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Photoswitching of Ferroelectric Liquid Crystals Using Unsymmetrical Chiral Thioindigo Dopants: Photoinduced Inversion of the Sign of Spontaneous Polarization

Jason Z. Vlahakis、Michael Wand、Robert P. Lemieux2004-07-01Advanced Functional Materials

Abstract A new unsymmetrical chiral thioindigo dopant 6‐[( R , R )‐2,3‐difluorooct‐1‐yloxy]‐5′‐nitro‐6′‐[( R )‐2‐octyloxy]thioindigo ( 4 ) designed to photoinvert the sign of spontaneous polarization ( P S ) in a ferroelectric chiral smectic C (SmC*) liquid crystal was prepared using a synthetic approach previously de…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistryMolecular spectroscopy and chirality

Protein Immobilization on Carbon Nanotubes Through a Molecular Adapter

Jeffrey S. Lenihan、Vasilis G. Gavalas、Jianquan Wang 等 5 位作者2004-07-01Journal of Nanoscience and Nanotechnology

A new approach to the modification of carbon nanotubes with biomolecules for the development of nanoscale biosensors is presented. Alkaline phosphatase was immobilized on the surface of multi-wall carbon nanotubes utilizing a layer-by-layer methodology. Carbon nanotubes were incubated with streptavidin, resulting in t…

Carbon Nanotubes in CompositesElectrochemical sensors and biosensorsMolecular Junctions and Nanostructures

Effect of isovalent doping of manganite (La1−xPrx)0.7Ca0.3MnO3 films (0≤x≤1) on their optical, magnetooptical, and transport properties near the metal-insulator transition

Yu. P. Sukhorukov、N. N. Loshkareva、Е. А. Ганьшина 等 9 位作者2004-07-01Physics of the Solid State

The optical, magnetooptical, and electric properties of epitaxial (La 1− x Pr x ) 0.7 Ca 0.3 MnO 3 films (0≤ x ≤1) grown by MOCVD on LaAlO 3 and SrTiO 3 substrates were studied. It is shown that the decrease in the average cation radius resulting from isovalent substitution of the Pr for La ions brings about a lowerin…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Preparation of Micrometer‐ to Sub‐micrometer‐Sized Nanostructured Silica Particles Using High‐Energy Ball Milling

J. Eric Hampsey、Claudio L. De Castro、Byron F. McCaughey 等 6 位作者2004-07-01Journal of the American Ceramic Society

Nanostructured porous silica particles with sizes in the micrometer to sub‐micrometer range are of great interest due to their potential applications as catalyst supports and nanocomposite materials. However, if these particles are to be used in industry, a process must be developed to affordably produce them on a lar…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisAerogels and thermal insulation

Relationship between the Size of the Latex Beads and the Solid−Solid Phase Transitions in Emulsion Polymerized Poly(tetrafluoroethylene)

Carla Marega、Antonio Marigo、Valerio Causin 等 6 位作者2004-07-01Macromolecules

Ten virgin powder samples of poly(tetrafluoroethylene) (PTFE) were examined by differential scanning calorimetry (DSC) and wide-angle X-ray scattering (WAXS). The samples, prepared by emulsion or nanoemulsion polymerization, differed by average molecular weight and particle size. DSC was used to study the trends of th…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Dynamics of jumpwise temperature pitch variations in planar cholesteric layers for a finite strength of surface anchoring

V. A. Belyakov、I. W. Stewart、M. A. Osipov2004-07-01Journal of Experimental and Theoretical Physics

The dynamics of pitch jumps in cholesteric layers with a finite surface anchoring strength under variations in temperature is investigated theoretically. General expressions are presented that connect the dynamics of pitch jumps with the parameters that determine the process, such as the viscosity, the specific form o…

Liquid Crystal Research AdvancementsForce Microscopy Techniques and ApplicationsPlant Reproductive Biology

Two-Phase Natural Circulation Flow in AP-1000 In-Vessel Retention-Related ULPU-V Facility Experiments

Nam Dinh、Jianwei Tu、T.G. Theofanous2004-07-01OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)

This paper is concerned with two-phase flow regimes and characteristics of coolant natural circulation around a reactor pressure vessel (RPV) in in-vessel retention (IVR) scenarios when the external vessel flooding is applied to arrest a hypothetical core melt accident. We focus on the AP1000 advanced plant design, an…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear Engineering Thermal-Hydraulics

Nucleation, Growth, Fractal Aggregation, and Late-Stage Coarsening on Structural Development of Polymer Physical Gels

Che‐Min Chou、Po‐Da Hong2004-07-01Macromolecules

By using the time-resolved small-angle light scattering (TRSALS) technique, we present the real-time measurement of the physical gelation process for a crystalline polymer. To investigate the growth kinetics, a complete picture of the gel structural formation should be differentiated into the nucleation and growth of…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

On determining the phase-selection principle in solidification from undercooled melts—competitive nucleation or competitive growth?

