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Diffusion Studies of Copper on Ruthenium Thin Film

Raymond Chan、Tiruchirapalli Arunagiri、Y. Zhang 等 7 位作者2004-01-01Electrochemical and Solid-State Letters

Diffusion studies were carried out on physical vapor deposited Cu/Ru(∼20 nm)/Si samples using secondary ion mass spectroscopy (SIMS) and transmission electron microscopy (TEM). Back side SIMS depth profiling revealed well-defined interfaces and showed that Cu interdiffusion was impeded by Ru thin film up to 450°C vacu…

Semiconductor materials and devicesElectrodeposition and Electroless CoatingsCopper Interconnects and Reliability

Plasticizers for Zein: Their Effect on Tensile Properties and Water Absorption of Zein Films

John W. Lawton2004-01-01Cereal Chemistry

ABSTRACT Cast zein films are brittle at room conditions, so plasticizers are added to make them more flexible. The tensile properties of these films are known to be affected by the relative humidity (RH) of the ambient air. However, little is known about how the plasticizers are affected by RH. Cast zein films were pl…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Sonochemical synthesis of aragonite-type calcium carbonate with different morphologies

Gen‐Tao Zhou、Jimmy C. Yu、Xinchen Wang 等 4 位作者2004-01-01New Journal of Chemistry

Aragonite, a high-pressure polymorph of CaCO3, was synthesized for the first time from simple Ca(HCO3)2 solutions by using high-power ultrasound irradiation. XRD, FT-IR and SEM techniques were used to characterize the phase composition and morphology of the products. The intensity of the ultrasound irradiation was fou…

Methane Hydrates and Related PhenomenaCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

Differential degradation rates in vivo and in vitro of biocompatible poly(lactic acid) and poly(glycolic acid) homo- and co-polymers for a polymeric drug-delivery microchip

Amy C. Richards Grayson、Gabriela Voskerician、Aaron D. Lynn 等 6 位作者2004-01-01Journal of Biomaterials Science Polymer Edition

The biocompatibility and biodegradation rate of component materials are critical when designing a drug-delivery device. The degradation products and rate of degradation may play important roles in determining the local cellular response to the implanted material. In this study, we investigated the biocompatibility and…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesAdvanced Drug Delivery Systems

A template-free aqueous route to ZnO nanorod arrays with high optical property

Qun Tang、Wenjia Zhou、Jianmin Shen 等 6 位作者2004-01-01Chemical Communications

A mild template-free aqueous route was successfully established to synthesize well-aligned ZnO nanorod arrays, which were proved to exhibit high optical property by PL spectra.

ZnO doping and propertiesPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Design of chiral dimesogens containing cholesteryl groups; formation of new molecular organizations and their application to molecular photonics

V. Ajay Mallia、Nobuyuki Tamaoki2004-01-01Chemical Society Reviews

Photoresponsive liquid crystals and organogels are finding increasing application in information technology and photonics. In this tutorial review, the authors describe how weak intermolecular interactions facilitate molecular organization of cholesterol-containing dimesogens to form such materials. Design considerati…

Liquid Crystal Research AdvancementsSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Surface-enhanced Raman scattering for ultrasensitive chemical analysis of 1 and 2-naphthalenethiols

Ramón A. Álvarez‐Puebla、D.S. dos Santos、Ricardo F. Aroca2004-01-01The Analyst

The results of the search for the optimal experimental conditions for ultrasentitive chemical analysis of 1-naphthalenethiol (1-NAT) and 2-naphthalenethiol (2-NAT) using surface-enhanced Raman scattering (SERS) are discussed. The report begins with a review of the vibrational spectra, including infrared and Raman spec…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy and Quantum Chemical StudiesProtein Interaction Studies and Fluorescence Analysis

Subwavelength photolithography based on surface-plasmon polariton resonance

Xiangang Luo、Teruya Ishihara2004-01-01Optics Express

The use of surface-plasmon polariton (SPP) resonance in the optical near field of a metallic mask to produce fine patterns with a resolution of subwavelength scale is proposed. Preliminary numerical simulations indicate that the critical resolution is mainly determined by the thickness of the metallic mask. The surfac…

Plasmonic and Surface Plasmon ResearchOptical Coatings and GratingsNear-Field Optical Microscopy

Strain-hardening due to Dispersed Cementite for Low Carbon Ultrafine-grained Steels

Akio Ohmori、Shiro Torizuka、Kotobu Nagai2004-01-01ISIJ International

Strain(work)-hardening in tensile tests was examined for low carbon steels with various ferrite grain sizes ranged from 0.4 to 16 μm. The steels had microstructures composed of ferrite grains and dispersed cementite particles. They were fabricated through warm caliber bar-rollings with an accumulative area reduction o…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Stability of hexagonal solidification patterns

M Plapp、M Dejmek2004-01-01Europhysics Letters (EPL)

We investigate the dynamics of cellular solidification patterns using three-dimensional phase-field simulations. The cells can organize into stable hexagonal patterns or exhibit unsteady evolutions. We identify the relevant secondary instabilities of regular hexagonal arrays and find that the stability boundaries depe…

