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The Structural Chemistry of Crystalline Carbon: Geometry, Stability, and Electronic Spectrum

Ivan V. Stankevich、M. V. Nikerov、D. A. Bochvar1984-07-31Russian Chemical Reviews

The crystalline modifications of carbon described in the literature are briefly reviewed. The publications in which new types of structures, differing from the diamond and graphite lattices, are proposed and discussed are analysed in detail. The geometrical-topological characteristics of the hypothetical modifications…

Advanced Chemical Physics StudiesCarbon Nanotubes in CompositesDiamond and Carbon-based Materials Research

Spectroscopic investigation of the ferroelectric phase transition in tris-sarcosine calcium chloride: an order-disorder system with displacive features. I. Experimental results

T Chen、G. Schaack1984-07-30Journal of Physics C Solid State Physics

The authors report infrared and Raman spectroscopic investigations of single crystals of tris-sarcosine calcium chloride (TSCC), of the isomorphous tris-sarcosine calcium bromide (TSCB) and of mixed crystals with different chlorine-bromine concentration ratios x (for TSCC 1-x B x ) in the whole wavenumber region below…

Solid-state spectroscopy and crystallographyCrystallization and Solubility StudiesMolecular spectroscopy and chirality

Thermal and transport evidence for a phase transition in 1T-TaS2observed at 282K upon warming

S. C. Bayliss、A. M. Ghorayeb、D.R.P. Guy1984-07-30Journal of Physics C Solid State Physics

The authors present evidence for the existence of a phase transition observed at 282K on warming in 1T-TaS 2 , through differential scanning calorimetry, in-plane electrical resistivity and Hall coefficient measurements. Some in-plane anisotropy is revealed, indicating that this transition may be mainly, though not wh…

Advanced Chemical Physics StudiesMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

Band-Overlap Metallization of BaTe

Thomas A. Grzybowski、Arthur L. Ruoff1984-07-30Physical Review Letters

Energy-dispersive x-ray diffraction studies have been made on BaTe to 410 kbar. It undergoes a first-order phase transition from the sodium chloride structure to the cesium chloride structure at 48 kbar. $P(V)$ data were obtained over the entire range. Optical studies indicated by extrapolation that metallization will…

Rare-earth and actinide compoundsIron-based superconductors researchInorganic Chemistry and Materials

Fiber Technology: From Film to Fiber

H. Krässig、J. Lenz、Herman Mark1984-07-25Medical Entomology and Zoology

This book is intended to fiber technologists, textile dealers, and textile salesmen a practical guideline to become acquainted with and to deepen their knowledge of the processes for the manufacture of film tapes, split-film yarns, and fibrillated film fibers.

Textile materials and evaluations

Calculation of Mg atom-metals XPS and Auger shifts using a ΔSCF excited atom model

D. R. Jennison、P. Weightman、P H Hannah 等 4 位作者1984-07-20Journal of Physics C Solid State Physics

The excited atom model using Delta SCF Hartree-Fock calculations is tested on Mg metal. It is found that the valence configurations of the ground, one- and two-core-hole states may be unambiguously determined simply from the values of the atom-metal XPS and Auger shifts. The above state energies suggest 3s 1 3p 1 , 3s…

Advanced Chemical Physics StudiesMetal and Thin Film MechanicsElectron and X-Ray Spectroscopy Techniques

The effect of H2 absorption on the magnetic properties of GdPd intermetallic compounds

K.H.J. Buschow、D.B. de Mooij1984-07-16physica status solidi (a)

The magnetic and crystallographic properties of several intermetallic compounds of Gd and Pd are studied and compared with the magnetic and crystallographic properties of the corresponding ternary hydrides obtained after charging with hydrogen gas. The mean magnetic coupling strength in the various intermetallic compo…

Rare-earth and actinide compoundsHydrogen Storage and MaterialsMagnetic Properties of Alloys

Electrooptic properties of Rb2ZnCl4 in the incommensurate and ferroelectric phases

Roland Sanctuary、Peter Günter1984-07-16physica status solidi (a)

The electrooptic coefficients ra = r33 − (n2/n3)3 r23, rb = r33, − (n1/n3)3 r13 and rc = r13 − (n2/n1)3 r23, of Rb,ZnCl4 for light propagation directions along the three crystallographic axes a, b, and c are measured in the temperature range from 100 to 220 K (ni, i = 1, 2, 3, indices of refraction). In the incommensu…

Glass properties and applicationsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Glasslike Behavior and Novel Pressure Effects inKTa1−xNbxO3

G. A. Samara1984-07-16Physical Review Letters

High-pressure studies have shown that $\mathrm{K}{\mathrm{Ta}}_{1\ensuremath{-}x}{\mathrm{Nb}}_{x}{\mathrm{O}}_{3}$ crystals with small $x(\ensuremath{\approx}0.02)$ exhibit relaxational glasslike behavior rather than a static ferroelectric structural phase transition as previously thought. The results show a pressure…

Ferroelectric and Piezoelectric MaterialsHigh-pressure geophysics and materialsMicrowave Dielectric Ceramics Synthesis

Pressure effect on magnetic transformations in the CoxNi1−x MnGe system

R. Zach、R. Duraj、A. Szytuła1984-07-16physica status solidi (a)

The magnetic phase diagram for the system CoxNi1−xMnGe (0 ≦ x ≦ 1.0) is determined by ac susceptibility measurements under pressure up to 1.5 GPa. The temperature of the magnetic phase transition behaves similarly for all compounds examined: increasing external pressure causes the Néel or Curie temperatures to increas…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

