Jason Z. Vlahakis、Michael Wand、Robert P. Lemieux2004-07-01Advanced Functional Materials
Abstract A new unsymmetrical chiral thioindigo dopant 6‐[( R , R )‐2,3‐difluorooct‐1‐yloxy]‐5′‐nitro‐6′‐[( R )‐2‐octyloxy]thioindigo ( 4 ) designed to photoinvert the sign of spontaneous polarization ( P S ) in a ferroelectric chiral smectic C (SmC*) liquid crystal was prepared using a synthetic approach previously de…
Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistryMolecular spectroscopy and chirality
Jeffrey S. Lenihan、Vasilis G. Gavalas、Jianquan Wang 等 5 位作者2004-07-01Journal of Nanoscience and Nanotechnology
A new approach to the modification of carbon nanotubes with biomolecules for the development of nanoscale biosensors is presented. Alkaline phosphatase was immobilized on the surface of multi-wall carbon nanotubes utilizing a layer-by-layer methodology. Carbon nanotubes were incubated with streptavidin, resulting in t…
Carbon Nanotubes in CompositesElectrochemical sensors and biosensorsMolecular Junctions and Nanostructures
Yu. P. Sukhorukov、N. N. Loshkareva、Е. А. Ганьшина 等 9 位作者2004-07-01Physics of the Solid State
The optical, magnetooptical, and electric properties of epitaxial (La 1− x Pr x ) 0.7 Ca 0.3 MnO 3 films (0≤ x ≤1) grown by MOCVD on LaAlO 3 and SrTiO 3 substrates were studied. It is shown that the decrease in the average cation radius resulting from isovalent substitution of the Pr for La ions brings about a lowerin…
Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides
J. Eric Hampsey、Claudio L. De Castro、Byron F. McCaughey 等 6 位作者2004-07-01Journal of the American Ceramic Society
Nanostructured porous silica particles with sizes in the micrometer to sub‐micrometer range are of great interest due to their potential applications as catalyst supports and nanocomposite materials. However, if these particles are to be used in industry, a process must be developed to affordably produce them on a lar…
Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisAerogels and thermal insulation
Carla Marega、Antonio Marigo、Valerio Causin 等 6 位作者2004-07-01Macromolecules
Ten virgin powder samples of poly(tetrafluoroethylene) (PTFE) were examined by differential scanning calorimetry (DSC) and wide-angle X-ray scattering (WAXS). The samples, prepared by emulsion or nanoemulsion polymerization, differed by average molecular weight and particle size. DSC was used to study the trends of th…
Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties
V. A. Belyakov、I. W. Stewart、M. A. Osipov2004-07-01Journal of Experimental and Theoretical Physics
The dynamics of pitch jumps in cholesteric layers with a finite surface anchoring strength under variations in temperature is investigated theoretically. General expressions are presented that connect the dynamics of pitch jumps with the parameters that determine the process, such as the viscosity, the specific form o…
Liquid Crystal Research AdvancementsForce Microscopy Techniques and ApplicationsPlant Reproductive Biology
Nam Dinh、Jianwei Tu、T.G. Theofanous2004-07-01OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)
This paper is concerned with two-phase flow regimes and characteristics of coolant natural circulation around a reactor pressure vessel (RPV) in in-vessel retention (IVR) scenarios when the external vessel flooding is applied to arrest a hypothetical core melt accident. We focus on the AP1000 advanced plant design, an…
Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear Engineering Thermal-Hydraulics
Che‐Min Chou、Po‐Da Hong2004-07-01Macromolecules
By using the time-resolved small-angle light scattering (TRSALS) technique, we present the real-time measurement of the physical gelation process for a crystalline polymer. To investigate the growth kinetics, a complete picture of the gel structural formation should be differentiated into the nucleation and growth of…
Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies
Mingjun Li、Shumpei Ozawa、Kazuhiko Kuribayashi2004-07-01Philosophical Magazine Letters
A survey of the published literature on undercooled metallic and oxide melts suggests that phase selection during solidification can be categorized as nucleation controlled or growth controlled. Common characteristics governing the phase-selection pathway have been identified for various alloy systems. It is recognize…
Metallic Glasses and Amorphous AlloysSolidification and crystal growth phenomenaMetallurgical Processes and Thermodynamics
Sang‐Kee Lee、Koji Takahashi、Masahiro Yokouchi 等 5 位作者2004-07-01Journal of the American Ceramic Society
Al 2 O 3 reinforced by SiC whiskers (Al 2 O 3 /SiC‐W) was hot‐pressed to investigate the fatigue strength of crack‐healed specimens at high temperature. Semielliptical surface cracks of 100 μm surface length were introduced on each specimen surface. These specimens were crack‐healed at 1300°C for 1 h in air, and stati…
Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesFire effects on concrete materials
