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Preparation of the Novel Mesoporous Solid Acid Catalyst UDCaT‐4 via Synergism of Persulfated Alumina and Zirconia into Hexagonal Mesoporous Silica for Alkylation Reactions

Ganapati D. Yadav、Ambareesh D. Murkute2004-03-01Advanced Synthesis & Catalysis

Abstract A novel mesoporous solid acid catalyst named UDCaT‐4 was designed by loading persulfated alumina and zirconia (PAZ) into highly oredered, hexagonal mesoporous silica (HMS). UDCaT‐4 was characterized by XRD, BET surface area and pore size analysis which revealed that neither pore blocking nor structure collaps…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisChemical Synthesis and Reactions

Thermotropic Liquid‐Crystalline Polymer Derived from Natural Cinnamoyl Biomonomers

Tatsuo Kaneko、Michiya Matsusaki、Trần Thị Như Hằng 等 4 位作者2004-03-01Macromolecular Rapid Communications

Abstract Summary: The compound 4‐hydroxycinnamic acid (4HCA), a natural biomonomer, is polymerized by melt polycondensation to yield a liquid‐crystalline biopolymer (P4HCA) with UV reactivity. L929 cells were successfully incubated on P4HCA films at 37 °C. Structure of poly(4‐hydroxycinnamic acid) (P4HCA) and its cros…

Liquid Crystal Research Advancementsbiodegradable polymer synthesis and propertiesAdvanced Materials and Mechanics

Flaw tolerant bulk and surface nanostructures of biological systems.

Huajian Gao、Baohua Ji、Markus J. Buehler 等 4 位作者2004-03-01PubMed

Bone-like biological materials have achieved superior mechanical properties through hierarchical composite structures of mineral and protein. Gecko and many insects have evolved hierarchical surface structures to achieve extraordinary adhesion capabilities. We show that the nanometer scale plays a key role in allowing…

Force Microscopy Techniques and ApplicationsCalcium Carbonate Crystallization and InhibitionAdhesion, Friction, and Surface Interactions

Gross Morphology and Absorption Capacity of Cell-Fibers from the Fibrous Vascular System of Loofah (Luffa cylindrica)

Kheir Eddine Bal、Youcef Bal、Abdelaziz Lallam2004-03-01Textile Research Journal

This paper investigates the liquid absorbency potential of the vegetal cell-fibers (CF) of Luffa cylindrica (LC) in relation to their microscopic morphology. Absorption after drainage and centrifugation, involving deionized water and saline solutions, is measured on both the raw fibers of the vegetal net and the cell-…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical Applications

Synthesis and Magnetic Properties of Single‐Crystals of MnFe2O4 Nanorods

Jun Wang、Qianwang Chen、Binyang Hou 等 4 位作者2004-03-01European Journal of Inorganic Chemistry

Abstract Single‐crystals of MnFe 2 O 4 nanorods with an average diameter of 20 nm and length of 250 nm were synthesized by a hydrothermal process at 180 °C after 12 h. High‐resolution transmission electron microscopy (HRTEM) and electron diffraction (ED) analysis revealed that the nanorods grow along the [110] axis, w…

Advancements in Battery MaterialsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

Energy Transfer in Fluorescent Silica Nanoparticles

Marco Montalti、Luca Prodi、Nelsi Zaccheroni 等 6 位作者2004-03-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTEnergy Transfer in Fluorescent Silica NanoparticlesMarco Montalti, Luca Prodi, Nelsi Zaccheroni, Andrea Zattoni, Pierluigi Reschiglian, and Giuseppe FaliniView Author Information Dipartimento di Chimica "G.Ciamician", Università di Bologna, Via Selmi 2, 40126 Bologna, Italy Cit…

Advanced biosensing and bioanalysis techniquesLuminescence and Fluorescent MaterialsCarbon and Quantum Dots Applications

Programming Heteropolymetallic Lanthanide Helicates: Thermodynamic Recognition of Different Metal Ions Along the Strands

Sébastien Floquet、Michal Borkovec、Gérald Bernardinelli 等 9 位作者2004-03-01Chemistry - A European Journal

Under stoichiometric conditions, the segmental tris-tridentate ligand L9 assembles with two different lanthanide metal ions Ln(1) and Ln(2) (Ln(1), Ln(2)=La, Nd, Sm, Eu, Yb, Lu, Y) to give mixtures of the heterotrimetallic triple-stranded helicates [(Ln(1))(x)(Ln(2))(3-x)(L9)(3)](9+) (x=0-3) in acetonitrile. The combi…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesLanthanide and Transition Metal Complexes

The Magnetic Field Diffusion Equation Including Dynamic Hysteresis: A Linear Formulation of the Problem

Marie‐Ange Raulet、Benjamin Ducharne、Jean‐Pierre Masson 等 4 位作者2004-03-01IEEE Transactions on Magnetics

The introduction of accurate material modeling such as hysteresis phenomenon in numerical field calculation leads to numerical problems induced by the nonlinear properties of the initial system. We focus on the solution of the magnetic field diffusion equation, which contains such problems. This paper presents a new f…

Microstructure and Mechanical Properties of SteelsSolidification and crystal growth phenomenaMagnetic Properties and Applications

Mechanism of etching and surface relief development of PMMA under low-energy ion bombardment