T2dependence of the in-plane resistivity of graphite at very low temperatures

Donald T. Morelli、Ctirad Uher1984-07-15Physical review. B, Condensed matter

High-precision measurements of the in-plane resistivity of graphite have been made in a dilution refrigerator down to 20 mK. Below 5 K, the resistivity varies as a quadratic function of temperature, behavior consistent with the electron-hole scattering mechanism. The strength of the interaction is in good agreement wi…

Graphene research and applicationsGraphite, nuclear technology, radiation studiesSurface and Thin Film Phenomena

Computer simulation of site formation for Na atoms trapped in Ar and Xe solids

L. C. Balling、John Wright1984-07-15The Journal of Chemical Physics

Existing data on Na-rare gas and rare gas–rare gas dimer potentials have been used in a computer program to simulate the formation of trapping sites for Na atoms isolated in Ar and Xe solids. The dimer potentials have also been employed to calculate the matrix perturbed energy-level structure of the Na atoms to obtain…

Luminescence Properties of Advanced MaterialsAtomic and Subatomic Physics ResearchInorganic Fluorides and Related Compounds

A study of the initial growth kinetics of the copper-aluminum thin-film interface reaction by i n s i t u x-ray diffraction and Rutherford backscattering analysis

R. A. Hamm、J. M. Vandenberg1984-07-15Journal of Applied Physics

X-ray diffraction and Rutherford backscattering (RBS) analysis were used independently to investigate the interface reaction of Cu-Al thin-film bilayers during in situ annealing in the temperature range 157–220 °C. The growth kinetics of the θ-CuAl2 phase were measured and were found to follow a diffusion limited proc…

Electronic Packaging and Soldering TechnologiesAluminum Alloys Composites PropertiesCopper Interconnects and Reliability

Dielectric surface-relief gratings with high diffraction efficiency

Kiyoshi Yokomori1984-07-15Applied Optics

Diffraction properties of dielectric surface-relief gratings were investigated by solving Maxwell’s equations numerically using the differential method. The diffraction efficiency of a grating with a groove depth about twice as deep as the grating period is comparable with the efficiency of a volume phase grating. Die…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Polarons, bipolarons, and their interactions in cis -polyacetylene

Yositaka Onodera1984-07-15Physical review. B, Condensed matter

Explicit solutions for the Brazovskii-Kirova continuum model of cis-polyacetylene are presented for the following three configurations: two polarons, two bipolarons, and a polaron and a bipolaron coexisting on a single chain. The results show that two polarons attract each other with a long-range potential reflecting…

Conducting polymers and applicationsAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Calibration of the Malvern particle sizer

Lee G. Dodge1984-07-15Applied Optics

A relatively simple technique has been developed to calibrate particle- and droplet-sizing instruments manufactured by Malvern and other similar Fraunhofer diffraction particle-sizing instruments. Measurements of standard reticles using an instrument calibrated in this manner demonstrate the effectiveness of the proce…

Electron and X-Ray Spectroscopy Techniques

Mechanism for photogeneration of charge carriers in polyacetylene

J. Orenstein、Z. Valy Vardeny、Gregory L. Baker 等 5 位作者1984-07-15Physical review. B, Condensed matter

In light of new experimental observations, a mechanism for the photogeneration of charge carriers in trans-polyacetylene is presented. By way of introduction, we discuss the qualitative changes in the picture of charged-solition photogeneration that are expected due to the inclusion of electron correlation effects. In…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

X-ray photoelectron and Auger-electron forward scattering: A new tool for studying epitaxial growth and core-level binding-energy shifts

W. F. Egelhoff1984-07-15Physical review. B, Condensed matter

Above a few hundred eV kinetic energy, Auger electrons and photoelectrons exhibit strong forward scattering by overlying atoms, and this produces intensity peaks at polar and azimuthal angles corresponding to internuclear axes. This provides a new structural probe which is especially useful for studying epitaxy, surfa…

X-ray Spectroscopy and Fluorescence AnalysisMachine Learning in Materials ScienceElectron and X-Ray Spectroscopy Techniques

Synchrotron photoemission investigation: Fluorine on silicon surfaces

J. F. Morar、F. R. McFeely、N. D. Shinn 等 5 位作者1984-07-15Applied Physics Letters

High resolution core level photoemission spectroscopy has been used to obtain the first direct identification of the chemical species remaining on silicon surfaces after exposure to fluorine. Both Si(111) 2×1 and Si(111) 7×7 were exposed to fluorine via the dissociative chemisorption of XeF2. For fluorine coverages in…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Physical mechanisms of dc switching in a liquid-crystal bistable boundary layer display

R. N. Thurston、Julian Cheng、Robert B. Meyer 等 4 位作者1984-07-15Journal of Applied Physics

We discuss two mechanisms proposed to explain dc switching of a bistable liquid-crystal boundary layer display. These are (1) biasing by double layer fields that arise from charge of one sign preferentially adsorbed at the walls, and (2) asymmetry in the transient depletion layer fields which result from a difference…

Liquid Crystal Research AdvancementsTheoretical and Computational PhysicsNonlinear Dynamics and Pattern Formation