Farhad Shir、E. DellaTorre、L. H. Bennett 等 5 位作者2004-07-01IEEE Transactions on Magnetics
A time-dependent model of temperature in magnetization and demagnetization processes is developed based on thermodynamic and heat transfer laws, material properties, and variable-field magnet parameters. Test results of a magnetic refrigeration test bed are compared with the model calculation. The model can be used to…
Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsOptical properties and cooling technologies in crystalline materials
Tetsuji Zama、Susumu Hara、Wataru Takashima 等 4 位作者2004-07-01Bulletin of the Chemical Society of Japan
Abstract Highly stretchable and powerful PPy film actuators, prepared electrochemically from a methyl benzoate solution of tetra-n-butylammonium tetrafluoroborate (TBABF4), showed a positive correlation between the electrochemical stress and the mechanical tensile strength. The more flexible CF3SO3−-doped PPy suits mu…
Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors
Heather L. Hartman、Katherine Bowers、Carol A. Fierke2004-07-01Journal of Biological Chemistry
Protein geranylgeranyltransferase type I (GGTase I) catalyzes the attachment of a geranylgeranyl lipid group near the carboxyl terminus of protein substrates. Unlike protein farnesyltransferase (FTase) and protein geranylgeranyltransferase type II, which require both Zn(II) and Mg(II) for maximal turnover, GGTase I tu…
Bacterial Genetics and BiotechnologyRNA and protein synthesis mechanismsEnzyme Structure and Function
I.M. Ashraf2004-07-01The Journal of Physical Chemistry B
The photoconductivity (PC) of TlGaS 2 layered single crystals was investigated in the 77−300 K temperature, 1000−2500 lx excitation intensity, 10−25 V applied voltage, and 415−535 nm wavelength ranges. Both the alternating current photoconductivity (ac-PC) and the spectral distribution of the photocurrent were studied…
Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography
Kousuke Moritani、Michio Okada、Seiichi Sato 等 7 位作者2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films
The oxidation processes of Cu(111) with a hyperthermal O2 molecular beam (HOMB) were studied using high-resolution x-ray photoemission spectroscopy in conjunction with a synchrotron radiation source. The O-uptake curves were precisely measured at ∼300 K when irradiating with 2.3 and 0.6 eV HOMB on a Cu(111) surface. A…
Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides
Loredana Magistri、R. Bozzo、Paola Costamagna 等 4 位作者2004-07-01Journal of Engineering for Gas Turbines and Power
High-efficiency hybrid systems (HS) based on the coupling of solid oxide fuel cells (SOFCs) and gas turbines (GT) are analyzed in this paper through the use of two different approaches: simplified and detailed SOFC models. The simplified model, already presented by the authors, is very useful for HS design and off-des…
Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesCatalysis and Oxidation Reactions
María José Galotto、Abél Guarda2004-07-01Packaging Technology and Science
Abstract The suitability of alternative fatty food simulants on overall migration determination under thermal treatment and microwave heating were analysed for different plastic materials commonly used for packs subjected to thermal treatment or microwave heating. Elevated temperature and microwave heating increased o…
Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingFood Waste Reduction and Sustainability
David Mills、Kurt W. Kołasiński2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films
Mesoscale silicon pillars are formed when silicon wafers are irradiated by a nanosecond excimer laser operating at 308 nm and incident fluence of ∼3 J cm−2. The morphology of the pillars responds to the chemical composition of the gas phase above the Si surface. Postprocessing can also be used to change the structure…
Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications
Masato Hiratani、Vasily V. Bulatov2004-07-01Philosophical Magazine Letters
The critical resolved shear stress (CRSS) for a dislocation percolating through penetrable obstacles with different pinning strength is derived analytically. The stability of dislocation–obstacle configurations is determined by evaluating the configurational entropy. The analytical results imply a superposition law fo…
Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsFusion materials and technologies
Ana B. Ortíz‐Magán、M. Mercedes Pastor‐Blas、José Miguel Martín‐Martínez2004-07-01The Journal of Adhesion
The surface modifications produced by treatment of a synthetic vulcanized styrene-butadiene rubber (R1) with oxidizing (oxygen, air, carbon dioxide) and nonoxidizing (nitrogen, argon) RF plasmas have been assessed by ATR-IR and XPS spectroscopy, SEM, and contact angle measurements. The effectiveness of the treatment d…
Surface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomenaSilicone and Siloxane Chemistry