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Novel V‐shaped negative temperature coefficient of conductivity thermistors and electromagnetic interference shielding effectiveness from butyl rubber–loaded boron carbide ceramic composites

Farid El‐Tantawy、Nikolay Dishovsky2004-01-13Journal of Applied Polymer Science

Abstract The presentation of a new conductive composite with good effective applications like negative and positive temperature coefficient of conductivity thermistors (i.e., V‐shaped thermistors) and electromagnetic interference shielding effectiveness (EMI) was the aim of this study. The effect of boron carbide (B 4…

Ferroelectric and Piezoelectric MaterialsElectromagnetic wave absorption materialsDielectric materials and actuators

Magnetron sputtering growth and characterization of high quality single crystal ZnO thin films on sapphire substrates

Il‐Soo Kim、Sang‐Hun Jeong、Sang Sub Kim 等 4 位作者2004-01-13Semiconductor Science and Technology

ZnO films were grown on sapphire substrates by rf magnetron sputtering and their structural and optical properties were characterized in detail. It was observed that high quality single crystal ZnO films are obtained when grown at high temperature (>600 °C) and low plasma power in oxygen-rich ambient. Films grown at 8…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Direct Observation of Charge Transfer at a MgO(111) Surface

A. Subramanian、Laurence D. Marks、Oliver Warschkow 等 4 位作者2004-01-13Physical Review Letters

Transmission electron diffraction (TED) combined with direct methods have been used to study the sqrt[3]xsqrt[3]R30 degrees reconstruction on the polar (111) surface of MgO and refine the valence charge distribution. The surface is nonstoichiometric and is terminated by a single magnesium atom. A charge-compensating e…

Advanced Chemical Physics StudiesPhysics of Superconductivity and MagnetismElectronic and Structural Properties of Oxides

Stress and structural relaxation in amorphous hydrogenated carbon films

M. Lejeune、M. Benlahsen、R. Bouzerar2004-01-13Applied Physics Letters

The correlation between the residual stress and the atomic-bond structure has been investigated in detail in hydrogenated amorphous films (a-C:H). The relaxation process was studied in relation with the Raman characteristics evolution and the induced metric distortions during growth. The analysis of the Raman data sho…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Effects of CuO and ZnO Additives on Sintering Temperature and Piezoelectric Properties of 0.41Pb(Ni1/3Nb2/3)O3–0.36PbTiO3–0.23PbZrO3Ceramics

Cheol‐Woo Ahn、Sahn Nahm、Jungho Ryu 等 7 位作者2004-01-13Japanese Journal of Applied Physics

ZnO-added 0.41PNN–0.36PT–0.23PZ ceramics cannot be sintered below 950°C. However, when CuO is added, the liquid phase forms and specimens can be sintered even at 850°C. The dielectric constant ( ε T 3 / ε o ), piezoelectric constant ( d 33 ) and electromechanical coupling factor ( k p ) increase with the addition of C…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

Large-Scale Synthesis of High-Quality Single-Walled Carbon Nanotubes by Catalytic Decomposition of Ethylene

S. C. Lyu、Baolong Liu、Seng Hua Lee 等 7 位作者2004-01-13The Journal of Physical Chemistry B

High-quality single-walled carbon nanotubes (SWNTs) have been synthesized over Fe−Mo/MgO catalyst by catalytic decomposition of ethylene at 800 °C. The produced carbon material primarily consists of a SWNT bundle with few defects and a very small amount of amorphous carbon coating. The diameter of an individual SWNT i…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Metallic Conductivity in a Polyoxovanadate Radical Salt of Bis(ethylenedithio)tetrathiafulvalene (BEDT‐TTF): Synthesis, Structure, and Physical Characterization of β″‐(BEDT‐TTF)5[H3V10O28]·4H2O

Eugenio Coronado、José Ramón Galán‐Mascarós、Carlos Giménez‐Saiz 等 7 位作者2004-01-13Advanced Materials