Y. Koval2004-03-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

The structure of the subsurface layer of polymethylmethacrylate (PMMA) formed by bombardment with low-energy ions of Ar is reported. It was found that the subsurface region contains a graphitized, cross-linked, and low-molecular weight layers. We argue that ion etching of PMMA is mostly determined by the properties of…

Diamond and Carbon-based Materials ResearchIon-surface interactions and analysisPolymer Nanocomposite Synthesis and Irradiation

3. Acetate manufacturing, process and technology 3.1 Chemistry of cellulose acetylation

Hans Steinmeier2004-03-01Macromolecular Symposia

Abstract Nowadays Celluloseacetate is mainly produced with the acetic acid process. After an activation with acetic acid and sulfuric acid the acetylation of the cellulose starts by adding acetic anhydride. The temperature and the catalyst concentration play an important role for the reaction. Beneath acetylation also…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesFiber-reinforced polymer composites

5. Applications of cellulose acetate 5.1 Cellulose acetate in textile application

Rachel C. Law2004-03-01Macromolecular Symposia

Abstract The first cellulose acetate fiber, commonly referred to as acetate, was produced in Europe in 1918 and on a large scale in the United States of America in 1924 making acetate the second man‐made fiber to be produced. 1 The usage of acetate worldwide peaked at a consumption of approximately 400 kilotons in the…

Dyeing and Modifying Textile FibersTextile materials and evaluations

Inhibition of Filiform Corrosion on Organic-Coated Aluminum Alloy by Hydrotalcite-Like Anion-Exchange Pigments

H. N. McMurray、G. Williams2004-03-01CORROSION

Novel anion-exchange anticorrosion pigments consisting of nitrate-, carbonate-, and chromate-exchanged hydrotalcite (HT) are shown to inhibit the propagation of filiform corrosion (FFC) effectively on organic-coated aluminum alloy 2024-T3 (AA2024-T3 [UNS A92024]) alloy. The HT-pigments are dispersed in polyvinyl butyr…

Layered Double Hydroxides Synthesis and ApplicationsThermal Expansion and Ionic ConductivityMagnesium Oxide Properties and Applications

A Time-Domain Homogenization Technique for Laminated Iron Cores in 3-D Finite-Element Models

Johan Gyselinck、Patrick Dular2004-03-01IEEE Transactions on Magnetics

The authors present a novel time-domain homogenization technique for laminated iron cores in three-dimensional (3-D) FE models of electromagnetic devices when using the magnetic vector potential formulation. The method is based on a polynomial orthogonal decomposition of the variation of the induction throughout the t…

Magnetic Properties and ApplicationsElectromagnetic Simulation and Numerical MethodsInduction Heating and Inverter Technology

Matrix loading: Assembly of extracellular matrix collagen fibrils during embryogenesis

Karl E. Kadler2004-03-01Birth Defects Research Part C Embryo Today Reviews

Nothing in biology stimulates the imagination like the development of a single fertilized egg into a newborn child. Consequently, a major focus of biomedical research is aimed at understanding cell differentiation, proliferation, and specialization during child health and human development. However, the fact that the…

Connective tissue disorders researchCollagen: Extraction and CharacterizationBone and Dental Protein Studies

Pitting and crevice corrosion of superaustenitic stainless steels

Gregor Mori、Dieter Bauernfeind2004-03-01Materials and Corrosion

Abstract Superaustenites are mainly used in offshore applications, oil production and chemical industry. Most important types of localised corrosion of these steels are pitting and crevice corrosion. Investigated materials were N08028, S31254 and three modified alloys. Chromium content of investigated alloys varied be…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and Creep

Experimental study of the transformation of smectite at 80 and 300°C in the presence of Fe oxides

Damien Guillaume、Alexander Neaman、M. .athelineau 等 9 位作者2004-03-01Clay Minerals

ABSTRACT: The alteration and transformation behaviour of montmorillonite (Wyoming bentonite) was studied experimentally to simulate the mineralogical and chemical reaction of clays in contact with steel in a nuclear waste repository. Batch experiments were conducted at 80 and 300ºC, in low-salinity solutions (NaCl, Ca…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

The atomic pair distribution function: past and present

Simon J. L. Billinge2004-03-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The history of the PDF method is briefly reviewed. Recent results, principally from the Billinge group, are also reviewed.

Advanced Chemical Physics StudiesCrystal Structures and PropertiesX-ray Diffraction in Crystallography

1. History of CA and evolution of the markets

Paul Rustemeyer2004-03-01Macromolecular Symposia

Abstract An overlook is given of the 100 years of technical, industrial and chemical development of cellulose acetate. CA has been used as raw material in the fields of laquer, plastics, textile, Filter Tow, film, membrane and others. In the field of applications for plastics and textiles CA was quite successful for m…

Advanced Cellulose Research StudiesAerosol Filtration and Electrostatic PrecipitationPolymer Science and PVC

Microstructure Dependence of Stress Corrosion Cracking Initiation in X-65 Pipeline Steel Exposed to a Near-Neutral pH Soil Environment

Raymond Chu、W. Chen、Sheng-Hui Wang 等 6 位作者2004-03-01CORROSION

A study was carried out to understand mechanisms of stress corrosion crack initiation in an X-65 pipeline steel exposed to a near-neutral pH soil environment under a mechanical loading condition typical of a pipeline operating in the field. Microcracks initiated on the polished surface of the X-65 pipeline steel after…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms