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Electronic structure of oxo-bridge iron(III) dimers

Harvey J. Schugar、George R. Rossman、C. G. Barraclough 等 4 位作者1972-04-01Journal of the American Chemical Society

Magnetic susceptibility results and extensive electronic, infrared, and Mi:issbauer spectral data are presented for enH_2[(FeHEDT A)_2O]· 6H_2O_3, Na_4[(FeEDTA)_2O]· 12H_2O, FeHEDTA· H_2O, and NaFeEDT A· 3H_2O (HEDTA = N-hydroxoethylethylenediaminetriacetate, EDTA = ethylenediaminetetraacetate, and enH_2^(2+) =
\n…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesMetal complexes synthesis and properties

Partitioning of Chloride Between a Silicate Melt and Coexisting Aqueous Phase from 2 to 8 Kilobars

I. A. Kilinc、Charles W. Burnham1972-04-01Economic Geology

Chloride bearing solutions were equilibrated with partially melted silicate rocks under two to eight kilobars fluid pressure, near the 700 degrees and 750 degrees C isotherms. Glasses, ranging in composition from granite to granodiorite and trondhjemite, were separated from the charges and were analyzed colorimetrical…

Groundwater and Isotope GeochemistryClay minerals and soil interactionsGeochemistry and Geologic Mapping

Experimental Investigation of Photoemission from Satellite Surface Materials

B. Feuerbacher、B. Fitton1972-04-01Journal of Applied Physics

Photoemission properties were measured for the materials gold, aluminium, stainless steel, vitreous carbon, Aquadag, graphite, silica, and semiconducting indium oxide. The surfaces were treated so as to simulate the conditions actually encountered in space missions. Results are presented on the reflectance, photoyield…

Plasma Diagnostics and ApplicationsElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

The interaction of injected helium with lattice defects in a tungsten crystal

E. V. Kornelsen1972-04-01Radiation Effects

Helium injected into tungsten has been found to undergo rapid interstitial diffusion at room temperature unless it encounters lattice defects. This effect has been used in a study of the lattice damage produced near a (100) tungsten surface by the impact of small numbers of 5 keV heavy ions. The helium, injected as 25…

Fusion materials and technologiesIon-surface interactions and analysisNuclear Materials and Properties

Precision neutron diffraction structure determination of protein and nucleic acid components. I. Crystal and molecular structure of the amino acid L-alanine

M. S. Lehmann、T. F. Koetzle、Walter C. Hamilton1972-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPrecision neutron diffraction structure determination of protein and nucleic acid components. I. Crystal and molecular structure of the amino acid L-alanineM. S. Lehmann, T. F. Koetzle, and W. C. HamiltonCite this: J. Am. Chem. Soc. 1972, 94, 8, 2657–2660Publication Date (Pr…

Enzyme Structure and FunctionX-ray Diffraction in CrystallographyCrystallography and molecular interactions

The Vibrational Properties of Disordered Systems: Numerical Studies

P. Dean1972-04-01Reviews of Modern Physics

A review is presented of the direct numerical approach to the study of the atomic vibrational properties of disordered systems. The basis and details of the numerical methods employed are first described. This is followed by a review of applications of the approach to two-component disordered lattices, glasses, mixed-…

Material Dynamics and PropertiesGlass properties and applicationsTheoretical and Computational Physics

International Institute of Welding

R. B. McCauley1972-04-01Indian Welding Journal

The annual meetings of Commission XIV were held on the occasion of the Annual Assembly of the International Institute of Welding in Lausanne from 16 to 19 July 1970. They were attended by 43 delegates, experts, observers and temporary experts from 20 different countries. Two countries tied for top honours in represent…

Titanium Alloys Microstructure and Properties

Substitutional solution hardening of magnesium single crystals

A. Akhtar、E. Teghtsoonian1972-04-01Philosophical magazine

Single crystals of magnesium containing varying amounts of In, Al, Pb and Bi in solid solution have been deformed in tension over a range of temperature between 4.2°k and 500°k. The critical resolved shear stress (CRSS) for basal slip has been examined in the light of the existing solution hardening theories. The earl…

Aluminum Alloy Microstructure PropertiesMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Thermally stable polyimides from solutions of monomeric reactants

T. T. Serafini、Peter Delvigs、George R. Lightsey1972-04-01OpenAlex

Abstract A method to prepare thermally stable resin fiber‐reinforced composites using solutions of appropriate monomers is described. Solutions containing a dimethyl ester of an aryl tetracarboxylic acid, the monomethyl ester of 5‐norbornene‐2,3‐dicarboxylic acid and an aryl diamine were used to impregnate graphite fi…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersFiber-reinforced polymer composites

Structural Aspects of the Metal-Insulator Transitions in Cr-Doped VO2

M. Marezio、D. B. McWhan、J. P. Remeika 等 4 位作者1972-04-01OpenAlex

The temperature-composition phase diagram of ${\mathrm{V}}_{1\ensuremath{-}x}{\mathrm{Cr}}_{x}{\mathrm{O}}_{2}$ with $0\ensuremath{\le}x\ensuremath{\le}0.025$ is found to contain four phases: rutile ($R$), normal monoclinic V${\mathrm{O}}_{2}$ (${M}_{1}$), and two monoclinic phases (${M}_{2}$ and ${M}_{3}$). For ${M}_…

