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Kinetic and spectroscopic studies on the self-aggregation of a meso-substituted amphiphilic corrole derivative

Manuela Stefanelli、Donato Monti、Mariano Venanzi 等 4 位作者2007-01-01New Journal of Chemistry

The solvent promoted aggregation behaviour of a meso-substituted amphiphilic corrole derivative occurs with the formation of aggregates with regular morphology, different from those obtained in the case of related porphyrin structures, opening interesting perspectives for the application of these derivatives in import…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSurface Chemistry and Catalysis

Supercapacitor Module SAM for Hybrid Busses: an Advanced Energy Storage Specification based on Experiences with the TOHYCO-Rider Bus Project

Vinzenz V. Haerri、Drago Martinović2007-01-01OpenAlex

In summer 2004 and 2006 the TOHYCO-Riderabus with supercapacitors and IPTbwas operated by the IIEECfor public transport services in Lucerne. A second generation version of a supercapacitor storage SAMdwas implemented and tested. A very important step in industrializing hybrid vehicles with SAM became fulfilled. The qu…

Supercapacitor Materials and FabricationAdvanced Battery Technologies ResearchElectric and Hybrid Vehicle Technologies

Retention of aqueous Ba2+ ions by calcite and aragonite over a wide range of concentrations: Characterization of the uptake capacity, and kinetics of sorption and precipitate formation

Özge Tunusoğlu、T. Shahwan、Ahmet E. Eroğlu2007-01-01GEOCHEMICAL JOURNAL

The uptake of aqueous Ba2+ ions by abiogenic calcite and aragonite was studied over a wide range of concentration; 1.0 × 101, 5.0 × 101, 1.0 × 102, 5.0 × 102, 1.0 × 103, 5.0 × 103, and 1.0 × 104 mg/L. The uptake process was characterized using ICP-AES, XRPD, SEM/EDS, and FTIR techniques. Up to the initial concentratio…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation TechniquesMine drainage and remediation techniques

The Science and Technology of Al-Ga Alloys as a Material for Energy Storage, Transport and Splitting Water

J. M. Woodall、Jeffrey T. Ziebarth、Charles R. Allen2007-01-01OpenAlex

Currently, there is much public discussion about the realization of a hydrogen economy as a viable alternative for future large-scale energy sources. Hydrogen as an energy source has several compelling features. For example, its gravimetric energy density is three times that of oil, its combustion and fuel cell produc…

Hydrogen Storage and MaterialsMXene and MAX Phase MaterialsAmmonia Synthesis and Nitrogen Reduction

Effect of Duplex-grained Structure on Yield Stress of IF Steels

Riichirou MATOBA、Nobuo Nakada、Y. Futamura 等 5 位作者2007-01-01鐵と鋼 : 日本鐡鋼協會々誌

The “nominal grain size” (average grain size) is generally applied to Hall-Petch relationship to evaluate grain refinement strengthening in polycrystalline materials. However, the steels with wide grain size distribution (duplex-grained structure) may not deform uniformly but yield preferentially from larger grains to…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetal Forming Simulation Techniques

Tuning of fluorescence properties of aminoterpyridine fluorophores by N-substitution

Jin‐Dong Cheon、Toshiki Mutai、Koji Araki2007-01-01Organic & Biomolecular Chemistry

Several N-alkyl and N-phenyl derivatives of 6-amino- () and 6,6'-diamino-2,2':6',2''-terpyridine () were synthesized, and their fluorescence properties were studied. A successive red-shift was observed as the number of the N-substituted groups increased. It was also shown that the susceptivity of the fluorophores to a…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Stress Corrosion Cracking Growth Rates of Candidate Canister Materials for Spent Nuclear Fuel Storage in Chloride-Containing Atmosphere

Junichi Tani、Masami Mayuzumi、Taku Arai 等 4 位作者2007-01-01MATERIALS TRANSACTIONS

Chloride-induced stress corrosion crack growth rates were measured for candidate canister materials in a simulated marine atmospheric environment. Half-inch compact tension specimens were used to obtain stress corrosion crack growth rates by applying a direct-current potential-drop method to measure crack lengths. The…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Reactive Diffusion between Solid Fe and Liquid Zn at 723 K

Ryosuke Kainuma、Kiyohito Ishida2007-01-01ISIJ International

Reactive diffusion between solid Fe and liquid Zn was experimentally examined using Fe/Zn diffusion couples prepared by an immersion technique. Using this technique, a pure iron sheet was immersed in a molten pure Zn bath with a constant temperature of T=723 K (450°C) for various times up to t=7.2×103 s (2 h). The mic…

Corrosion Behavior and InhibitionMetallurgical Processes and ThermodynamicsElectrodeposition and Electroless Coatings

Improvement of optical gas sensing using LB films containing a water insoluble porphyrin organized in a calixarene matrix

Gustavo de Miguel、Marı́a T. Martı́n-Romero、José M. Pedrosa 等 7 位作者2007-01-01Journal of Materials Chemistry

A water insoluble porphyrin 5,10,15,20-tetrakis[3,4-bis(2-ethylhexyloxy)phenyl]-21H,23H-porphine (EHO) that is highly sensitive to low concentrations of NO2 in nitrogen has been organized at the air–water interface using a host calix[8]arene (C8A) matrix. Different composition ratios of C8A have been studied at the ai…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Cross-linked and functionalized polyester materials constructed using ketoxime ether linkages

