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Unusual chelating properties of the ligand 1,8-bis(3,5-dimethyl-1-pyrazolyl)-3,6-dithiaoctane (bddo). Crystal structures of Ni(bddo)(NCS) 2 , Zn(bddo)(NCS) 2 and Cd 2 (bddo)(NCS) 4

Willem G. Haanstra、W.L. Driessen、J. Reedijk 等 5 位作者1989-01-01Journal of the Chemical Society Dalton Transactions

The synthesis and characterization of the ligand 1,8-bis(3,5-dimethyl-1-pyrazolyl)-3,6-dithiaoctane (bddo) and its co-ordination compounds with zinc, cobalt, nickel, and cadmium thiocyanate are described. The general formula is M(bddo)(NCS)2 with M = Ni, Co, or Zn. With cadmium, Cd2(bddo)(NCS)4 was found. X-Ray struct…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Plasma gas discharge deposited fluorocarbon polymers exhibit reduced elutability of adsorbed albumin and fibrinogen

Janice L. Bohnert、Bradford C. Fowler、Thomas A. Horbett 等 4 位作者1989-01-01Journal of Biomaterials Science Polymer Edition

The adsorption and subsequent detergent elutability of fibrinogen and albumin were measured on various treated and untreated polymer films in order to determine whether the relative adsorption of these proteins was responsible for the enhanced thromboresistance of Dacron vascular grafts treated with tetrafluoroethylen…

Surface Modification and SuperhydrophobicityPolymer Nanocomposite Synthesis and IrradiationElectrohydrodynamics and Fluid Dynamics

Thermodynamic and vibrational characterization of CO adsorption on variously pretreated anatase

Vera Bolis、Bice Fubini、Edoardo Garrone 等 4 位作者1989-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

Joint i.r. and microcalorimetric work has shown that two types of CO adsorb on pure anatase: one (species A) absorbing at 2184–2188 cm–1, has an adsorption heat of ca. 52 kJ mol–1, the other (species B), absorbing at 2203–2208 cm–1, has an adsorption heat of 69 kJ mol–1. When sulphates are present at the surface, left…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

Determination of experimental and theoretical kASi factors for a 200‐kV analytical electron microscope

Patrick J. Sheridan1989-01-01Journal of Electron Microscopy Technique

The relative sensitivity of an analytical electron microscope and energy-dispersive x-ray detector to x-rays of various elements is investigated through an extensive kASi factor study. Elemental standards, primarily National Bureau of Standards multielement research glasses, were dry-ground into submicrometer-sized pa…

X-ray Spectroscopy and Fluorescence AnalysisNuclear Physics and ApplicationsElectron and X-Ray Spectroscopy Techniques

Magnetic properties of aerosol synthesized barium ferrite particles

Zhuang Tang、S. Nafis、C. M. Sorensen 等 5 位作者1989-01-01IEEE Transactions on Magnetics

Barium ferrite fine particles have been synthesized from ferric nitrate and barium nitrate aqueous solution by an aerosol technique. The as-received particles showed a spin-glass behavior with a history-dependent low-field magnetization below 180 K. An exothermic peak with an initial crystallization temperature of 687…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesMagneto-Optical Properties and Applications

Synthesis of tetranuclear and pentanuclear vanadium-oxide-carboxylate aggregates

Dwight D. Heinrich、Kirsten Folting、William E. Streib 等 5 位作者1989-01-01Journal of the Chemical Society Chemical Communications

Treatment of VOCl42– with tca–(tca–= thiophene-2-carboxylate) under aerobic conditions leads to formation of [V5O9Cl(tca)4]2–, whereas if AgNO3 is also present, the product is [V4O8(NO3)(tca)4]2–; the two anions have been isolated as NR4+ salts and their unusual structures elucidated by crystallographic methods.

Polyoxometalates: Synthesis and ApplicationsInorganic and Organometallic ChemistryVanadium and Halogenation Chemistry

Effect of heat treatments on thermally formed martensite phases in monocrystalline Cu-Al-Ni shape memory alloy.

Hidekazu Sakamoto、Ken‐ichi Shimizu1989-01-01ISIJ International

The effect of heat treatments on martensitic transformations in monocrystalline Cu–14.1Al–4.2Ni (mass%) (alloy 1) and Cu–14.7Al–4.2Ni (mass%) (alloy 2) shape memory alloys has been investigated by means of differential scanning calorimetry measurements, optical microscopy and tensile tests of martensitic specimens. As…

Microstructure and Mechanical Properties of SteelsShape Memory Alloy TransformationsSolidification and crystal growth phenomena

The oxidation of ketones with a heteropolyacid, H 5 [PMo 10 V 2 O 40 ] and dioxygen

Bassam El Ali、Jean‐Marie Brégeault、Jacqueline Mercier 等 6 位作者1989-01-01Journal of the Chemical Society Chemical Communications

Substituted cycloalkanones, 1-phenylalkanones, and open-chain ketones are oxidatively cleaved by the title compound under very mild conditions.

Polyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysisChemical Synthesis and Reactions

Low‐Temperature Sintering of Seeded Sol—Gel‐Derived, ZrO 2 ‐Toughened Al 2 O 3 Composites

Gary L. Messing、Masato Kumagai1989-01-01Journal of the American Ceramic Society

Seeding a mixture of boehmite (AIOOH) and colloidal ZrO 2 with α‐alumina particles and sintering at 1400°C for 100 min results in 98% density. The low sintering temperature, relative to conventional powder processing, is a result of the small alumina particle size (∼0.3 μm) obtained during the θ‐to α‐alumina transform…

Bone Tissue Engineering MaterialsFerroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesis

Does one-electron transfer to nickel(II) porphyrins involve the metal or the porphyrin ligand?

