (SEST). The crystal structure and lattice parameters of the crystal were confirmed by powder X-ray diffraction and it was found that…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchNonlinear Optical Materials Studies

Phase Diagram and Enhanced Piezoelectric Response of Lead‐Free BaTiO 3 – CaTiO 3 – BaHfO 3 System

Dali Wang、Zhaohua Jiang、Bin Yang 等 7 位作者2014-07-24Journal of the American Ceramic Society

Three composition groups in the BaTiO 3 – CaTiO 3 – BaHfO 3 ternary system, (1 − x ) Ba ( Hf y Ti 1− y ) O 3 – x ( Ba 1− z Ca z ) TiO 3 (abbreviated as BH y T – x BC z T with x = 0–1.0, y = 0.16, z = 0.20; x = 0–1.0, y = 0.16, z = 0.30; x = 0–1.0, y = 0.20, z = 0.30, respectively), have been designed for investigating…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

Order parameter for structural heterogeneity in disordered solids

Hua Tong、Ning Xu2014-07-24Physical Review E

We construct a structural order parameter from the energy equipartition of normal modes of vibration to quantify the structural heterogeneity in disordered solids. The order parameter exhibits strong spatial correlations with low-temperature dynamics and local structural entropy. To characterize the role of particles…

High-pressure geophysics and materialsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Integration of Self‐Assembled Epitaxial BiFeO3–CoFe2O4 Multiferroic Nanocomposites on Silicon Substrates

Dong Hun Kim、Nicolas M. Aimon、Xue Yin Sun 等 7 位作者2014-07-24Advanced Functional Materials

Perovskite‐spinel epitaxial nanocomposite thin films are commonly grown on single crystal perovskite substrates, but integration onto a Si substrate can greatly increase their usefulness in devices. Epitaxial BiFeO 3 –CoFe 2 O 4 nanocomposites consisting of CoFe 2 O 4 pillars in a BiFeO 3 matrix are grown on (001) Si…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Graphene–Single-Walled Carbon Nanotubes–Poly(3-methylthiophene) Ternary Nanocomposite for Supercapacitor Electrode Materials

Saptarshi Dhibar、Pallab Bhattacharya、Debasis Ghosh 等 5 位作者2014-07-24Industrial & Engineering Chemistry Research

Herein, we report a cost-effective and easy synthetic procedure for the fabrication of a graphene–single-walled carbon nanotube–poly(3-methylthiophene) ternary nanocomposite for high-performance supercapacitor electrodes. The possible interactions of both graphene (Gr) and single-walled carbon nanotubes (SWCNTs) with…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Enhanced visible-light photoelectrochemical behaviour of heterojunction composite with Cu 2 O nanoparticles-decorated TiO 2 nanotube arrays

Jianfang Zhang、Yan Wang、Cuiping Yu 等 9 位作者2014-07-24New Journal of Chemistry

Heterojunction composites based on n-type TiO2 nanotubes arrays (TNAs) coupled with p-type Cu2O nanoparticles were synthesized using a square wave voltammetry deposition method for in situ deposition of Cu2O nanoparticles onto the inner surfaces and interfaces of TNAs. The prepared samples were characterized by field-…

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

Synthesis of Silica Vesicles with Controlled Entrance Size for High Loading, Sustained Release, and Cellular Delivery of Therapeutical Proteins

Jun Zhang、Surajit Karmakar、Meihua Yu 等 6 位作者2014-07-24Small

A rationally designed two-step synthesis of silica vesicles is developed with the formation of vesicular structure in the first step and fine control over the entrance size by tuning the temperature in the second step. The silica vesicles have a uniform size of ≈50 nm with excellent cellular uptake performance. When t…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesMesoporous Materials and Catalysis

Multifunctional Hybrid Nanomaterials from Water Dispersible CaF2:Eu3+, Mn2+ and Fe3O4 for Luminescence and Hyperthermia Application

Laishram Priyobarta Singh、S. K. Srivastava、Ratikant Mishra 等 4 位作者2014-07-24The Journal of Physical Chemistry C

CaF 2 nanoparticles doped with 1 at. % Eu 3+ and codoped with Mn 2+ ions (1, 2, and 3 at. %) were synthesized at 180 °C by using ethylene glycol as a capping agent and solvent medium. The emission spectra of these nanomaterials show two main peaks at 590 and 612 nm after excitation at 240 or 394 nm. Enhancement in lum…

Luminescence Properties of Advanced MaterialsAtomic and Subatomic Physics ResearchInorganic Fluorides and Related Compounds

Thermal and Mechanical Properties of Natural Rubber Composites Reinforced with Cellulose Nanocrystals from Southern Pine

Chunmei Zhang、Yi Dan、Jun Peng 等 6 位作者2014-07-24Advances in Polymer Technology

ABSTRACT There is currently a considerable interest in developing bio‐based and green nanocomposites in industrial and technological areas owing to their biodegradability, biocompatibility, and environmental friendliness. In this study, a bio‐based nanosized material, cellulose nanocrystals (CNC), extracted from south…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

Induced Magnetization inLa0.7Sr0.3MnO3/BiFeO3Superlattices

Surendra Singh、J. T. Haraldsen、J. Xiong 等 17 位作者2014-07-24Physical Review Letters

