Materials Literature
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Abstract Trialkyl cis-1,3,5-cyclohexanetricarboxamides were able to cause physical gelation in organic liquids to afford completely transparent organogel. The main driving force for gelation was intermolecular hydrogen bonding between amides and van der Waals interaction among hydrophobic alkyl chains.
1 H-NMR spectral properties of two paramagnetic binuclear copper(II) complexes 1 and 2, which are weakly antiferro- and ferromagnetically coupled, respectively, in the solid state, have been studied in solution; corresponding parameters are compared to a mononuclear copper(II) analogue 1a . Compound 1 exhibits unusual…
We report a convenient and general synthesis of β-octafluoroporphyrins bearing meso -tetraaryl substituents, including the first synthesis and full characterization of a perfluorinated tetraarylporphyrin, perfluoro-5,10,15,20-tetraphenylporphyrin, 2 . The structural, spectroscopic, and electrochemical data indicate th…
Abstract Molybdenum(VI) solutions were investigated in detail by Raman spectroscopy with a view to establishing the speciation of the predominant polynuclear species (isopolymolybdates) formed in aqueous solution. The most intense Raman frequencies due to asymmetric stretching vibration of Mo=O were very sensitive to…
A structural feature shared by many protein kinases is the requirement for phosphorylation of threonine or tyrosine in the so-called activation loop for full enzyme activity. Previous studies by several groups have indicated that the isotypes alpha, betaI, and betaII of protein kinase C (PKC) are synthesized as inacti…
Newly surveyed sets of energy loss cross sections are presented for N2, O2, and O. The work was motivated by a number of new electron energy loss measurements in the late 1980s and early 1990s and recent selected review articles. Each set includes a total ionization cross section and excitation cross sections that cor…
Abstract Four heterogeneous nucleating agents were added to polypropylene (PP) homoblock and random copolymers. Melting and crystallization of the polymers were studied by differential scanning calorimetry (DSC), and characteristics derived from the crystallization exotherms were related to the mechanical properties o…
Scatterometry, the analysis of light diffraction from periodic structures, is shown to be a versatile metrology technique applicable to a number of processes involved in the production of microelectronic devices. We have demonstrated that the scatterometer measurement technique is robust to changes in the thickness of…
Poly(ε-caprolactone) (PCL) with a wide range of molecular weight (MW) has been prepared via fractionation by either precipitating PCL/chloroform solutions into different amounts of methanol or adding methanol into PCL/tetrahydrofuran (THF) solutions. The samples with M n ranging from 1900 to 64 700 were used to invest…
This paper presents the evaluation of enhancement in the mechanical properties of short sisal fiber reinforced polyethylene composites by the incorporation of short glass fiber as an intimate mix with sisal. Intimately mixed short glass-sisal hybrid fiber reinforced polyethylene composites (GSRP) were prepared by solu…
The development of second-generation photosensitizers to improve photodynamic therapy (PDT) is an area of extensive research. Three such compounds that have been synthesized in our group are polysubstituted Zn(II) phthalocyanines that differ in their overall net charge (one cationic, one anionic and one neutral). The…
An investigation of the primary Bjerknes force acting on a bubble in a strong acoustic field is presented. The approach takes into account the nonlinear resonancelike response of small bubbles to strong acoustic pressure amplitudes. It is shown that for high pressure amplitudes even very small bubbles are repelled fro…
The monoclinic‐to‐tetragonal phase transformation in LaNbO 4 has been investigated by X‐ray diffraction and dilatometry. Based on the experimental results and theoretical concerns (Landau theory and thermodynamics), it is suggested that this transformation is second order in nature.
This article tries to provide some direct evidence about the relationship between the intramolecular hydrogen bonds in cellulose and their corresponding effect on physical properties. The formation of intramolecular hydrogen bonds has been proved to contribute directly to certain physical properties of cellulose, such…
Simple expressions are given for the Newtonian viscosity ${\mathrm{\ensuremath{\eta}}}_{\mathrm{N}}$(\ensuremath{\varphi}) as well as the viscoelastic behavior of the viscosity \ensuremath{\eta}(\ensuremath{\varphi},\ensuremath{\omega}) of neutral monodisperse hard-sphere colloidal suspensions as a function of volume…
The synthesis of amphiphilic AB block copolymers, having 1,4-polydiene or corresponding hydrogenated aliphatic polyolefin blocks and poly(ethylene oxide) (PEO) blocks, is described. The materials are obtained in a two-step process. In the first step isoprene is polymerized anionically in a hydrocarbon solvent with sec…
A photoisomerizable nitrospiropyran monolayer assembled on a Au electrode provides a functionalized interface for the photochemical, pH, and thermal control of electrochemical processes of charged electroactive redox probes. (Mercaptobutyl)nitrospiropyran 1 was assembled as a monolayer on a Au electrode. The monolayer…
This review focuses on the use of heterogeneous catalysts in the production of fine and speciality chemicals. The major emphasis is on those systems which have been commercialised already and those which are close to commercialisation. These include the use of TS-1 for oxidation reactions including the production of h…
Several edible films based on methylcellulose and polyethylene glycol 400 (PEG400) were prepared and stored until equilibration at different relative humidities. Tensile stress−strain curves show very different behaviors as a function of PEG400 and relative humidity. Tensile strength strongly depends on relative humid…
The present analysis provides Tb(0.27−0.30)Dy(0.73−0.70)Fe(1.9−2.0) magnetization and magnetostriction states during applied magnetic field and stress processes by minimizing the total magnetic free energy in the presence of a parameter selected inverse exponential magnetic free energy distribution. A comparison betwe…