Mingjun Li、Shumpei Ozawa、Kazuhiko Kuribayashi2004-07-01Philosophical Magazine Letters

A survey of the published literature on undercooled metallic and oxide melts suggests that phase selection during solidification can be categorized as nucleation controlled or growth controlled. Common characteristics governing the phase-selection pathway have been identified for various alloy systems. It is recognize…

Metallic Glasses and Amorphous AlloysSolidification and crystal growth phenomenaMetallurgical Processes and Thermodynamics

High‐Temperature Fatigue Strength of Crack‐Healed Al 2 O 3 Toughened by SiC Whiskers

Sang‐Kee Lee、Koji Takahashi、Masahiro Yokouchi 等 5 位作者2004-07-01Journal of the American Ceramic Society

Al 2 O 3 reinforced by SiC whiskers (Al 2 O 3 /SiC‐W) was hot‐pressed to investigate the fatigue strength of crack‐healed specimens at high temperature. Semielliptical surface cracks of 100 μm surface length were introduced on each specimen surface. These specimens were crack‐healed at 1300°C for 1 h in air, and stati…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesFire effects on concrete materials

Modeling of Magnetization and Demagnetization in Magnetic Regenerative Refrigeration

Farhad Shir、E. DellaTorre、L. H. Bennett 等 5 位作者2004-07-01IEEE Transactions on Magnetics

A time-dependent model of temperature in magnetization and demagnetization processes is developed based on thermodynamic and heat transfer laws, material properties, and variable-field magnet parameters. Test results of a magnetic refrigeration test bed are compared with the model calculation. The model can be used to…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsOptical properties and cooling technologies in crystalline materials

The Correlation between Electrically Induced Stress and Mechanical Tensile Strength of Polypyrrole Actuators

Tetsuji Zama、Susumu Hara、Wataru Takashima 等 4 位作者2004-07-01Bulletin of the Chemical Society of Japan

Abstract Highly stretchable and powerful PPy film actuators, prepared electrochemically from a methyl benzoate solution of tetra-n-butylammonium tetrafluoroborate (TBABF4), showed a positive correlation between the electrochemical stress and the mechanical tensile strength. The more flexible CF3SO3−-doped PPy suits mu…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Lysine β311 of Protein Geranylgeranyltransferase Type I Partially Replaces Magnesium

Heather L. Hartman、Katherine Bowers、Carol A. Fierke2004-07-01Journal of Biological Chemistry

Protein geranylgeranyltransferase type I (GGTase I) catalyzes the attachment of a geranylgeranyl lipid group near the carboxyl terminus of protein substrates. Unlike protein farnesyltransferase (FTase) and protein geranylgeranyltransferase type II, which require both Zn(II) and Mg(II) for maximal turnover, GGTase I tu…

Bacterial Genetics and BiotechnologyRNA and protein synthesis mechanismsEnzyme Structure and Function

Photophysical Properties of TlGaS2 Layered Single Crystals

I.M. Ashraf2004-07-01The Journal of Physical Chemistry B

The photoconductivity (PC) of TlGaS 2 layered single crystals was investigated in the 77−300 K temperature, 1000−2500 lx excitation intensity, 10−25 V applied voltage, and 415−535 nm wavelength ranges. Both the alternating current photoconductivity (ac-PC) and the spectral distribution of the photocurrent were studied…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Photoemission study of the translational energy induced oxidation processes on Cu(111)

Kousuke Moritani、Michio Okada、Seiichi Sato 等 7 位作者2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

The oxidation processes of Cu(111) with a hyperthermal O2 molecular beam (HOMB) were studied using high-resolution x-ray photoemission spectroscopy in conjunction with a synchrotron radiation source. The O-uptake curves were precisely measured at ∼300 K when irradiating with 2.3 and 0.6 eV HOMB on a Cu(111) surface. A…

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Simplified Versus Detailed Solid Oxide Fuel Cell Reactor Models and Influence on the Simulation of the Design Point Performance of Hybrid Systems

Loredana Magistri、R. Bozzo、Paola Costamagna 等 4 位作者2004-07-01Journal of Engineering for Gas Turbines and Power

High-efficiency hybrid systems (HS) based on the coupling of solid oxide fuel cells (SOFCs) and gas turbines (GT) are analyzed in this paper through the use of two different approaches: simplified and detailed SOFC models. The simplified model, already presented by the authors, is very useful for HS design and off-des…

Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesCatalysis and Oxidation Reactions

Suitability of alternative fatty food simulants to study the effect of thermal and microwave heating on overall migration of plastic packaging

María José Galotto、Abél Guarda2004-07-01Packaging Technology and Science

Abstract The suitability of alternative fatty food simulants on overall migration determination under thermal treatment and microwave heating were analysed for different plastic materials commonly used for packs subjected to thermal treatment or microwave heating. Elevated temperature and microwave heating increased o…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingFood Waste Reduction and Sustainability

Laser-etched silicon pillars and their porosification

David Mills、Kurt W. Kołasiński2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Mesoscale silicon pillars are formed when silicon wafers are irradiated by a nanosecond excimer laser operating at 308 nm and incident fluence of ∼3 J cm−2. The morphology of the pillars responds to the chemical composition of the gas phase above the Si surface. Postprocessing can also be used to change the structure…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Solid-solution hardening by point-like obstacles of different kinds

Masato Hiratani、Vasily V. Bulatov2004-07-01Philosophical Magazine Letters

The critical resolved shear stress (CRSS) for a dislocation percolating through penetrable obstacles with different pinning strength is derived analytically. The stability of dislocation–obstacle configurations is determined by evaluating the configurational entropy. The analytical results imply a superposition law fo…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsFusion materials and technologies

SURFACE MODIFICATIONS AND ADHESION OF VULCANIZED SBR RUBBER TREATED WITH RF PLASMAS OF DIFFERENT GASES

Ana B. Ortíz‐Magán、M. Mercedes Pastor‐Blas、José Miguel Martín‐Martínez2004-07-01The Journal of Adhesion

The surface modifications produced by treatment of a synthetic vulcanized styrene-butadiene rubber (R1) with oxidizing (oxygen, air, carbon dioxide) and nonoxidizing (nitrogen, argon) RF plasmas have been assessed by ATR-IR and XPS spectroscopy, SEM, and contact angle measurements. The effectiveness of the treatment d…

Surface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomenaSilicone and Siloxane Chemistry