Brooke Van Horn、Karen L. Wooley2007-01-01Soft Matter

A modular and simple approach to the graft functionalization and cross-linking of ketone-containing poly(ε-caprolactone)s has been investigated for the preparation of novel gel and nanoparticulate materials. Poly(ε-caprolactone--2-oxepane-1,5-dione) (P(CL--OPD)), was grafted by reaction with 1-aminooxydodecane and cro…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Estimate of the vibrational contribution to the entropy change associated with the spin transition in the d 4 systems [Mn III (pyrol) 3 tren] and [Cr II (depe) 2 I 2 ]

Yann Garcia、Hauke Paulsen、Volker Schünemann 等 5 位作者2007-01-01Physical Chemistry Chemical Physics

The vibrational contribution to DeltaS of the low-spin ((3)T(1)) to high-spin ((5)E) spin transition in two 3d(4) octahedral systems [Mn(III)(pyrol)(3)tren] and [Cr(depe)(2)I(2)] have been estimated by means of DFT calculations (B3LYP/CEP-31G) of the vibrational normal-modes frequencies. The obtained value at the tran…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Potassium-Assisted Chromium Transport in Solid Oxide Fuel Cells

Brian J. Ingram、T. A. Cruse、M. Krumpelt2007-01-01Journal of The Electrochemical Society

Chromium transport from stainless steel current collectors to the cathode can be a route for rapid performance degradation in solid oxide fuel cells. Typical volatile chromium species, such as , are manageable; however, volatile species with higher vapor pressures may play a significant role in chromium transport and…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsElectronic and Structural Properties of Oxides

AgI Nanoplates in Unusual 7H/9R Structures

Yu‐Guo Guo、Jong‐Sook Lee、Yong‐Sheng Hu 等 4 位作者2007-01-01Journal of The Electrochemical Society

Homogeneous AgI nanoplates in diameter and in thickness can be prepared by a solution-based route using poly(diallyldimethylammonium chloride) as capping agent. The formation of unusual 7H/9R polytype modifications is the origin of the huge room temperature superionic conductivity and the large hysteresis in the phase…

Advanced Battery Materials and TechnologiesQuantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and Devices

Antimicrobial properties of fungal chitosan

Azam Jeihanipour、Kazem Karimi、Mohammad J. Taherzadeh2007-01-01KTH Publication Database DiVA (KTH Royal Institute of Technology)

Cell wall of zygomycetes fungus is an alternative source for chitosan production. In this study chitosan was extracted from cell wall of filamentous fungus Rhizopus oryzae and its antimicrobial properties was studied against three typical human pathogenic microorganisms, Escherichia coli, Klebsiella pneumoniae and Sta…

Nanocomposite Films for Food PackagingPlant Pathogens and Fungal DiseasesMedicinal Plant Research

Hydrogen degradation of high strength weldable steels

J. Ćwiek2007-01-01Journal of Achievements of Materials and Manufacturing Engineering

Purpose: Purpose of this paper is presentation of hydrogen degradation issue of high strength steels and especially their welded joints. Establishing of applicable mechanisms of hydrogen-enhanced cracking was the aim of performed research. Design/methodology/approach: High strength quenched and tempered steels grade S…

Fatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

Evaluating Weigh-In-Motion Sensing Technology for Traffic Data Collection

L Zhang、Charles J. Hass、Susan Tighe2007-01-01OpenAlex

The significance of highway preservation and budget allocation constraints have motivated development of sensing technologies for collecting accurate and detailed traffic information. While static scales had been used widely to collect vehicle weights, Weigh-In-Motion (WIM) systems have been focused on utilizing state…

Engineering and Material Science ResearchTransport Systems and TechnologyTransportation Safety and Impact Analysis

Preparations of TiO2 film coated on foam nickel substrate by sol-gel processes and its photocatalytic activity for degradation of acetaldehyde

Hu、Hai Hai、Xiao Xiao 等 13 位作者2007-01-01Acta Scientiarum Naturalium Universitatis Sunyatseni

锐钛矿 TiO2 电影被 XPS , XRD , FE-SEM , TEM 和紫外力的吸收成功地用 TiO2 电影 wereinvestigated 的 tetrabutyl titanate asprecursor.The 特征在泡沫镍底层bysol胶化技术上准备 spectra.Thephotocatalytic 活动 ofTiO2 电影被气体的乙醛的 photocatalytic 降级反应调查, anindoorpollutant ,在紫外光下面, irradiation.It 被发现那Ni2+做进 TiO2 filmsdue 到泡沫镍底层 resultedin 前

Catalytic Processes in Materials ScienceNanomaterials for catalytic reactionsAdvanced Nanomaterials in Catalysis

PREPARATION AND CHARACTERIZATION OF PHOSPHATE GLASSES CONTAINING TITANIUM

Babita Tiwari、Anupam Dixit、G.P. Kothiyal 等 5 位作者2007-01-01OpenAlex

A b s t r a c t Clear bubble-free phosphate glasses, having composition 40Na 2 O-10Al 2 O 3 -xTiO 2 -(50-x)P 2 O 5 , (x = 0-20 mol %), were prepared by conventional melt quench method. Density, molar volume, glass transition temperature (Tg), MicroHardness (MH), and Thermal Expansion Coefficient (TEC) were measured as…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPigment Synthesis and Properties