Materials Literature
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The X-ray emission spectra (Mg-Kβ1,3, Mg-L2,3 M, and O-Kα), X-ray photoelectron spectra, and O-KLL Auger spectra from brucite, Mg[OH]2, are reported. The electronic structure of brucite is discussed using these spectra and a simple Hückel molecular-orbital model. The spectra indicate that the strongest interaction exi…
The kinetic mechanism of CVD deposition has been studied for ( i ) reaction at 675°–940°C for and , ( ii ) reaction at 400°–807°C for and , and ( iii ) reaction at 425°–578°C for and . In combination with the available literature data, the results of the present investigation have been interpreted to show atomic oxyge…
The surface tension γ has been measured for two cyanobiphenyls (5CB and 8CB) at temperatures near the nematic-isotropic transition temperature T c, using the Wilhelmy plate method. Reproducible results were obtained, but only by the exercise of considerable patience: for reasons that are discussed at the end of the pa…
Abstract The relative crystallinity of various moist potato starches were measured by X‐ray diffractometer. The diffraction patterns showed to become sharp with increasing of the amount of sorption moisture. Both areas of crystallinity portion were proportionally correlated with the amount of moisture. On the assumpti…
Earlier neutron-diffraction measurements [Willis (1964), Proc. Br. Ceram. Soc. 1, 9-19] on a single crystal of UO2.12 at 800°C showed that interstitial oxygen atoms enter the UO2 lattice at two kinds of site, which are displaced by about 1 Å along the (110) and (111) directions from the cubic-coordinated interstitial…
An explicit model of contact-charge exchange in polymers is proposed in which the steady-state exchanged charge resides in intrinsic molecular-ion states. The eigenvalue spectra of these states are inferred from metal/polymer contact-charge measurements using a theoretical formalism constructed for this purpose. This…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCryophotoclustering techniques for synthesizing very small, naked silver clusters Agn of known size (where n = 2-5). The molecular metal cluster-bulk metal particle interfaceGeoffrey A. Ozin and Helmut HuberCite this: Inorg. Chem. 1978, 17, 1, 155–163Publication Date (Print)…
From an analysis of the ac deconstriction of the hysteresis loop and microscopical observation of moving domain walls, it is concluded, that the ferroelectric domain stabilization in Mn-doped BaTiO3 crystals is due to bulk effects. Esr measurements have revealed that in reduced crystals Mn2+-V0 associates exist, havin…
The electric permittivities, refractive indices and densities of the homologous series of alkyl-cyano-biphenyls (CnH2n+1.φ.φ.CN) have been measured as a function of temperature in the nematic phases for n = 5 to 9, and in the smectic phases for n = 8 and 9. The results have been analysed in terms of the Maier and Meie…
Abstract Absorbed moisture was found to plasticize the type of cross‐linked epoxy resin system investigated, causing a lowering of the Ta and in turn affecting mechanical response, such as by shifting the relaxation moduli to shorter times. The phenomenon is described and quantified in terms of an existing free volume…
Recently compiled data for the first electron affinity and the first ionization potential are used to obtain values for an atomic electronegativity scale, based on the Mulliken relation. From this scale and a new compilation of work function data, a linear equation is obtained which includes a parameter for any given…
Extensive experiments were conducted on annealed copper under cyclic nonproportional strain histories. After cyclically stabilizing the material by uniaxial cycling, out-of-phase axial-shear strain cycling for the same effective strain range caused additional increases in stress amplitudes to restabilized levels. Foll…
We report the relative HH Raman spectra obtained from high-purity bulk samples of the primary glass formers SiO2, GeO2, B2O3, and P2O5. With 514.5-nm excitation, the peak Raman cross sections of these glasses have relative strengths of 1, 9.2, 4.7, and 5.7, respectively. The superior scattering strength of the latter…
Provides a systematic scientific basis for understanding and controlling the processing of powders and ceramic bodies. Applies a wide range of analytical tools for characterizing agglomerate features throughout the processing steps. Contains electron and optical micrographs and discusses the improvement of product rel…
The phase diagram for the system ZrO 2 ‐Y 2 O 3 was redetermined. The extent of the fluorite‐type ZrO 2 ‐Y z O 3 solid solution field was determined with a high‐temperature X‐ray furnace, precise lattice parameter measurements, and a hydrothermal technique. Long range ordering occurred at 40 mol% Y 2 O 3 and the corre…
Low temperature transmission electron microscopy can be used to study the structure of biological materials in the hydrated state. Spatial averaging techniques are necessary to overcome the radiation damage problems, and for this reason the techniques described are most applicable to crystalline objects. However, with…
An experimental model of a hard-disc system (the two-dimensional analogue of a hard-sphere system) is described. The melting transition is studied qualitatively by a photographic technique. The half-width of the singlet distribution function is measured and compared with results obtained by the method of molecular dyn…
Die von Hrn. Kurlbaum in der heutigen Sitzung mitgeteilten interessanten Resultate der von ihm in Gemeinschaft mit Hrn. Rubens auf dem Gebiete der längsten Spektralwellen ausgeführten Energiemessungen haben die zuerst von den Herren Lummer und Pringsheim auf Grund ihrer Beobachtungen aufgestellte Behauptung nachdrückl…
A theoretical description of the inelastic interactions of electrons with solid polystyrene is presented. The response of the valence electrons to energy and momentum transfers is determined by a model insulator theory; carbon K-shell ionization cross sections are derived from atomic, generalized oscillator strengths.…
Abstract The thermal degradation of ammonium polyphosphate (APP), a commercial fire retardant, and its blends with poly(methyl methacrylate) (PMMA) have been studied by thermal volatilization analysis (TVA) and the degradation products identified. APP degrades under vacuum in three stages. Initially it condenses to an…