Doris Lexa、Michel Momenteau、Joël Mispelter 等 4 位作者1989-01-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDoes one-electron transfer to nickel(II) porphyrins involve the metal or the porphyrin ligand?Doris Lexa, Michel Momenteau, Joel Mispelter, and Jean Michel SaveantCite this: Inorg. Chem. 1989, 28, 1, 30–35Publication Date (Print):January 1, 1989Publication History Published…

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

The structure of 18-molybdodisulphate( VI )(4–) ion in (NEt 4 ) 4 S 2 Mo 18 O 62 ·CH 3 CN

Toshitaka Hori、Osamu Tamada、Sadayuki Himeno1989-01-01Journal of the Chemical Society Dalton Transactions

The structure of (NEt4)4S2Mo18,O62·CH3CN has been determined by the single-crystal X-ray method. The crystals are triclinic, space group P, with cell parameters a= 15.062(4), b= 23.296(4), c= 13.813(4)Å, and α= 97.66(4), β= 115.98(2), γ= 84.63(4)°, and Z= 2. The structure model was refined by full-matrix least squares…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsOrganometallic Compounds Synthesis and Characterization

Acid–base and oxidation catalysis on heteropolysalts with surface acid layers

Katarzyna Bruckman、J. Haber、Ewa M. Serwicka1989-01-01Faraday Discussions of the Chemical Society

Physicochemical and catalytic properties of heteropolyacids of the series H3 +nPVnMo12–nO40(n= 0–3), both pure and supported on the potassium salt K3PMo12O40, have been investigated. Thin acid coats formed on such a support display modified properties and enhanced thermal stability. In particular, it is postulated tha…

Polyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation ReactionsPigment Synthesis and Properties

Free Radicals in Cellulose Fibers Treated with Low Temperature Plasma

Tomiji Wakida、Keiji Takeda、Itsuo TANAKA 等 4 位作者1989-01-01Textile Research Journal

Cellulose fibers such as cotton, linen, viscose rayon, and polynosic fibers were treated with low temperature plasmas of O 2 , N2, H2, Ar, CO, CH4, and CF 4 . For comparison wool, silk, nylon 6, and poly ( ethylene terephthalate ) (PET) were also subjected to the plasma treatments. The relative free-radical intensity…

Advanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical ApplicationsDyeing and Modifying Textile Fibers

Photochemical deposition of electrically conducting polypyrrole

Jean‐Marc Kern、Jean‐Pierre Sauvage1989-01-01Journal of the Chemical Society Chemical Communications

Conducting polypyrrole can be photochemically deposited onto any type of surface by visible light irradiation of the surface covered with a multicomponent solution (pyrrole, electron acceptor, photoactive species).

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

MFIT: Multiple spectra fitting program

A. P. Hammersley、Christian Riekel1989-01-01Synchrotron Radiation News

(1989). MFIT: Multiple spectra fitting program. Synchrotron Radiation News: Vol. 2, No. 1, pp. 24-26.

Advanced X-ray Imaging TechniquesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Shear-flow instabilities in non-flow-aligning nematic liquid crystals

Ignacio Zúñiga、F. M. Leslie1989-01-01Liquid Crystals

This paper investigates theoretically the stability of non-flow-aligning nematics in simple shear flow by analyzing the relevant continuum equations. With the aid of numerical techniques, it proves possible to predict thresholds for instability to perturbations both within and out of the shear plane, based on the full…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationAdvanced Materials and Mechanics

Blends of poly(tetramethylene terephthalate) with a liquid‐crystalline polyester, poly(decamethylene 4,4′‐terephthaloyldioxydibenzoate), 2. Crystallization kinetics and melting behaviour

Mariano Pracellà、Emo Chiellini、D. Dainelli1989-01-01Die Makromolekulare Chemie

Abstract The isothermal crystallization kinetics, the morphology and melting behaviour of blends of poly(tetramethylene terephthalate) {poly(butylene terephthalate), (PBT)} with a thermotropic liquid‐crystalline polyester, poly(decamethylene 4,4′‐terephthaloyldioxydibenzoate) (HTH10), were studied in the composition r…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Lichtsensitive Dihydroazulene: Alternativer Syntheseweg – Einfluß von Alkylsubstituenten im Fünfring auf das photochrome Verhalten

Sebastian Gierisch、Jörg Daub1989-01-01Chemische Berichte

Abstract Die Dihydroazulene 1a – d werden ausgehend von Cycloheptatrienylium‐tetrafluoroborat ( 8 ) hergestellt. Zwischenverbindungen sind substituierte Cycloheptatriene 10 – 13 . Die Dicyanvinylderivate 12 bzw. 13 werden durch Dehydrogenierung in die Vinylheptafulvene 2 umgewandelt, die wiederum thermisch in 1 umlage…

Radical Photochemical ReactionsFluorine in Organic ChemistryPhotochromic and Fluorescence Chemistry

Studies of Organic Semiconductors for 40 Years—V

C. Pecile、A. Palnelli、Alberto Girlando1989-01-01Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics

The aim of the present paper is limited to a survey of part of the prolonged research activity of the Padova group in Italy on the structural and electronic properties of organic charge transfer (CT) crystals studied by optical spectroscopy methods. The presentation is given in the form of a short review, without atte…

Magnetism in coordination complexesMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

An intrinsically photosensitive polyimide

James A. Moore、Andrew N. Dasheff1989-01-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleAn intrinsically photosensitive polyimideJ. A. Moore and A. N. DasheffCite this: Chem. Mater. 1989, 1, 1, 163–166Publication Date (Print):January 1, 1989Publication History Published online1 May 2002Published inissue 1 January 1989https://pubs.acs.org/doi/10.1021/cm00001a029http…

Synthesis and properties of polymers