Advanced Condensed Matter PhysicsTransition Metal Oxide NanomaterialsCatalysis and Oxidation Reactions

Static and Dynamic Pore-Collapse Relations for Ductile Porous Materials

M. M. Carroll、A. C. Holt1972-04-01OpenAlex

Static and dynamic pore-collapse relations for ductile porous materials are obtained by analysis of the collapse of a hollow sphere of incompressible elastic-plastic material, with appropriate pore radius and over-all porosity. There are three phases of the pore-collapse process: an initial phase, a transitional elast…

High-Velocity Impact and Material BehaviorFluid Dynamics Simulations and InteractionsElasticity and Material Modeling

Selective Sorption and Fixation of Cations by Clay Minerals: A Review

B. L. Sawhney1972-04-01OpenAlex

Abstract Investigations concerning selective sorption and fixation of K and similar cations by clay minerals and soil clays and the mechanisms of these reactions are reviewed. In particular, recent observations on selective sorption of these ions in dilute solutions by weathered micas and vermiculite in relation to th…

Clay minerals and soil interactionsSoil and Unsaturated FlowChemical Synthesis and Characterization

Thermal Conductivity of the Elements

Ching-Yen Ho、R.W. Powell、P. E. Liley1972-04-01OpenAlex

This is the abridged version of a comprehensive volume on the thermal conductivity of the elements. It contains recommended reference values resulting from critical evaluation, analysis, and synthesis of all the available data. It also gives estimated values for those elements for which no thermal conductivity data ar…

Thermodynamic and Structural Properties of Metals and AlloysGraphite, nuclear technology, radiation studies

Theory of the Interface between Immiscible Polymers. II

Eugene Helfand、Yukiko Tagami1972-04-01OpenAlex

A theory is developed to predict the interfacial properties between two immiscible polymers. A self-consistent-field approach is employed to describe the configurational statistics of polymer molecules in the interfacial region. The density profiles and surface tension are calculated, and compare well with experiments…

Material Dynamics and PropertiesBlock Copolymer Self-AssemblyRheology and Fluid Dynamics Studies

Optics in Stratified and Anisotropic Media: 4×4-Matrix Formulation

Dwight W. Berreman1972-04-01OpenAlex

A 4×4-matrix technique was recently introduced by Teitler and Henvis for finding propagation and reflection by stratified anisotropic media. It is more general than the 2×2-matrix technique developed by Jones and by Abelès and is applicable to problems involving media of low optical symmetry. A little later, we develo…

Photonic and Optical DevicesMolecular spectroscopy and chiralityLiquid Crystal Research Advancements

Sound Velocity in a Nematic Liquid Crystal

Michael Mullen、B. Lüthi、M. J. Stephen1972-03-27Physical Review Letters

We have made sound-velocity measurements in the liquid crystal $p$-methoxy-benzylidine, $p\ensuremath{-}n$-butyl-aniline. Near the nematic-isotropic phase transition we observe a dispersion in the sound velocity. Quantitative measurements are presented on the sound-velocity anisotropy in an oriented liquid crystal.

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationMolecular spectroscopy and chirality

Small-Polaron Hopping Motion in Some Chalcogenide Glasses

David Emin、C. H. Seager、Rod K. Quinn1972-03-27Physical Review Letters

Unlike prior attempts to describe the motion of electronic charge carriers in disordered materials, we suggest that the (holelike) charge carriers may actually be selftrapped, i.e., small polarons. In support of our hypothesis, we discuss our measurements of the electrical conductivity, thermoelectric power, and Hall…

Theoretical and Computational PhysicsPhase-change materials and chalcogenidesGlass properties and applications

Electrohydrodynamic Effects in Cholesteric Liquid Crystals under ac Electric Fields

F. Rondelez、H. Arnould、C.J. Gerritsma1972-03-20Physical Review Letters

When an electric field is applied perpendicularly to a cholesteric planar texture, periodic perturbations arise. The frequency dependence of the threshold of this instability is reported for nematic-cholesteric mixtures with both positive and negative dielectric anisotropy. In the latter case a "conduction" and a "die…

Plant Reproductive BiologyNonlinear Dynamics and Pattern FormationLiquid Crystal Research Advancements

Application of the Weiss molecular field theory to the B-site spinel

W. E. Holland、H. A. Brown1972-03-16physica status solidi (a)

A molecular field treatment of the B-site spinel was used to determine the ordering temperatures and the asymptotic Curie temperature in terms of the exchange integrals. The theory was developed from a 16-sublattice model and took into account interactions between an atom and its nearest to fourth-nearest neighbors. E…

Magnetic Properties and Synthesis of FerritesCrystal Structures and PropertiesPhase-change materials and chalcogenides

Effect of Direct Current on Precipitation in Quenched Al + 4% Cu Thin Films

M. C. Shine、S. R. Herd1972-03-15Applied Physics Letters

Resistance changes associated with precipitation in Al–Cu thin films were monitored during power annealing at current densities up to 4×106 A/cm2 and temperatures of ∼178 and 200 °C. The rate of change of resistance decreased as the current increased. It is argued that this decrease is due to the current inhibiting th…

Aluminum Alloy Microstructure PropertiesCopper Interconnects and ReliabilityAnodic Oxide Films and Nanostructures