Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynergy in N-ethylformamide dehydration by mixtures of molybdenum trioxide and antimony oxide (.alpha.-Sb2O4)B. Zhou, S. Ceckiewicz, and B. DelmonCite this: J. Phys. Chem. 1987, 91, 19, 5061–5067Publication Date (Print):September 10, 1987Publication History Published online1…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron pairing in dilute liquid metal-metal halide solutionsA. Selloni, R. Car, M. Parrinello, and P. CarnevaliCite this: J. Phys. Chem. 1987, 91, 19, 4947–4949Publication Date (Print):September 10, 1987Publication History Published online1 May 2002Published inissue 10 Sep…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemical effects on the optical properties of semiconductor particlesY. Wang and N. HerronCite this: J. Phys. Chem. 1987, 91, 19, 5005–5008Publication Date (Print):September 10, 1987Publication History Published online1 May 2002Published inissue 10 September 1987https://pubs…
Microcrystals and microcrystalline films of diamond were prepared on molybdenum substrates in a thermal plasma which was produced by rf inductive heating in an argon-hydrogen-methane mixture gas under 1 atm pressure. The deposition rate amounted to 1 μm/min.
Measurements of the self-diffusion coefficient in supercooled water to 300 MPa are reported. Translational diffusion in liquid water at 243 K is enhanced by 60% when the pressure is increased from 0.1 to 150 MPa, and rotational diffusion is enhanced by almost 250% between 0.1 and 250 MPa. These striking anomalies are…
The ferromagnetic resonance (FMR) and infrared spectra (IR) of polycrystalline MnZn ferrite have been studied for samples with high permeability (∼10000) and low permeability (∼4000) values to investigate the origin of physical processes which result in permeability enhancement. Two resonance peaks are observed for al…
The relationship between tensile elongation and acoustic emission (AE) detected during compressive deformation of Al-Li and Al-Li-Zr alloys has been investigated for a range of microstructure. For comparison, AE measurements have been carried out for Al-Cu and commercial 7050 alloys. In the polycrystalline binary Al-L…
Abstract Reaction of UO2F2 with UF5 at 400 °C under UF6-pressure of 3 atm followed by evaporation of excess UF5 has yielded a greenish white residue. Its X-ray diffraction pattern and infrared spectrum are sufficiently unique to establish that this material is a true compound. Its chemical formula has been shown to be…
Abstract Lattice constants of sodium chlorate and sodium bromate and their mixed crystals were determined over the temperature range from room temperature to 320 °C. The observed lattice constants for the various compositions show strong deviations from those expected from Vegard's rule. The lattice constants at vario…
Abstract X-ray powder diffraction and single-crystal data are reported for a series of isomorphous compounds with the general chemical composition (Fe,Al) 3 (K,NH 4 ,H 3 O)H 14 (PO 4 ) 8 ·4H 2 O. The compounds are monoclinic with space group C2/c. Unit-cell parameters were determined on the mixed salt (Fe 0.84 ,Al 0.1…
The conventional, large scale techniques employed for casting fabrication ingot in aluminium alloys allow, in certain circumstances, the molten alloy to come into contact with water. Industry codes of practice have been developed that reduce the likelihood of explosions in these "run-out" situations to a very low leve…
The effect of varying degrees of stretch on various cotton yarn properties during mercerization was studied. Scoured cotton yarns were slack mercerized in an aqueous solution of caustic soda, then restretched to 90%, 94%, 96%, 100%, and 103% of the original lengths. There was a considerable increase in strength and a…
Als eine Art „anorganische Sandwich‐Verbindung”︁ ohne Metall‐Metall‐Bindungen kann der Komplex 1 angesehen werden: Er enthält zwei relativ flache [Mn 4 III O 2 ]‐Einheiten und dazwischen ein Mn II ‐Atom. 1 bildet sich in Form schwarzer Kristalle aus [Mn 3 O(O 2 CPh) 6 (py) 2 (H 2 O)], das in Acetonitril gelöst und mit…
Abstract Aromatic polyesters containing imide pendant groups have been prepared from diphenols and 5‐imidoisophthaloyl chlorides by the interfacial polycondensation method. Linear polyesters without substituents have also been synthesized by the same method for comparative purposes. The presence of side imide groups e…
Abstract Zn(II) complexes of pyridoxal–α-amino acid Schiff bases showed photochromic behavior in methanol. Spectral studies revealed that intramolecular nucleophilic attack of 5′-hydroxyl group on imine linkage forms cyclic α-amino ether intermediates which thermally return to the original complexes. The photochromism…
Triboelectric charging of hair modified by surface deposition of a series of monomeric and polymeric long alkyl chain quaternary ammonium salts was examined. The length of the hydrophobic alkyl chain in both monomeric and polymeric surfactants, the composition of copolymer-containing surfactant and nonsurfactant units…
Nylon 6, nylon 66, and poly(ethylene terephthalate) (PET) fibers were subjected to superheated steaming. The effects of a small amount of water vapor in superheated steam on the fine structure and dyeing behavior of the fibers were examined at varying steaming temperatures by measuring shrinkage, crystallinity, crysta…
UV‐visible, infrared, and Raman spectroscopic studies have shown that little to weak interactions occur between the halogens , , and or the interhalogens , , , and , and . The degree of dissociation of the interhalogens in have been determined to be similar to those in the nonpolar medium of . Cyclic voltammetric stud…
Testing cables in the field requires a specialized knowledge of dielectric behavior, electrical stress phenomena, safe and proper use of test equipment, and interpretation of test results. Theoretical and practical aspects of high-potential field testing of medium- and high-voltage extruded cables are discussed. The f…
The mechanical properties of ferrite filled thermoplastics at high filler loadings of 75-85% by weight are reported. Barium ferrite was used as the filler in the magnetic polymeric composites. Three types of thermoplastic elastomers, namely, styrenic, polyester-ether, and polyurethane were investigated as matrix mater…