Materials Literature
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Abstract A kind of hydrophilic nano‐SiO 2 was applied to poly(ethylene terephthalate)/polyamide‐6 (PA‐6) blends. Melt‐blended composites were prepared at various component ratios and different nano‐SiO 2 levels. Mechanical, morphological, dynamic mechanical, and thermal tests were carried out to characterize the prope…
A kinetic model is developed with the goal of understanding and predicting the morphology evolution of nanocrystals in nonequilibrium growth conditions. The model is based on the assumption that under such conditions, different crystal planes have different kinetic parameters. This model focuses on the morphology-deve…
A new kind of amphiphiles containing an organometallic headgroup, an alkyl zinc alkoxide, self-assembles to form [MeZnOPEGn] gel (PEG: polyethylene glycol; n=400; see picture, left), which in turn serves as a precursor to afford nanoporous ZnO (right).
Abstract Waste tire powder was functionalized in the presence of various concentrations of allylamine and benzoyl peroxide. Fourier transform infrared spectroscopy studies confirmed the presence of allylamine on the surface of the rubber powder. The surface energy of the functionalized rubber powder revealed that the…
Abstract The changes of chemical and crystal structures of the reacetylation and degraded chitosans caused by sonication, acid hydrolysis, and H 2 O 2 oxidation were studied systematically. During the reacetylation of chitosan, acetic anhydride can result in the degradation of chitosan when its concentration exceeds a…
Beta,beta'-Fused monoruthenocenylporphyrins, Cp*Ru(III)[1,2-[M(II)-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-porphyrinato]-3-methyl-cyclopentadienide] (M = Ni (20), Cu (21), Zn (22)), and bisferrocenoporphyrins, Fe(II) bis[1,2-[M(II)-5,10,15,20-tetraphenylporphyrinato]-3-methyl-cyclopentadienide] (M = Ni (24), Cu (…
The properties of isotactic polypropylene (iPP) melts are investigated via atomistic molecular dynamics (MD) simulations in the isothermal−isobaric ( NPT ) ensemble. A fully flexible model is developed and validated by comparing predicted volumetric and thermodynamic behavior with available experimental data. Atomic-l…
Abstract A novel superabsorbent nanocomposite based on partially neutralized acrylic acid, waste polystyrene foam, and sodium type montmorillonite (Na‐MMT) powder was synthesized through emulsion polymerization using N, N′‐methylenebisacrylamide as a crosslinker, 2,2′‐azo‐bisiso‐butyronitrile, ammonium persulfate, and…
The relation between a dynamic and a thermodynamic temperature, glass transition Tg and boiling point Tb, is investigated for various glass-forming liquids, with emphasis on monohydroxy alcohols. As is well known, Tb and Tg are positively correlated across a large variety of liquids. However, we found that the same qu…
Abstract Fibers made of cellulose (CE) and silk fibroin (SF) are wet spun from solutions in N , N ‐dimethylacetamide containing 7% LiCl (w/w). Different coagulation baths (water and ethanol) and spinning conditions are used. By using water as the coagulant, a partial dissolution of SF occurs and negligible variation o…
Abstract Poly(ethylene terephthalate) (PET) resin is one of the most widely used engineering plastic with high performance, but the poor impact strength limits its applications for the notch sensitivity. In this research, toughened PET alloy was prepared by blending recycled PET with polycarbonate (PC) and MDI (methyl…
Abstract Methyl methacrylate (MMA) was directly grafted on natural rubber (NR) or sulfur prevulcanized (SP) NR surface. The rubber sheet was primarily treated with argon plasma, followed by exposure to air for generating active functional groups. After immersing in a mixture of 30% hydrogen peroxide and MMA in ethanol…
Abstract Polymer substrates are widely used in the flat‐panel‐display industry because of their flexibility, light weight, and high power efficiency. However, the lower glass‐transition temperatures and thermal stability and higher water/oxygen permeation of cycloolefin copolymers (COCs) constrain their applications i…
Abstract Aliphatic‐aromatic copolyesters of poly(butylene adipate‐ co ‐butylene terephthalate) have been synthesized by polycondensation. Molecular weights and thermal properties have been measured. The four samples of copolyesters, with aromatic contents, varying from 40 to 60 mol %, were investigated by 1 H‐NMR spec…
Abstract Cationic dyeable polyester and poly(butylene terephthalate) fabrics were treated with ozone gas under atmospheric pressure and at a pressure of 0.1 MPa. The effect of the ozone‐gas treatment was investigated on the basis of electron spectroscopy for chemical analysis, Fourier transform infrared spectrum, X‐ra…
Despite its good technical properties, the "Macigno" sandstone undergoes a typical process of decay when used outdoor, consisting prevalently in a flaking of the stone surface with detachment of rock fragments. In order to understand the causes of this decay, the relationships between mineralogy and physical rock prop…
Abstract In this paper, polyamide‐6 and polyamide‐6 nanocomposites were prepared by direct melt intercalation technique. The thermal degradation behavior of both polyamide‐6 and polyamide‐6 clay nanocomposites has been studied. The apparent activation energy of the nanocomposites is almost the same with that of pure p…
Abstract The present study is aimed to prepare hybrid materials by incorporating layered silicates and microcrystalline cellulose into thermoplastic polymer. Using ethylene–propylene (EP) copolymer as thermoplastic polymer matrix and maleated EP (MEP) copolymer as compatibilizer, three types of composites were prepare…
Author: Seydoux-Guillaume, A.-M. et al.; Genre: Journal Article; Finally published : 2007; Keywords: monazite, amorphous thorium silicate, TEM, FTIR, natural irradiation, aggregate spheres; Title: Contrasting response of ThSiO4 and monazite to natural irradiation
Abstract In this study silanized acrylated epoxidized soybean oil (silanized‐AESO), a multifunctional monomer, was synthesized by reacting acrylated epoxidized soybean oil with 3‐Aminopropyltriethoxysilane via a Michael addition reaction using less than equivalent amount of the silane. The characterization of silanize…