RNA Research and SplicingSolidification and crystal growth phenomenaNonlinear Dynamics and Pattern Formation

Quantum tunneling of the magnetization in the Ising chain compound Ca 3 Co 2 O 6

A. Maignan、V. Hardy、S. Hébert 等 8 位作者2004-01-01Journal of Materials Chemistry

The magnetic behavior of the Ca3Co2O6 spin chain compound is characterized by a large Ising-like character of its ferromagnetic chains, set on a triangular lattice, that are antiferromagnetically coupled. At low temperature, T < 7 K, the 3D antiferromagnetic state evolves towards a spin frozen state. In this temperatu…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesAdvanced Condensed Matter Physics

Numerical Solution of Polymer Self-Consistent Field Theory

Héctor D. Ceniceros、Glenn H. Fredrickson2004-01-01Multiscale Modeling and Simulation

We propose efficient pseudospectral numerical schemes for solving the self-consistent, mean-field equations for inhomogeneous polymers. In particular, we introduce a robust class of semi-implicit methods that employ asymptotic small scale information about the nonlocal density operators. The relaxation schemes are fur…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Manufacture of elastic biodegradable PLCL scaffolds for mechano-active vascular tissue engineering

Sung In Jeong、Soo Hyun Kim、Young Ha Kim 等 7 位作者2004-01-01Journal of Biomaterials Science Polymer Edition

A soft and very elastic poly(lactide-co-epsilon-caprolactone) (PLCL)(50:50, Mn 185 x 10(3)) was synthesized. Tubular scaffolds were prepared by an extrusion-particulate leaching method for mechano-active vascular tissue engineering. The copolymer was very flexible but completely rubber-like elastic. Even the high poro…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

On the role of interface polymers for the mechanics of natural polymeric composites

Peter Fratzl、Ingo Burgert、Himadri S. Gupta2004-01-01Physical Chemistry Chemical Physics

Research on the deformation mechanisms of tendons and wood has shown that these tissues deform mostly by shearing of a soft matrix between stiff fibres. For this type of composite to be both strong and tough, tight binding between matrix and fibres is required. Recent results suggest that Nature may have evolved speci…

Adhesion, Friction, and Surface InteractionsSilk-based biomaterials and applicationsCollagen: Extraction and Characterization

How to determine structures when single crystals cannot be grown: opportunities for structure determination of molecular materials using powder diffraction data

Kenneth D. M. Harris、Eugene Cheung2004-01-01Chemical Society Reviews

Many crystalline solids cannot be prepared as single crystals of sufficient size and/or quality for structure determination to be carried out using single crystal X-ray diffraction techniques. In such cases, when only polycrystalline powders of a material are available, it is necessary instead to tackle structure dete…

Crystallography and molecular interactionsChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

BACTERIAL DEGRADATION OF BLACK AND WHITE FEATHERS

Gérald Goldstein、Kelly R. Flory、Beth Ann Browne 等 6 位作者2004-01-01The Auk

Abstract When feather-degrading Bacillus licheniformis is grown in culture, it secretes a keratinase that hydrolyzes the β-keratin matrix of a feather, thereby releasing oligopeptides that dissolve into the medium surrounding the feather and feather-degrading bacilli. These peptides absorb light passed through a sampl…

Glycosylation and Glycoproteins ResearchEnzyme Production and CharacterizationSilk-based biomaterials and applications

Correlation between hydroxyl fraction and O/Al atomic ratio as determined from XPS spectra of aluminium oxide layers

J. F. J. van den Brand、W.G. Sloof、Herman Terryn 等 4 位作者2004-01-01Surface and Interface Analysis

Abstract A set of five different aluminium oxide layers has been investigated using XPS. The oxide layers were made by oxidizing aluminium in a vacuum, with an alkaline and acidic pretreatment and in boiling water. Hydroxyl fractions of the aluminium oxide layers ranging from 0.0 to 0.5 were determined by constrained…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides

Using light to control physical properties of polymers and surfaces with azobenzene chromophores

R. H. El Halabieh、Ozzy Mermut、Christopher J. Barrett2004-01-01Pure and Applied Chemistry

Abstract Azobenzene chromophores can be switched between two geometric isomers using visible light. This photoisomerization is rapid, reversible, and of high quantum yield, and the wavelengths effecting the transformation can be tuned synthetically with substituent groups to the chromphores. Upon isomerization, there…

Interactive and Immersive DisplaysPhotochromic and Fluorescence ChemistryElectrowetting and Microfluidic Technologies

Stable π-dimer of a tetrathiafulvalene cation radical encapsulated in the cavity of cucurbit[8]uril

Albina Y. Ziganshinа、Young Ho Ko、Woo Sung Jeon 等 4 位作者2004-01-01Chemical Communications

The first stable pi-dimer of a tetrathiafulvalene (TTF) cation radical encapsulated in the cavity of cucurbit[8]uril has been isolated at room temperature and fully characterized; it shows absorption bands at 400, 540 and 760 nm, characteristic of the TTF cation radical dimer.

Supramolecular Chemistry and ComplexesMagnetism in coordination complexesOrganic and Molecular Conductors Research