The first hybrid radical salt of bis(ethylenedithio)tetrathiafulvalene (BEDT‐TTF) using a polyoxovanadate as the counterion, (BEDT‐TTF) 5 [H 3 V 10 O 28 ]·4H 2 O, has been obtained and characterized. It contains segregated mixed‐valence 2D stacks of organic radicals interleaved by anionic layers of [H 3 V 10 O 28 ] 3–…

Polyoxometalates: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchVanadium and Halogenation Chemistry

Tailoring of Luminous Transmittance upon Switching for Thermochromic VO2Films by Thickness Control

Gang Xu、Ping Jin、Masato Tazawa 等 4 位作者2004-01-13Japanese Journal of Applied Physics

The difference in luminous transmittance (Δ T lum ) upon switching of VO 2 films strongly affects its solar controllability when used as a thermochromic window. It was found that Δ T lum is controllable by film thickness. Optical calculation for a VO 2 film on quartz glass revealed that the low-temperature semiconduct…

Thin-Film Transistor TechnologiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

The dynamic behaviour of CH3OH and NO2adsorbed on CeO2(111) studied by noncontact atomic force microscopy

Yoshimichi Namai、Kenichi Fukui、Yasuhiro Iwasawa2004-01-13Nanotechnology

The adsorption and reaction of methanol (CH3OH) and nitrogen dioxide (NO2) on CeO2(111) surfaces in different oxidation states were studied by noncontact atomic force microscopy (NC-AFM). After CH3OH exposure, surface oxygen defects without reconstruction of the surrounding oxygen atoms were healed by methoxy species…

Catalytic Processes in Materials ScienceForce Microscopy Techniques and ApplicationsElectronic and Structural Properties of Oxides

Covalent Attachment of Phospholipid Analogous Polymers To Modify a Polymeric Membrane Surface: A Novel Approach

Zhi‐Kang Xu、Qing-Wen Dai、Jian Wu 等 5 位作者2004-01-13Langmuir

A novel method for the surface modification of a microporous polypropylene membrane by tethering phospholipid analogous polymers (PAPs) is given, which includes the photoinduced graft polymerization of N,N-dimethylaminoethyl methacrylate (DMAEMA) and the ring-opening reaction of grafted poly-(DMAEMA) with 2-alkyloxy-2…

Membrane Separation TechnologiesRNA Interference and Gene DeliveryPolymer Surface Interaction Studies

A Tin-Complexation Strategy for Use with Diverse Acylation Methods in the Preparation of 1,9-Diacyldipyrromethanes

Shun‐ichi Tamaru、Lianhe Yu、W. Justin Youngblood 等 6 位作者2004-01-13The Journal of Organic Chemistry

The acylation of dipyrromethanes to form 1,9-diacyldipyrromethanes is an essential step in the rational synthesis of porphyrins. Although several methods for acylation are available, purification is difficult because 1,9-diacyldipyrromethanes typically streak extensively upon chromatography and give amorphous powders…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Correlation of field emission and surface microstructure of vertically aligned carbon nanotubes

Sung Ho Jo、Yi Tu、Zhiwei Huang 等 7 位作者2004-01-13Applied Physics Letters

Two kinds of distinctive field emission behaviors were observed on vertically aligned multiwall carbon nanotube (CNT) films grown by hot filament dc-plasma enhanced chemical vapor deposition. Some samples have stable emission current for more than 60 h (type I), while others degrade substantially in the first 16 h (ty…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Photonic Control of Photoinduced Electron Transfer via Switching of Redox Potentials in a Photochromic Moiety

Yuichi Terazono、Gerdenis Kodis、Joakim Andréasson 等 10 位作者2004-01-13The Journal of Physical Chemistry B

A porphyrin (P) has been covalently linked to a photochromic dihydroindolizine moiety (DHI) to form a P-DHI dyad. When the dihydroindolizine is in its closed, spirocyclic form (DHIc), the photophysics of the attached porphyrin are unaffected. Irradiation with UV light opens the photochromic moiety to the betaine form…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Reactive Deposition of Cobalt and Nickel Films from Their Metallocenes in Supercritical Carbon Dioxide Solution