Using polarized neutron reflectometry, we observe an induced magnetization of $75\ifmmode\pm\else\textpm\fi{}25\text{ }\mathrm{kA}/\mathrm{m}$ at 10 K in a ${\mathrm{La}}_{0.7}{\mathrm{Sr}}_{0.3}{\mathrm{MnO}}_{3}$ $(\mathrm{LSMO})/{\mathrm{BiFeO}}_{3}$ superlattice extending from the interface through several atomic…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

Cross-linked Polymer Nanofibers for Hyperthermophilic Enzyme Immobilization: Approaches to Improve Enzyme Performance

Christina Tang、Carl D. Saquing、Stephen W. Morton 等 6 位作者2014-07-24ACS Applied Materials & Interfaces

We report an enzyme immobilization method effective at elevated temperatures (up to 105 °C) and sufficiently robust for hyperthermophilic enzymes. Using a model hyperthermophilic enzyme, α-galactosidase from Thermotoga maritima, immobilization within chemically cross-linked poly(vinyl alcohol) (PVA) nanofibers to prov…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Phase Diagrams and Electromechanical Strains in Lead‐Free BNT‐Based Ternary Perovskite Compounds

Wangfeng Bai、Lingyu Li、Wei Li 等 6 位作者2014-07-24Journal of the American Ceramic Society

Lead‐free compounds based on perovskite solid solutions in the ternary system ( Bi 0.5 Na 0.5 ) TiO 3 ‐ MeNbO 3 ‐ SrTiO 3 ( BNT ‐ MeNbO 3 ‐ ST , Me=K, Na,( K 0.5 Na 0.5 )) were fabricated using a conventional solid‐state reaction method. The effect of ST addition to BNT ‐ MeNbO 3 ceramics on the strain behavior, diele…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Structural, optical, and electrical properties of strained La-doped SrTiO3 films

Miri Choi、Agham Posadas、Cesar Rodriguez 等 11 位作者2014-07-24Journal of Applied Physics

The structural, optical, and room-temperature electrical properties of strained La-doped SrTiO3 epitaxial thin films are investigated. Conductive La-doped SrTiO3 thin films with concentration varying from 5 to 25% are grown by molecular beam epitaxy on four different substrates: LaAlO3, (LaAlO3)0.3(Sr2AlTaO6)0.7, SrTi…

Semiconductor materials and devicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

High Power Performance of Manganese‐Doped BNT ‐Based Pb‐Free Piezoelectric Ceramics

Mehdi Hejazi、Elaheh Taghaddos、Erkan A. Gurdal 等 5 位作者2014-07-24Journal of the American Ceramic Society

Electromechanical properties and high power characteristics of Pb ‐free hard piezoelectric ceramics in the ( BiN a 0.88 K 0.08 Li 0.04 ) 0.5 ( Ti 1− x Mn x ) O 3 ( x = 0, 0.014, 0.015, and 0.016) system were studied. Mn doping resulted in a considerable enhancement of mechanical quality factor Q m and vibration veloci…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

Ca 2+ ‐Doped LaCrO 3 : A Novel Energy‐Saving Material with High Infrared Emissivity

Zhao Han、Jun Liu、Xiaowei Li 等 6 位作者2014-07-24Journal of the American Ceramic Society

The present study describes the successful synthesis of a Ca 2+ ‐doped LaCrO 3 ceramic with high infrared ( IR ) emissivity, which is important for high‐temperature applications for significant energy saving. It is demonstrated that 20 mol% Ca 2+ ‐doped LaCrO 3 , i.e., La 0.8 Ca 0.2 CrO 3 , exhibited an IR emissivity…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Polyhydroxyalkanoate biosynthesis and simultaneous remotion of organic inhibitors from sugarcane bagasse hydrolysate by Burkholderia sp.

Mateus Schreiner Garcez Lopes、José Gregório Cabrera Gomez、Marilda Keico Taciro 等 5 位作者2014-07-24Journal of Industrial Microbiology & Biotechnology

Burkholderia sp. F24, originally isolated from soil, was capable of growth on xylose and removed organic inhibitors present in a hemicellulosic hydrolysate and simultaneously produced poly-3-hydroxybutyrate (P3HB). Using non-detoxified hydrolysate, Burkholderia sp. F24 reached a cell dry weight (CDW) of 6.8 g L(-1), c…

Biofuel production and bioconversionEnzyme Catalysis and Immobilizationbiodegradable polymer synthesis and properties

Chemical Vapor Deposition of Graphene on a “Peeled-Off” Epitaxial Cu(111) Foil: A Simple Approach to Improved Properties

Hak Ki Yu、Kannan Balasubramanian、Ki-Soo Kim 等 9 位作者2014-07-24ACS Nano

We present a simple approach to improving the quality of CVD grown graphene, exploiting a Cu(111) foil catalyst. The catalyst is epitaxially grown by evaporation on a single crystal sapphire substrate, thickened by electroplating, and peeled off. The exposed surface is atomically flat, easily reduced, and exclusively…

Graphene research and applicationsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Red, Green, Blue (RGB) Electrochromic Fibers for the New Smart Color Change Fabrics

Kerui Li、Qinghong Zhang、Hongzhi Wang 等 4 位作者2014-07-24ACS Applied Materials & Interfaces

These fibers are prepared using stainless steel wires (SSWs) as a substrate. Three kinds of electrochromic materials (poly(3,4-ethylenedioxythiophene), poly(3-methylthiophene), and poly(2,5-dimethoxyaniline)) are quickly deposited on the surface of the SSWs by electrochemical polymerization. A polymer gel electrolyte…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsTransition Metal Oxide Nanomaterials