Ephrem T. Hunde、James J. Watkins2004-01-13Chemistry of Materials

High-purity Co and Ni thin films were deposited directly onto the native oxide of Si wafers and onto TaN and TiN films supported on Si wafers by the hydrogen reduction of their respective metallocenes in supercritical CO 2 solution using a batch, cold-wall chemical fluid deposition (CFD) reactor. For Co deposition fro…

Catalytic Processes in Materials SciencePhase Equilibria and ThermodynamicsHigh-Temperature Coating Behaviors

Surface Modification of Carbon Nanofiber with High Degree of Graphitization

Seongyop Lim、Seong‐Ho Yoon、Isao Mochida 等 4 位作者2004-01-13The Journal of Physical Chemistry B

Mechanical and chemical treatments were found to improve the graphitization extent of graphitized platelet carbon nanofiber, which showed little change in graphitization parameters of X-ray diffraction even after heat treatment at 2800 °C. Such treatments also restored the surface area that was significantly decreased…

Carbon Nanotubes in CompositesGraphene research and applicationsFiber-reinforced polymer composites

Effect of soft‐segment chemistry on polyurethane biostability during in vitro fatigue loading

Michael J. Wiggins、Matt MacEwan、James M. Anderson 等 4 位作者2004-01-13Journal of Biomedical Materials Research Part A

The effect of soft-segment chemistry on biostability of polyurethane elastomers was studied with a diaphragm-type film specimen under conditions of static and dynamic loading. During testing, the films were exposed to an H(2)O(2)/CoCl(2) solution, which simulated the oxidative component of the in vivo environment. Fil…

Polymer composites and self-healingCarbon dioxide utilization in catalysisFree Radicals and Antioxidants

Enhanced luminescence of Gd2O3:Eu3+ thin-film phosphors by Li doping

Soung‐Soo Yi、Jong‐Seong Bae、Kyoo Sung Shim 等 6 位作者2004-01-13Applied Physics Letters

Gd 2 O 3 : Eu 3+ and Li-doped Gd2O3:Eu3+ luminescent thin films have been grown on Al2O3 (0001) substrates using pulsed-laser deposition. The films grown under different deposition conditions show different microstructural and luminescent characteristics. Both cubic and monoclinic crystalline structures were observed…

Luminescence Properties of Advanced MaterialsSemiconductor materials and devicesSilicon Nanostructures and Photoluminescence

Construction of Silk Fiber Core in Lepidoptera

František Sehnal、Michal Žurovec2004-01-13Biomacromolecules

The formation and properties of lepidopteran silk fibers depend on amino acid repeats in the principal protein, heavy chain fibroin (H-fibroin). In H-fibroins of the "bombycoid" type, concatenations of alanine or of the GAGAGS crystalline motifs (1st tier repeats) and adjacent sequences breaking periodicity make 2nd t…

Neurobiology and Insect Physiology ResearchInsect and Arachnid Ecology and BehaviorSilk-based biomaterials and applications

Zinc oxide nanotetrapods

Zheng Chen、Zhiwei Shan、Mao‐Sheng Cao 等 5 位作者2004-01-13Nanotechnology

The carrier gas flow rate, a key parameter for controlling the morphology and size in the synthesis of nanomaterials by thermal evaporation—vapour phase transport—condensation processes, can significantly affect the shape and size of the products. Besides nanoscale ZnO dendrites and wires, a uniform tetrapod-shaped Zn…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

The vibrational properties of one-dimensional ZnO:Ce nanostructures

Baochang Cheng、Yanhe Xiao、Guosheng Wu 等 4 位作者2004-01-13Applied Physics Letters

Different morphological one-dimensional ZnO:Ce nanostructures were synthesized on a large scale. The microstructures and vibrational properties were investigated by x-ray diffraction, electron microscopy, Raman spectroscopy, and infrared spectroscopy. The results show that Ce can effectively control the growth of ZnO…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials